13 research outputs found
Effect of Flow Rate of a Biphasic Reaction Mixture on Limonene Hydrogenation in High Pressure CO 2
No full textIonic liquids’ cation and anion influence on aromatic amine solubility
No full texthe mutual solubility of aniline and a series of imidazolium based ionic liquids with bis(trifluoromethylsulfonyl)amide, chloride, dicyanamide, tetrafluoroborate, and hexafluorophospate anions were studied. The produced results show the potential in the new solvent systems which can be used in amine chemistry. The liquid–liquid equilibrium (LLE) and solid–liquid equilibrium (SLE) measurements were performed using a dynamic (synthetic) method. The mutual solubility of aniline in
bis(trifluoromethylsulfonyl)amide and hexafluorophosphate ionic liquids was complete in the examined range of temperatures. The solubility of remaining studied ionic liquids decreases with the decrease of Kamlet–Taft basicity of ionic liquid anion. In other words, the solubility was the lowest for a chloride ionic liquid and increases for dicyanamide and for tetrafluoroborate ionic liquids. Additionally, the increase of the alkyl chain length of the IL cation effects negatively the solubility of aniline in the
investigated ionic liquids
Catalytic hydrodeoxygenation of pyrolysis oil over nickel-based catalysts under H2/CO2 atmosphere
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Volumetric and Acoustic Properties of Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Tetrafluoroborate [bmim][BF 4
No full textEfficient Conversion of α-Angelica Lactone into γ-Valerolactone with Ionic Liquids at Room Temperature
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