Pressure dependence of Raman modes in double wall carbon nanotubes filled with α-Fe.

The preparation of highly anisotropic one-dimensional (1D) structures confined into carbon nanotubes (CNTs) in general is a key objective in CNTs research. In this work, the capillary effect was used to fill double wall carbon nanotubes with iron. The samples are characterized by Mössbauer and Raman spectroscopy, transmission electron microscopy, scanning area electron diffraction, and magnetization. In order to investigate their structural stability and compare it with that of single wall carbon nanotubes (SWNTs), elucidating the differences induced by the inner-outer tube interaction, unpolarized Raman spectra of tangential modes of double wall carbon nanotubes (DWNTs) filled with 1D nanocrystallin α-Fe excited with 514 nm were studied at room temperature and elevated pressure. Up to 16 GPa we find a pressure coefficient for the internal tube of 4.3 cm−1 GPa−1 and for the external tube of 5.5 cm−1 GPa−1. In addition, the tangential band of the external and internal tubes broadens and decreases in amplitude. All findings lead to the conclusion that the outer tube acts as a protection shield for the inner tubes (at least up 16 GPa). Structural phase transitions were not observed in this range of pressure

Group theory: Application to the physics of condensed matter

Every process in physics is governed by selection rules that are the consequence of symmetry requirements. The beauty and strength of group theory resides in the transformation of many complex symmetry operations into a very simple linear algebra. This concise and class-tested book has been pedagogically tailored over 30 years MIT and 2 years at the University Federal of Minas Gerais (UFMG) in Brazil. The approach centers on the conviction that teaching group theory in close connection with applications helps students to learn, understand and use it for their own needs. For this reason, the theoretical background is confined to the first 4 introductory chapters (6-8 classroom hours). From there, each chapter develops new theory while introducing applications so that the students can best retain new concepts, build on concepts learned the previous week, and see interrelations between topics as presented. Essential problem sets between the chapters also aid the retention of the new material and for the consolidation of material learned in previous chapters. The text and problem sets have proved a useful springboard for the application of the basic material presented here to topics in semiconductor physics, and the physics of carbon-based nanostructures

Purification, functionalization, and bioconjugation of carbon nanotubes.

Bioconjugation of carbon nanotubes (CNTs) with biomolecules promises exciting applications such as biosensing, nanobiocomposite formulation, design of drug vector systems, and probing protein interactions. Pristine CNTs, however, are virtually water-insoluble and difficult to evenly disperse in a liquid matrix. Therefore, it is necessary to attach molecules or functional groups to their sidewalls to enable bioconjugation. Both noncovalent and covalent procedures can be used to conjugate CNTs with a target biomolecule for a specific bioapplication. This chapter presents a few selected protocols that can be performed at any wet chemistry laboratory to purify and biofunctionalize CNTs. The preparation of CNTs modified with metallic nanoparticles, especially gold, is also described since biomolecules can bind and self-organize on the surfaces of such metal-decorated CNTs.Peer reviewed: YesNRC publication: Ye