24 research outputs found

    The Rotating Cone Electrode

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    The Dynamic Micropolarization Method: I . Application to Aluminum

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    Sensitive amperometric titration of o-phenylenediamine employing catalyticelectrode reaction end-point detection

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    The catalytic prewave of the Ni-opda system has been used for a sensitive amperometric detection of the end-point of the opda titration. Au(III) was chosen as titrant from a large group of possible oxidants, because of its favourable equilibrium and kinetic properties. Three end-points are observed in the titration and the reactions involved were shown to be as follows:Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/33209/1/0000598.pd
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