83 research outputs found
Unexpected drop of dynamical heterogeneities in colloidal suspensions approaching the jamming transition
As the glass (in molecular fluids\cite{Donth}) or the jamming (in colloids
and grains\cite{LiuNature1998}) transitions are approached, the dynamics slow
down dramatically with no marked structural changes. Dynamical heterogeneity
(DH) plays a crucial role: structural relaxation occurs through correlated
rearrangements of particle ``blobs'' of size
\cite{WeeksScience2000,DauchotPRL2005,Glotzer,Ediger}. On approaching
these transitions, grows in glass-formers\cite{Glotzer,Ediger},
colloids\cite{WeeksScience2000,BerthierScience2005}, and driven granular
materials\cite{KeysNaturePhys2007} alike, strengthening the analogies between
the glass and the jamming transitions. However, little is known yet on the
behavior of DH very close to dynamical arrest. Here, we measure in colloids the
maximum of a ``dynamical susceptibility'', , whose growth is usually
associated to that of \cite{LacevicPRE}. initially increases with
volume fraction , as in\cite{KeysNaturePhys2007}, but strikingly drops
dramatically very close to jamming. We show that this unexpected behavior
results from the competition between the growth of and the reduced
particle displacements associated with rearrangements in very dense
suspensions, unveiling a richer-than-expected scenario.Comment: 1st version originally submitted to Nature Physics. See the Nature
Physics website fro the final, published versio
Mars Regolith Simulant Ameliorated by Compost as In Situ Cultivation Substrate Improves Lettuce Growth and Nutritional Aspects
Heavy payloads in future shuttle journeys to Mars present limiting factors, making self-sustenance essential for future colonies. Therefore, in situ resources utilization (ISRU) is the path to successful and feasible space voyages. This research frames the concept of planting leafy vegetables on Mars regolith simulant, ameliorating this substrateâs fertility by the addition of organic residues produced in situ. For this purpose, two butterhead lettuce (Lactuca sativa L. var. capitata) cultivars (green and red SalanovaÂź) were chosen to be cultivated in four dierent mixtures of MMS-1 Mojave Mars simulant:compost (0:100, 30:70, 70:30 and 100:0; v:v) in a phytotron open gas exchange growth chamber. The impact of compost rate on both crop performance and the nutritive value of green- and red-pigmented cultivars was assessed. The 30:70 mixture proved to be optimal in terms of crop performance, photosynthetic activity, intrinsic water use eciency and quality traits of lettuce. In particular, red SalanovaÂź showed the best performance in terms of these quality traits, registering 32% more phenolic content in comparison to 100% simulant. Nonetheless, the 70:30 mixture represents a more realistic scenario when taking into consideration the sustainable use of compost as a limited resource in space farming, while still accepting a slight significant decline in yield and quality in comparison to the 30:70 mixture
Potentially toxic element availability and risk assessment of cadmium dietary exposure after repeated croppings of brassica juncea in a contaminated agricultural soil
Phytoextraction of potentially toxic elements (PTEs) is eco-friendly and cost-effective for remediating agricultural contaminated soils, but plants can only take up bioavailable forms of PTEs, thus meaning that bioavailability is the key for the feasibility of this technique. With the aims to assess the phytoextraction efficiency on an agricultural soil contaminated by Cr, Zn, Cd, and Pb and the changes induced by plants in PTE bioavailability and in human health risk due to dietary exposure, in this work we carried out a mesocosm experiment with three successive croppings of Brassica juncea, each followed by Rocket salad as bioindicator. Brassica juncea extracted more Zn and Cd than Cr and Pb, significantly reducing, after three repeated croppings, the bioavailable element concentrations in soil as a result of plant uptake and soil pH changes. For Cd, this reduction did not bring the bioavailable amounts obtained by soil extraction with NH4NO3 below the trigger value of 0.1 mg kgâ1 set by some European countries. Nevertheless, the Hazard Quotient for Cd in Rocket salad decreased across three repeated croppings of Brassica juncea. This indicated the beginning of a re-equilibration process between soil PTE forms of different bioavailability, that are in a dynamic equilibrium, thus stressing the need to monitor the possible regeneration of the most readily bioavailable pool
On the rigidity of a hard sphere glass near random close packing
We study theoretically and numerically the microscopic cause of the
mechanical stability of hard sphere glasses near their maximum packing. We show
that, after coarse-graining over time, the hard sphere interaction can be
described by an effective potential which is exactly logarithmic at the random
close packing . This allows to define normal modes, and to apply recent
results valid for elastic networks: mechanical stability is a non-local
property of the packing geometry, and is characterized by some length scale
which diverges at [1, 2]. We compute the scaling of the bulk and
shear moduli near , and speculate on the possible implications of these
results for the glass transition.Comment: 7 pages, 4 figures. Figure 4 had a wrong unit in abscissa, which was
correcte
The effect of novel biodegradable films on agronomic performance of zucchini squash grown under open-field and greenhouse conditions
The soil mulching is an important agricultural practice for increasing crop productivity and earliness. Mulching can be made with natural or synthetic materials. The common films being used these days are usually made of low density polyethylene (LDPE), but its disposal can represent a serious environmental and economic problem. The biodegradable mulching can overcome these problems. Two experiments were carried out comparing the effects of biodegradable and LDPE mulching films on yield and quality of zucchini (Cucurbita pepo L.) grown in two environments (open-field vs. greenhouse). In both the environments a randomized complete block design was adopted. The treatments composed of no-mulched crop (control), soil covered by 15 microns black biodegradable film (MB15) and soil covered by 50 microns black LDPE film. The results showed that MB15 was able to maintain discrete technical proprieties until the end of cycle, especially in greenhouse, assuring a sufficient heating of soil, similar to LDPE. The soil heating promoted crop development. Furthermore, earliness was increased (84 in greenhouse vs. 99 days in open air) in greenhouse. The early production of zucchini grown on MB15 was similar to the one in LDPE production in greenhouse. The total marketable yield of plants grown on both films was not different but it was lower in open air. The biodegradable film significantly improved fruits quality, with higher values of firmness and total soluble solid than fruits grown on LDPE
