Coordination of Cu(II) and Ni(II) in polymers imprinted so as to optimize amine chelate formation

Molecular imprinting has become an established technique. However, little was done on direct investigation of the sorbents produced. In the present work, en ESR method was used for the investigation of the complex formation processes within the sorbents imprinted with copper(II) and nickel(II). The sorbents were synthesized from a mixture of linear low molecular weight polyethyleneimine oligomers. The composition, structure and distribution of complexes in the resin phase were investigated. The effects of the synthesis conditions, loading degree and water content were examined. The presence of certain copper complexes was found to be a convenient characteristic of the imprinting efficiency. The optimum synthesis conditions for obtaining sorbents imprinted with copper(II) or nickel(II) were identified. The imprinting results in the improvement of the stability of the complexes and the selectivity and working capacity of the sorbents. The imprinted samples are also characterized by a more even distribution of chelating sites. The synthesis conditions and loading by ions allow for the regulation of the ratio between individual complexes and magnetic associates in the resin phase. This is a critical point on the future use of the metal containing imprinted sorbents as catalysts. (C) 2003 Published by Elsevier Science Ltd

Characterization of chitin and its complexes extracted from natural raw sources

It is known that the main source of chitin and chitosan are shells of shrimp and other sea crustaceans. Alternative row sources of chitin, chitosan and its complexes are the lowest plants - mushrooms and insects. Also industrial wastes, especially from brewing of beer and manufacture of wine and ethanol can be used for extracting chitosan-containing products. The present research is aimed to the extraction of chitin and its complexes from alternative row sources, such as insects (cockroaches Pariplaneta Americana linnaeus and bees Apis mellifera lineaus), mushrooms (Amanita phalloides and Lactarius subdulius), waste banana wine (Kovibar and Urwibutso Inc.) and beer products (Bralirwa Inc., traditional sorghum) characteristic for Rwanda and their characterization using FTIR spectroscopy and elementary analysis. In chitin and its complexes extraction from all used raw sources, conditions for deproteinization were: 8% NaOH at 95 °C for 1 h and demineralization involved treatment with 6.7 % HCl at room temperature. Chitin and its complexes in the extracted samples were identified by FTIR spectroscopy using reference sample of Aspegillus Niger mushrooms. The presence of chitin parts causes the absorption band at 1650, 1552 and 1376 cm-1, which correspond to vibrations of amide groups amide I amide II and amide III, respectively. Using elemental analysis, the ratios of chitin and glucan parts were estimated and the percentage of chitin composition of all species was determined. For most of raw sources a fraction of chitin part was greater than that of glucan part. The chitin content of the samples studied ranged between 0.7-0.8 % of DM (dried mass) for wine (beer) waste products and 38% of dried mass (DM) for cockroaches. © 2016 Author(s).2014/239, 4.1626.2014/KRussian Foundation for Basic Research, RFBR: 14-03-00898Government Council on Grants, Russian FederationThis work was supported by the Russian Foundation for Basic Research (Grant 14-03-00898), the Program 211 of the Government of the Russian Federation No 02.A03.21.0006 and the State Tasks of the Ministry of Education (Russian Federation) No. 4.1626.2014/K and No. 2014/239 and the local Grant of University of Rwanda "Chitosancontaining materials of multifunctional application for needs of Rwanda". The authors are thankful to J.P. Intwali (Rwanda), E.V. Habumugisha (Rwanda), Ch. Ukundineza (Rwanda) and D. Niyoyita (Rwanda) for capturing insects and gathering mushrooms and their initial preparation for chitin extraction

Properties of coatings on the basis of carbon, tungsten, boron, and titanium obtained by the pulsed vacuum-arc method

Results of an investigation of the properties of coatings on the basis of carbon, tungsten, boron, and titanium obtained by the pulsed vacuum-arc method are presented. It has been found that the adhesion characteristics of coatings based on boron and titanium may be improved using a composite carbon-based coating, doped with tungsten, boron, and titanium, which, moreover, has a microhardness greater than those of a coating based on titanium and boro

Open star clusters in the Milky Way - Comparison of photometric and trigonometric distance scales based on Gaia TGAS data

The global survey of star clusters in the Milky Way (MWSC) is a comprehensive list of 3061 objects that provides, among other parameters, distances to clusters based on isochrone fitting. The Tycho-Gaia Astrometric Solution (TGAS) catalogue, which is a part of Gaia data release 1 (Gaia DR1), delivers accurate trigonometric parallax measurements for more than 2 million stars, including those in star clusters. We compare the open cluster photometric distance scale with the measurements given by the trigonometric parallaxes from TGAS to evaluate the consistency between these values. The average parallaxes of probable cluster members available in TGAS provide the trigonometric distance scale of open clusters, while the photometric scale is given by the distances published in the MWSC. Sixty-four clusters are suited for comparison as they have more than 16 probable members with parallax measurements in TGAS. We computed the average parallaxes of the probable members and compared these to the photometric parallaxes derived within the MWSC. We find a good agreement between the trigonometric TGAS-based and the photometric MWSC-based distance scales of open clusters, which for distances less than 2.3 kpc coincide at a level of about 0.1 mas with no dependence on the distance. If at all, there is a slight systematic offset along the Galactic equator between $30^\circ$ and $160^\circ$ galactic longitude.Comment: Accepted for publication as a Letter in Astronomy and Astrophysics, 4 pages, 4 figure

CHALLENGES AND PROSPECTS OF WHITE BIOTECHNOLOGY. AN OVERVIEW

Biotechnology is a large field of science comprising various areas of study such as bio-chemistry, microbiology, biology, chemistry, chemical engineering, immunology, etc. White Biotechnology, mainly known as Industrial Biotechnology is the key technology