1,693 research outputs found
Few layer graphene on SiC, pyrolitic graphite and graphene: a Raman scattering study
The results of micro-Raman scattering measurements performed on three
different ``graphitic'' materials: micro-structured disks of highly oriented
pyrolytic graphite, graphene multi-layers thermally decomposed from carbon
terminated surface of 4H-SiC and an exfoliated graphene monolayer are
presented. Despite its multi-layer character, most parts of the surface of the
graphitized SiC substrates shows a single-component, Lorentzian shape, double
resonance Raman feature in striking similarity to the case of a single graphene
monolayer. Our observation suggests a very weak electronic coupling between
graphitic layers on the SiC surface, which therefore can be considered to be
graphene multi-layers with a simple (Dirac-like) band structure.Comment: 4 pages, 3 Figures Structure of the paper strongly modified, small
changes in Fig 2 and 3. Same interpretation and same result
Circular dichroism of magneto-phonon resonance in doped graphene
Polarization resolved, Raman scattering response due to E phonon in
monolayer graphene has been investigated in magnetic fields up to 29 T. The
hybridization of the E phonon with only the fundamental inter Landau
level excitation (involving the n=0 Landau level) is observed and only in one
of the two configurations of the circularly crossed polarized excitation and
scattered light. This polarization anisotropy of the magneto-phonon resonance
is shown to be inherent to relatively strongly doped graphene samples, with
carrier concentration typical for graphene deposited on SiO
Modeling trade-offs across carbon sequestration, biodiversity conservation, and equity in the distribution of global REDD+ funds
The program on Reducing Emissions from Deforestation and Forest Degradation (REDD+) is one of the major attempts to tackle climate change mitigation in developing countries. REDD+ seeks to provide result-based incentives to promote emission reductions and increase carbon sinks in forest land while promoting other cobenefits, such as the conservation of biodiversity. We model different scenarios of international REDD+ funds distribution toward potential recipient countries using 2 carbon emission reduction targets (20% and 50% compared to the baseline scenario, i.e., deforestation and forest degradation without REDD+) by 2030. The model combines the prioritization of environmental outcomes in terms of carbon sequestration and biodiversity conservation and social equity, accounting for the equitable distribution of international REDD+ funds. Results highlight the synergy between carbon sequestration and biodiversity conservation under alternative fund allocation criteria, especially for scenarios of low carbon emission reduction. Trade-offs increase when distributional equity is considered as an additional criterion, especially under higher equity requirements. The analysis helps to better understand the inherent trade-offs between enhancing distributional equity and meeting environmental targets under alternative REDD+ fund allocation options. (c) 2019 National Academy of Sciences. All rights reserved.I.P. is supported by a grant by the Spanish Ministry of Economy and Competitiveness (IJCI-2016–28475). I.P., U.P., and M.J.S. are supported under the Basque Centre for Climate Change “Unit of Excellence” (Spanish Ministry of Economy and Competitiveness; MDM-2017-0714)
Role of dynein, dynactin, and CLIP-170 interactions in LIS1 kinetochore function
Mutations in the human LIS1 gene cause type I lissencephaly, a severe brain developmental disease involving gross disorganization of cortical neurons. In lower eukaryotes, LIS1 participates in cytoplasmic dynein-mediated nuclear migration. We previously reported that mammalian LIS1 functions in cell division and coimmunoprecipitates with cytoplasmic dynein and dynactin. We also localized LIS1 to the cell cortex and kinetochores of mitotic cells, known sites of dynein action. We now find that the COOH-terminal WD repeat region of LIS1 is sufficient for kinetochore targeting. Overexpression of this domain or full-length LIS1 displaces CLIP-170 from this site without affecting dynein and other kinetochore markers. The NH2-terminal self-association domain of LIS1 displaces endogenous LIS1 from the kinetochore, with no effect on CLIP-170, dynein, and dynactin. Displacement of the latter proteins by dynamitin overexpression, however, removes LIS1, suggesting that LIS1 binds to the kinetochore through the motor protein complexes and may interact with them directly. We find that of 12 distinct dynein and dynactin subunits, the dynein heavy and intermediate chains, as well as dynamitin, interact with the WD repeat region of LIS1 in coexpression/coimmunoprecipitation and two-hybrid assays. Within the heavy chain, interactions are with the first AAA repeat, a site strongly implicated in motor function, and the NH2-terminal cargo-binding region. Together, our data suggest a novel role for LIS1 in mediating CLIP-170–dynein interactions and in coordinating dynein cargo-binding and motor activities
Autocorrelation analysis for the unbiased determination of power-law exponents in single-quantum-dot blinking
We present an unbiased and robust analysis method for power-law blinking
statistics in the photoluminescence of single nano-emitters, allowing us to
extract both the bright- and dark-state power-law exponents from the emitters'
intensity autocorrelation functions. As opposed to the widely-used threshold
method, our technique therefore does not require discriminating the emission
levels of bright and dark states in the experimental intensity timetraces. We
rely on the simultaneous recording of 450 emission timetraces of single
CdSe/CdS core/shell quantum dots at a frame rate of 250 Hz with single photon
sensitivity. Under these conditions, our approach can determine ON and OFF
power-law exponents with a precision of 3% from a comparison to numerical
simulations, even for shot-noise-dominated emission signals with an average
intensity below 1 photon per frame and per quantum dot. These capabilities pave
the way for the unbiased, threshold-free determination of blinking power-law
exponents at the micro-second timescale
Fluorescent oxide nanoparticles adapted to active tips for near-field optics
We present a new kind of fluorescent oxide nanoparticles with properties well
suited to active-tip based near-field optics. These particles with an average
diameter in the range 5-10 nm are produced by Low Energy Cluster Beam
Deposition (LECBD) from a YAG:Ce3+ target. They are studied by transmission
electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), classical
photoluminescence, cathodoluminescence and near-field scanning optical
microscopy (NSOM). Particles of extreme photo-stability as small as 10 nm in
size are observed. These emitters are validated as building blocks of active
NSOM tips by coating a standard optical tip with a 10 nm thick layer of
YAG:Ce3+ particles directly in the LECBD reactor and by subsequently performing
NSOM imaging of test surfaces.Comment: Changes made following Referee's comments; added references; one
added figure. See story on this article at:
http://nanotechweb.org/cws/article/tech/3606
Overbias Light Emission From Memristive Nanojunctions
A nanoscale dielectric gap clamped between two metal electrodes may undergo a
large resistance change from insulating to highly conducting upon applying an
electrical stress. This sudden resistive switching effect is largely exploited
in memristors for emulating synapses in neuromorphic neural networks. Here, we
show that resistive switching can be accompanied by a release of
electromagnetic radiation spanning the visible spectral region. Importantly, we
find that the spectrum is characterized by photon energies exceeding the
maximum kinetic energy of electrons provided by the switching voltage. This
so-called overbias emission can be described self-consistently by a thermal
radiation model featuring an out-of-equilibrium electron distribution generated
in the device with an effective temperature exceeding 2000~K. The emitted
spectrum is understood in terms of hot electrons radiatively decaying to
resonant optical modes occurring in a nanoscale \ch{SiO2} matrix located
between two \ch{Ag} electrodes. The correlation between resistive switching and
the onset of overbias emission in atomic-scale photonic memristor brings new
venues to generate light on chip and their exploitation in optical
interconnects. Photons emitted during memristive switching can also be
monitored to follow the neural activation pathways in memristor-based networks
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