Tris(hydroxypropyl)phosphine Oxide: A Chiral Three-Dimensional Material with Nonlinear Optical Properties

The achiral C_(3v) organic phosphine tris(hydroxypropyl)phosphine oxide (1) crystallizes in the unusual chiral hexagonal space group P6_3. The structure is highly ordered because each phosphine oxide moiety forms three hydrogen bonds with adjacent hydroxy groups from three different molecules. The properties of the crystals and the presence of hydrogen bonding interactions were investigated using single crystal Raman spectroscopy. The crystals show nonlinear optical properties and are capable of efficient second harmonic generation

Photometry and the Metallicity Distribution of the Outer Halo of M31. II. The 30 Kpc Field

We present the results of a wide-field (V,I) photometric study of the red-giant branch (RGB) stars in the outer halo of M31, in a field located 30 to 35 kpc from the center of the galaxy along the southeast minor axis. At this remote location, we find that RGB stars belonging to M31 are sparsely but definitely present, after statistical subtraction of field contamination. We derive the metallicity distribution (MDF) for the halo stars using interpolation within a standard (I,V-I) grid of RGB evolutionary tracks. The halo MDF is quite broad but dominated by a moderately high-metallicity population peaking at [m/H] ~ -0.5, strikingly different from the [m/H] ~ -1.3 level which characterizes the outer halo of the Milky Way. However,the shape and peak metallicity for this region are entirely similar to those found in other studies for the inner regions of the M31 halo, particularly our previous study of a 20-kpc region (Durrell, Harris, & Pritchet 2001) employing similar data. In summary, we find no evidence for a metallicity gradient or systematic change in the MDF out to quite large distances in the M31 halo: it appears to be a homogeneous and moderately metal-rich subsystem of the galaxy at all locations. The star counts in the 30-kpc field are also consistent with the r^1/4 law that fits the interior regions of the M31 spheroid surface brightness profile. The metal-rich MDF and the r^1/4 spheroid suggests M31 more strongly resembles a giant elliptical galaxy than other, Milky-Way-like, spirals.Comment: 28 pages, including 9 figures; accepted for publication in the Astronomical Journa

BST1047+1156: A (Failing) Ultradiffuse Tidal Dwarf in the Leo I Group

© 2024 The Author(s). Published by the American Astronomical Society. This is an open access article distributed under the terms of the Creative Commons Attribution License (CC BY), https://creativecommons.org/licenses/by/4.0/We use deep Hubble Space Telescope imaging to study the resolved stellar populations in BST1047+1156, a gas-rich, ultradiffuse dwarf galaxy found in the intragroup environment of the Leo I galaxy group. While our imaging reaches approximately two magnitudes below the tip of the red giant branch at the Leo I distance of 11 Mpc, we find no evidence for an old red giant sequence that would signal an extended star formation history for the object. Instead, we clearly detect the red and blue helium-burning sequences of its stellar populations, as well as the fainter blue main sequence, all indicative of a recent burst of star formation having taken place over the past 50–250 Myr. Comparing to isochrones for young metal-poor stellar populations, we infer this post-starburst population to be moderately metal-poor, with metallicity [M/H] in the range −1 to −1.5. The combination of a young, moderately metal-poor post starburst population and no old stars motivates a scenario in which BST1047 was recently formed during a weak burst of star formation in gas that was tidally stripped from the outskirts of the neighboring massive spiral M96. BST1047's extremely diffuse nature, lack of ongoing star formation, and disturbed H i morphology all argue that it is a transitory object, a “failing tidal dwarf” in the process of being disrupted by interactions within the Leo I group. Finally, in the environment surrounding BST1047, our imaging also reveals the old, metal-poor ([M/H] = − 1.3 ± 0.2) stellar halo of M96 at a projected radius of 50 kpc.Peer reviewe

Photometry and the Metallicity Distribution of the Outer Halo of M31

We have conducted a wide-field CCD-mosaic study of the resolved red-giant branch (RGB) stars of M31, in a field located 20 kpc from the nucleus along the SE minor axis. In our (I, V-I) color-magnitude diagram, RGB stars in the top three magnitudes of the M31 halo are strongly present. Photometry of a more distant control field to subtract field contamination is used to derive the `cleaned' luminosity function and metallicity distribution function (MDF) of the M31 halo field. From the color distribution of the foreground Milky Way halo stars, we find a reddening E(V-I)= 0.10 +/- 0.02 for this field, and from the luminosity of the RGB tip, we determine a distance modulus (m-M)_o = 24.47 +/- 0.12 (= 783 +/- 43 kpc). The MDF is derived from interpolation within an extensive new grid of RGB models (Vandenberg et al. 2000). The MDF is dominated by a moderately high-metallicity population ([m/H]~ -0.5) found previously in more interior M31 halo/bulge fields, and is much more metal-rich than the [m/H]~ -1.5 level in the Milky Way halo. A significant (~30% - 40%, depending on AGB star contribution) metal-poor population is also present. To first order, the shape of the MDF resembles that predicted by a simple, single-component model of chemical evolution starting from primordial gas with an effective yield y=0.0055. It strongly resembles the MDF recently found for the outer halo of the giant elliptical NGC 5128 (Harris et al. 2000), though NGC 5128 has an even lower fraction of low-metallicity stars. Intriguingly, in both NGC 5128 and M31, the metallicity distribution of the globular clusters in M31 does not match the halo stars; the clusters are far more heavily weighted to metal-poor objects. We suggest similarities in the formation and early evolution of massive, spheroidal stellar systems.Comment: to appear in the Astronomical Journal; 43 pages, including 15 figure

