Effect of impurity presence in zinc chloride electrowinning

Zinc chloride electrowinning presents difficulties in obtaining smooth, compact and dendrite free deposits with a high current efficiency due to the presence of undesirable metal ions. However, it is hard to define a level of impurities tolerable in zinc deposition, and despite a lot of research in this field, the reaction mechanisms of the undesired metal ions are still not clearly understood. In this study, the influence of Fe, Cd, Co, Ni and Cu additions were investigated, as well as their synergic effect on the zinc electrodeposition process from chloride electrolytes and on the obtained deposit morphology. The tests were all performed in presence of TBAC1 which reduces the harmful effect of such impurities on the zinc reduction

Influence of structural factor on corrosion rate of functional Zn-Ni coatings

The electrocrystallization processes of Zn-Ni coatings from weakly acid Sulfate Solutions with the addition of citrate and acetate complexing compounds have been compared. The deposition kinetics and the influence of electrolyte composition on the Zn-Ni alloy composition and on some physicochemical properties (corrosion resistance, texture, phase composition, morphology) were determined. It was found that the properties of coatings obtained under the same operating conditions in electrolytes with the same [Ni(II)]/[Zn(II)] concentration ratio and pH but containing different complexing agents were different. The composition of the deposits and their texture as well as phase structure were found to depend on the complexing species present. Coatings deposited from acetate solutions are richer in Ni than those from citrate solutions. The corrosion resistance of a Zn-Ni alloy depends in practice on the percentage of Ni, but in sulfate-citrate electrolytes, layers containing less Ni were obtained with the same corrosion resistance as Ni-rich coatings deposited from acetate solution. The corrosion current decreases more rapidly with increasing Ni content. This effect is connected mainly with phase composition. In citrate solutions practically single-phase (hexagonal eta) deposits were obtained which provide better protection with a lower corrosion rate in comparison with alloys consisting of three phases (hexagonal eta, monoclinic delta, regular gamma) deposited from acetate baths. (C) 2003 Elsevier Science Ltd. All rights reserved

Electrodeposition of Zn-Ni protective coatings from sulfate-acetate baths

The electrodeposition conditions for Zn-Ni alloys from sulfate-acetate electrolytes have been studied with the view of preparing protective coatings. The influence of electrolyte composition (different [Ni(II)/[Zn(H)] ratios, pH, buffer), cathode current density, cathode potential and hydrodynamic conditions on the composition of coatings, cathode current efficiency and corrosion resistance were determined. For all of the conditions examined, strong inhibition of nickel reduction with simultaneous increase in the rate of zinc discharge characteristic of an anomalous system, have been observed. The Zn(II) discharge becomes diffusion-controlled at more negative cathode potentials, whereas the partial nickel current densities are independent of electrode rotation speed. Consequently, nickel content and current efficiency are reduced with decreasing thickness of the diffusive layer. An increase in pH above 3.3 causes a significant catalysis of Zn-Ni deposition with a simultaneous decrease of the nickel in coatings. This effect may be related to the formation and increasing concentration of Zn(H) and Ni(II) acetate complexes in this condition. The Zn-Ni coatings obtained (5-18% NO characterise improved corrosion resistance in comparison to Zn layers deposited under the same conditions. (C) 2002 Elsevier Science B.V. All rights reserved

Failure modes of coatings on steel substrate

The critical monotonic strain of Ni-W and MoS2(Ti,W) coatings on steel substrates was studied. The idea of axisymmetric bending test (called here as coin bending test) limited to monitoring of the coating failure was used. Experiments revealed mechanism of the coating failure, as cracking initiated from coating surface defects and/or substrate was demonstrated using indentation technique. By pushing the center of the uncoated side of a circular plate, the axisymmetric stress state was generated in the coating. The stress components varied gradually from the greatest value in the center to the smallest value at the edge of the specimen. The changes of the sample surface as a result of loading were monitored step by step via optical microscopy

Failure modes of coatings on steel substrate

The critical monotonic strain of Ni-W and MoS2(Ti,W) coatings on steel substrates was studied. The idea of axisymmetric bending test (called here as coin bending test) limited to monitoring of the coating failure was used. Experiments revealed mechanism of the coating failure, as cracking initiated from coating surface defects and/or substrate was demonstrated using indentation technique. By pushing the center of the uncoated side of a circular plate, the axisymmetric stress state was generated in the coating. The stress components varied gradually from the greatest value in the center to the smallest value at the edge of the specimen. The changes of the sample surface as a result of loading were monitored step by step via optical microscopy

Effects of current density, coating thickness, temperature, pH and particle concentration on internal stress during Ni–MoS 2

Internal stress in plated deposits has been a common problem that may affect the functionality of coatings. Electrodeposition parameters and insoluble particles modify the characteristics and the level of internal stress of coatings. The influence of the electrocodeposition parameters and their interaction effects on the internal stress during the electrodeposition of Ni and Ni-MoS2 composite coatings were studied by fractional factorial design. The parameters studied and their ranges were: MoS2 particle concentration (0-10 g L-1), temperature (30-50 degrees C), pH (2-4), current density (1.2-4.8 A dm(-2)), and coating thickness (25-50 mu m). MoS2 addition into Watts bath resulted in the decrease in the tensile internal stress values or even changed the stress character from tensile to compressive. Moreover, low stress values were obtained when pH was 2 and coating thickness was 50 mu m