Permeability of mixed soft and hard granular material: hydrogels as drainage modifiers

We measure the flow of water through mixed packings of glass spheres and soft swellable hydrogel grains, at constant sample volume. Permeability values are obtained at constant sample volume and at porosities smaller than random close packing, for different glass bead diameters $D$ and for variable gel grain diameter $d$, as controlled by the salinity of the water. The gel content is also varied. We find that the permeability decays exponentially in $n(D/d)^b$ where $n=N_{gel}/N_{glass}$ is the gel to glass bead number ratio and $b$ is approximately 3. Therefore, flow properties are determined by the volume fraction of gel beads. A simple model based on the porosity of overlapping spheres is used to account for these observations

Effect of hydrogel particle additives on water-accessible pore structure of sandy soils: A custom pressure plate apparatus and capillary bundle model

To probe the effects of hydrogel particle additives on the water-accessible pore structure of sandy soils, we introduce a custom pressure plate method in which the volume of water expelled from a wet granular packing is measured as a function of applied pressure. Using a capillary bundle model, we show that the differential change in retained water per pressure increment is directly related to the cumulative cross-sectional area distribution $f(r)$ of the water-accessible pores with radii less than $r$. This is validated by measurements of water expelled from a model sandy soil composed of 2 mm diameter glass beads. In particular, the expelled water is found to depend dramatically on sample height and that analysis using the capillary bundle model gives the same pore size distribution for all samples. The distribution is found to be approximately log-normal, and the total cross-sectional area fraction of the accessible pore space is found to be $f_0=0.34$. We then report on how the pore distribution and total water-accessible area fraction are affected by superabsorbent hydrogel particle additives, uniformly mixed into a fixed-height sample at varying concentrations. Under both fixed volume and free swelling conditions, the total area fraction of water-accessible pore space in a packing decreases exponentially as the gel concentration increases. The size distribution of the pores is significantly modified by the swollen hydrogel particles, such that large pores are clogged while small pores are formed

Topological persistence and dynamical heterogeneities near jamming

We introduce topological methods for quantifying spatially heterogeneous dynamics, and use these tools to analyze particle-tracking data for a quasi-two-dimensional granular system of air-fluidized beads on approach to jamming. In particular we define two overlap order parameters, which quantify the correlation between particle configurations at different times, based on a Voronoi construction and the persistence in the resulting cells and nearest neighbors. Temporal fluctuations in the decay of the persistent area and bond order parameters define two alternative dynamic four-point susceptibilities, XA(t) and XB(t), well-suited for characterizing spatially-heterogeneous dynamics. These are analogous to the standard four-point dynamic susceptibility X4(l,t), but where the space-dependence is fixed uniquely by topology rather than by discretionary choice of cutoff function. While these three susceptibilities yield characteristic time scales that are somewhat different, they give domain sizes for the dynamical heterogeneities that are in good agreement and that diverge on approach to jamming

Rain water transport and storage in a model sandy soil with hydrogel particle additives

We study rain water infiltration and drainage in a dry model sandy soil with superabsorbent hydrogel particle additives by measuring the mass of retained water for non-ponding rainfall using a self-built 3D laboratory set-up. In the pure model sandy soil, the retained water curve measurements indicate that instead of a stable horizontal wetting front that grows downward uniformly, a narrow fingered flow forms under the top layer of water-saturated soil. This rain water channelization phenomenon not only further reduces the available rain water in the plant root zone, but also affects the efficiency of soil additives, such as superabsorbent hydrogel particles. Our studies show that the shape of the retained water curve for a soil packing with hydrogel particle additives strongly depends on the location and the concentration of the hydrogel particles in the model sandy soil. By carefully choosing the particle size and distribution methods, we may use the swollen hydrogel particles to modify the soil pore structure, to clog or extend the water channels in sandy soils, or to build water reservoirs in the plant root zone

Relaxing in foam

We investigate the mechanical response of an aqueous foam, and its relation to the microscopic rearrangement dynamics of the bubble-packing structure. At rest, even though the foam is coarsening, the rheology is demonstrated to be linear. Under flow, shear-induced rearrangements compete with coarsening-induced rearrangements. The macroscopic consequences are captured by a novel rheological method in which a step-strain is superposed on an otherwise steady flow