27 research outputs found
Structure and time-dependence of quantum breathers
Quantum states of a discrete breather are studied in two ways. One method
involves numerical diagonalization of the Hamiltonian, the other uses the path
integral to examine correlations in the eigenstates. In both cases only the
central nonlinearity is retained. To reduce truncation effects in the numerical
diagonalization, a basis is used that involves a quadratic local mode. A
similar device is used in the path integral method for deducing localization.
Both approaches lead to the conclusion that aside from quantum tunneling the
quantized discrete breather is stable.Comment: 33 pages, 20 figures, to appear in J. Chem. Phy
Discrete breathers in and related models
We touch upon the wide topic of discrete breather formation with a special
emphasis on the the model. We start by introducing the model and
discussing some of the application areas/motivational aspects of exploring time
periodic, spatially localized structures, such as the discrete breathers. Our
main emphasis is on the existence, and especially on the stability features of
such solutions. We explore their spectral stability numerically, as well as in
special limits (such as the vicinity of the so-called anti-continuum limit of
vanishing coupling) analytically. We also provide and explore a simple, yet
powerful stability criterion involving the sign of the derivative of the energy
vs. frequency dependence of such solutions. We then turn our attention to
nonlinear stability, bringing forth the importance of a topological notion,
namely the Krein signature. Furthermore, we briefly touch upon linearly and
nonlinearly unstable dynamics of such states. Some special aspects/extensions
of such structures are only touched upon, including moving breathers and
dissipative variations of the model and some possibilities for future work are
highlighted
Optical properties of -doped phosphor
KLuS2 single crystals doped with trivalent cerium were synthesized in the form of crystalline hexagonal platelets. VUV/UV/VIS absorption and luminescence characteristics were measured in the broad temperature and concentration intervals. The band edge of KLuS2 is found at 303 nm, Ce3+ 4f–5d excitation band at 490 nm and Ce3+ emission at 580 nm with the 35 ns decay time. Both thermal and concentration quenching of the Ce3+ emission are investigated. Phenomenological modeling and delayed recombination decays measurement are employed to understand the Ce3+ excited state dynamics. The application potential in X-ray phosphors is discussed
Luminescence and scintillation properties of YAG:Ce single crystal and optical ceramics
We use various techniques to study optical and scintillation properties of Ce-doped yttrium aluminum garnet, Y3Al5O12 (YAG:Ce), in the form of a high-quality industrial single crystal. This was compared to optical ceramics prepared from YAG:Ce nanopowders. We present experimental data in the areas of optical absorption, radioluminescence, scintillation decay, photoelectron yield, thermally stimulated luminescence and radiation-induced absorption. The results point to an interesting feature—the absence of antisite (YAl, i.e. Y at the Al site) defects in optical ceramics. The scintillation decay of the ceramics is faster than that of the single crystal, but its photoelectron yield (measured with 1 μs integration time) is about 30–40% lower. Apart from the photoelectron yield value the YAG:Ce optical ceramic is fully comparable to a high quality industrial YAG:Ce single crystal and can become a competitive scintillator material