17,506 research outputs found
On the distribution of high-frequency stock market traded volume: a dynamical scenario
This manuscript reports a stochastic dynamical scenario whose associated
stationary probability density function is exactly a previously proposed one to
adjust high-frequency traded volume distributions. This dynamical conjecture,
physically connected to superstatiscs, which is intimately related with the
current nonextensive statistical mechanics framework, is based on the idea of
local fluctuations in the mean traded volume associated to financial markets
agents herding behaviour. The corroboration of this mesoscopic model is done by
modelising NASDAQ 1 and 2 minute stock market traded volume
Liquid mixtures involving fluorinated alcohols: The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol) Experimental and Simulation
Liquid mixtures involving fluorinated alcohols:
The equation of state (p, r, T, x) of (Ethanol + Trifluoroethanol)
Experimental and Simulation
Pedro Duartea, Djêide Rodriguesa, Marcelo Silvaa, Pedro Morgadoa,
Luís Martinsa,b and Eduardo J. M. Filipea*
aCentro de Química Estrutural, Instituto Superior Técnico, 1049-001 Lisboa, Portugal
bCentro de Química de Évora, Universidade de Évora, 7000-671 Évora, Portugal
Fluorinated alcohols are substances with unique properties and high technological value in the pharmaceutical and chemical industries. Trifluoroethanol (TFE), in particular, displays a number of unusual properties as a solvent. For example, it dissolves nylon at room temperature and is effectively used as solvent in bioengineering. The presence of the three fluorines atoms gives the alcohol a high ionization constant, strong hydrogen bonding capability and stability at high temperatures.
In the pharmaceutical industry, TFE finds use as the major raw material for the production of inhalation anesthetics. Mixtures of TFE and water (known as Fluorinols®) are used as working fluids for Rankine cycle heat engines for terrestrial and space applications, as a result of a unique combination of physical and thermodynamic properties such as high thermal efficiency and excellent turbine expansion characteristics.
Environmentally, TFE is a CFC substitute with an acceptable short lifetime and with small ozone depletion potential. Additionally, TFE is known to induce conformational changes in proteins and it is used as a co-solvent to analyze structural features of partially folded states.
The (ethanol + TFE) system displays an interesting and peculiar behaviour, combining a negative azeotrope with high positive excess volumes.
In this work, liquid mixtures of (ethanol + TFE) were investigated. The densities of the mixtures were measured as a function of composition between 278K and 338K and at pressures up to 700 bar. The corresponding excess volumes as a function of temperature and pressure, the isothermal compressibilities and thermal expansivities were calculated from the experimental results. The mixtures are highly non-ideal with excess volumes ranging from 0.8 - 1.0 cm3mol-1.
Finally, molecular dynamic simulations were performed to model and interpret the experimental results. The Trappe force field was used to simulate the (TFE + ethanol) mixtures and calculate the corresponding excess volumes. The simulation results are able to reproduce the correct sign and order of magnitude of the experimental VE without fitting to the experimental data. Furthermore, the simulations suggest the presence of a particular type of hydrogen bridge between ethanol and TFE, that can help to rationalize the experimental results
A unification in the theory of linearization of second order nonlinear ordinary differential equations
In this letter, we introduce a new generalized linearizing transformation
(GLT) for second order nonlinear ordinary differential equations (SNODEs). The
well known invertible point (IPT) and non-point transformations (NPT) can be
derived as sub-cases of the GLT. A wider class of nonlinear ODEs that cannot be
linearized through NPT and IPT can be linearized by this GLT. We also
illustrate how to construct GLTs and to identify the form of the linearizable
equations and propose a procedure to derive the general solution from this GLT
for the SNODEs. We demonstrate the theory with two examples which are of
contemporary interest.Comment: 8 page
The role of human resources on the economy: a study of the Balkan eu member states
In this paper we analyze the impact of the quality of human capital on the main economic indicators of South-Eastern Europe countries [SEE] at the NUTS 2 level. The subjects of this research are the human capital indicators of regional competitiveness. The quality of human capital depends largely on the age structure of the population and the quality of education. Those regions, which have the highest percentage of the working-age population and highly educated people, are able to achieve higher productivity and gain a competitive advantage over other regions. As main indicators of the quality of human capital we identified: population; persons aged 25-64 with tertiary education attainment; students in tertiary education and participation of adults aged 25-64 in education and training and human resources in science and technology. As main economic indicators, we identified: regional gross domestic product; employment and income of households. The aim of this paper is to determine whether there is a correlation between the indicators of the quality of human capital and economic indicators. As a main methodology we have used the correlation coefficient which shows interdependence of the analyzed indicators. As part of our analysis, we consider only EU member states that belong to the SEE countries: Slovenia, Croatia, Romania, Bulgaria and Greece. We conclude that in all countries there is a high multiple correlation coefficient between the indicators human resources in science and technology, number of students and employment.This paper is the result of the project No. 47007 III funded by the Ministry for Education, Science and Technological Development of Republic of Serbia
Solving 1ODEs with functions
Here we present a new approach to deal with first order ordinary differential
equations (1ODEs), presenting functions. This method is an alternative to the
one we have presented in [1]. In [2], we have establish the theoretical
background to deal, in the extended Prelle-Singer approach context, with
systems of 1ODEs. In this present paper, we will apply these results in order
to produce a method that is more efficient in a great number of cases.
Directly, the solving of 1ODEs is applicable to any problem presenting
parameters to which the rate of change is related to the parameter itself.
Apart from that, the solving of 1ODEs can be a part of larger mathematical
processes vital to dealing with many problems.Comment: 31 page
Spectral stability of Markov systems
For a class of semigroups of stochastic dynamical systems,
, where denotes a state and the
state probability transition,
we relate its spectral stability with the combinatorial
stability of the underlying non-deterministic dynamics,
associated to the point-set map
Combinatorial stability of non-deterministic systems
We introduce and study, from a combinatorial-topological viewpoint, some semigroups of continuous non-deterministic dynamical systems. Combinatorial stability, i.e. the persistence of the combinatorics of the attractors, is characterized and its genericity established.
Some implications on topological (deterministic) dynamics are drawn
Axial gravity, massless fermions and trace anomalies
This article deals with two main topics. One is odd parity trace anomalies in
Weyl fermion theories in a 4d curved background, the second is the introduction
of axial gravity. The motivation for reconsidering the former is to clarify the
theoretical background underlying the approach and complete the calculation of
the anomaly. The reference is in particular to the difference between Weyl and
massless Majorana fermions and to the possible contributions from tadpole and
seagull terms in the Feynman diagram approach. A first, basic, result of this
paper is that a more thorough treatment, taking account of such additional
terms { and using dimensional regularization}, confirms the earlier result. The
introduction of an axial symmetric tensor besides the usual gravitational
metric is instrumental to a different derivation of the same result using Dirac
fermions, which are coupled not only to the usual metric but also to the
additional axial tensor. The action of Majorana and Weyl fermions can be
obtained in two different limits of such a general configuration. The results
obtained in this way confirm the previously obtained ones.Comment: 55 pages, comments added in section 2 and 5. Sections 6.4, 6.6, 7,
7.1, 7.2 and Appendices 5.3, 5.5 partially modifie
A Method to Tackle First Order Differential Equations with Liouvillian Functions in the Solution - II
We present a semi-decision procedure to tackle first order differential
equations, with Liouvillian functions in the solution (LFOODEs). As in the case
of the Prelle-Singer procedure, this method is based on the knowledge of the
integrating factor structure.Comment: 11 pages, late
- …