Heterogeneous Dynamics, Marginal Stability and Soft Modes in Hard Sphere Glasses
In a recent publication we established an analogy between the free energy of
a hard sphere system and the energy of an elastic network [1]. This result
enables one to study the free energy landscape of hard spheres, in particular
to define normal modes. In this Letter we use these tools to analyze the
activated transitions between meta-bassins, both in the aging regime deep in
the glass phase and near the glass transition. We observe numerically that
structural relaxation occurs mostly along a very small number of
nearly-unstable extended modes. This number decays for denser packing and is
significantly lowered as the system undergoes the glass transition. This
observation supports that structural relaxation and marginal modes share common
properties. In particular theoretical results [2, 3] show that these modes
extend at least on some length scale where
corresponds to the maximum packing fraction, i.e. the jamming
transition. This prediction is consistent with very recent numerical
observations of sheared systems near the jamming threshold [4], where a similar
exponent is found, and with the commonly observed growth of the rearranging
regions with compression near the glass transition.Comment: 6 pages, improved versio
Sweet basil functional quality as shaped by genotype and macronutrient concentration reciprocal action
Basil (Ocimum basilicum L.) is among the most widespread aromatic plants due to its versatility of use and its beneficial health properties. This aromatic plant thrives in hydroponics, which is a valid tool to improve the production and functional quality of crops, but nevertheless, it offers the possibility to de-seasonalize production. A floating raft system was adopted to test the production and quality potential during autumn season of three different genotypes of Genovese basil (Aroma 2, Eleonora and Italiano Classico) grown in three nutrient solutions with crescent electrical conductivity (EC: 1, 2 and 3 dS mâ1). The aromatic and phenolic profiles were determined by GC/MS and HPLC analysis, respectively. The combination Aroma 2 and the EC 2 dS mâ1 resulted in the highest production, both in terms of fresh weight and dry biomass. The 2 dS mâ1 treatment determined the major phenolic content, 44%, compared to the other two EC. Italiano Classico showed a higher total polyphenolic content in addition to a different aromatic profile compared to the other cultivars, characterized by a higher percentage of Eucalyptol (+37%) and Eugenol (+107%) and a lower percentage of linalool (â44%). Correct management of the nutritional solution combined with adequate genetic material managed an improvement in the production and the obtainment of the desired aromatic and phenolic profiles
Dynamic heterogeneities in attractive colloids
We study the formation of a colloidal gel by means of Molecular Dynamics
simulations of a model for colloidal suspensions. A slowing down with gel-like
features is observed at low temperatures and low volume fractions, due to the
formation of persistent structures. We show that at low volume fraction the
dynamic susceptibility, which describes dynamic heterogeneities, exhibits a
large plateau, dominated by clusters of long living bonds. At higher volume
fraction, where the effect of the crowding of the particles starts to be
present, it crosses over towards a regime characterized by a peak. We introduce
a suitable mean cluster size of clusters of monomers connected by "persistent"
bonds which well describes the dynamic susceptibility.Comment: 4 pages, 4 figure
Non-equilibrium dynamics of spin facilitated glass models
We consider the dynamics of spin facilitated models of glasses in the
non-equilibrium aging regime following a sudden quench from high to low
temperatures. We briefly review known results obtained for the broad class of
kinetically constrained models, and then present new results for the behaviour
of the one-spin facilitated Fredrickson-Andersen and East models in various
spatial dimensions. The time evolution of one-time quantities, such as the
energy density, and the detailed properties of two-time correlation and
response functions are studied using a combination of theoretical approaches,
including exact mappings of master operators and reductions to integrable
quantum spin chains, field theory and renormalization group, and independent
interval and timescale separation methods. The resulting analytical predictions
are confirmed by means of detailed numerical simulations. The models we
consider are characterized by trivial static properties, with no finite
temperature singularities, but they nevertheless display a surprising variety
of dynamic behaviour during aging, which can be directly related to the
existence and growth in time of dynamic lengthscales. Well-behaved
fluctuation-dissipation ratios can be defined for these models, and we study
their properties in detail. We confirm in particular the existence of negative
fluctuation-dissipation ratios for a large number of observables. Our results
suggest that well-defined violations of fluctuation-dissipation relations, of a
purely dynamic origin and unrelated to the thermodynamic concept of effective
temperatures, could in general be present in non-equilibrium glassy materials.Comment: 72 pages, invited contribution to special issue of JSTAT on
"Principles of Dynamics of Nonequilibrium Systems" (Programme at Newton
Institute Cambridge). v2: New data added to Figs. 11, 23, 24, new Fig. 26 on
East model in d=3, minor improvements to tex
Fluctuations in glassy systems
We summarize a theoretical framework based on global time-reparametrization
invariance that explains the origin of dynamic fluctuations in glassy systems.
We introduce the main ideas without getting into much technical details. We
describe a number of consequences arising from this scenario that can be tested
numerically and experimentally distinguishing those that can also be explained
by other mechanisms from the ones that we believe, are special to our proposal.
We support our claims by presenting some numerical checks performed on the 3d
Edwards-Anderson spin-glass. Finally, we discuss up to which extent these ideas
apply to super-cooled liquids that have been studied in much more detail up to
present.Comment: 33 pages, 7 figs, contribution to JSTAT special issue `Principles of
Dynamical Systems' work-shop at Newton Institute, Univ. of Cambridge, U
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