The FLARE Network: Vicarious Cal/Val for Earth Observation Satellites

Calibration and characterization of radiometric and geospatial performance is necessary for the accurate retrieval of information from Earth Observation platforms. For small satellite constellations, this is especially true to ensure data quality and consistency among multiple craft that lack on-board calibration equipment. The Field Line-of-sight Automate Radiance Exposure (FLARE) Network provides an automated, on-demand calibration solution designed to meet the requirements of both agency and commercial operators by providing NIST traceable data without the need for expensive campaigns o r on-board calibration sources. FLARE radiometric performance has been verified with Landsat 8 – OLI. FLARE was successfully utilized with Planet SkySat and PlanetScope assets for rapid verification of resolution performance, and in commissioning efforts of new satellites following launch

The Next Generation Virgo Cluster Survey. X. Properties of Ultra-Compact Dwarfs in the M87, M49 and M60 Regions

We use imaging from the Next Generation Virgo cluster Survey (NGVS) to present a comparative study of ultra-compact dwarf (UCD) galaxies associated with three prominent Virgo sub-clusters: those centered on the massive, red-sequence galaxies M87, M49 and M60. We show how UCDs can be selected with high completeness using a combination of half-light radius and location in color-color diagrams ($u^*iK_s$ or $u^*gz$). Although the central galaxies in each of these sub-clusters have nearly identical luminosities and stellar masses, we find large differences in the sizes of their UCD populations, with M87 containing ~3.5 and 7.8 times more UCDs than M49 and M60, respectively. The relative abundance of UCDs in the three regions scales in proportion to sub-cluster mass, as traced by X-ray gas mass, total gravitating mass, number of globular clusters, and number of nearby galaxies. We find that the UCDs are predominantly blue in color, with ~85% of the UCDs having colors similar to blue GCs and stellar nuclei of dwarf galaxies. We present evidence that UCDs surrounding M87 and M49 may follow a morphological sequence ordered by the prominence of their outer, low surface brightness envelope, ultimately merging with the sequence of nucleated low-mass galaxies, and that envelope prominence correlates with distance from either galaxy. Our analysis provides evidence that tidal stripping of nucleated galaxies is an important process in the formation of UCDs.Comment: 37 pages, 40 figures. To appear in The Astrophysical Journa

The Next Generation Virgo Cluster Survey. VIII. The Spatial Distribution of Globular Clusters in the Virgo Cluster

We report on a large-scale study of the distribution of globular clusters (GCs) throughout the Virgo cluster, based on photometry from the Next Generation Virgo Cluster Survey, a large imaging survey covering Virgo's primary subclusters to their virial radii. Using the g', (g'-i') color-magnitude diagram of unresolved and marginally-resolved sources, we constructed 2-D maps of the GC distribution. We present the clearest evidence to date showing the difference in concentration between red and blue GCs over the extent of the cluster, where the red (metal-rich) GCs are largely located around the massive early-type galaxies, whilst the blue (metal-poor) GCs have a more extended spatial distribution, with significant populations present beyond 83' (215 kpc) along the major axes of M49 and M87. The GC distribution around M87 and M49 shows remarkable agreement with the shape, ellipticity and boxiness of the diffuse light surrounding both galaxies. We find evidence for spatial enhancements of GCs surrounding M87 that may be indicative of recent interactions or an ongoing merger history. We compare the GC map to the locations of Virgo galaxies and the intracluster X-ray gas, and find good agreement between these baryonic structures. The Virgo cluster contains a total population of 67300$\pm$14400 GCs, of which 35% are located in M87 and M49 alone. We compute a cluster-wide specific frequency S_N,CL=$2.8\pm0.7$, including Virgo's diffuse light. The GC-to-baryonic mass fraction is e_b=$5.7\pm1.1\times10^{-4}$and the GC-to-total cluster mass formation efficiency is e_t=$2.9\pm0.5\times10^{-5}$, values slightly lower than, but consistent with, those derived for individual galactic halos. Our results show that the production of the complex structures in the unrelaxed Virgo cluster core (including the diffuse intracluster light) is an ongoing process.(abridged)Comment: 23 pages, 17 figures. Accepted for publication in the Astrophysical Journal. Figure 1 has reduced resolution. Revised version with updated references, corrected typos -- no changes to result