1 research outputs found
Novel Synthesis of CuâSchiff Base Complex@MetalâOrganic Framework MILâ101âvia a Mild Method: A Comparative Study for Rapid Catalytic Effects
Abstract The use of metal complex immobilized/decorated porous materials as catalysts has found various applications. As such, finding a new and mild method for synthesis of metal complex immobilized over porous material is of great interest. Immobilized porous materials for styrene oxidation were reported in this work. Immobilized porous material of CuâSchiff base complex @MILâ101 were described, in which immobilized CuâSchiff base complex within super cage of a metalâorganic framework (MOF)âbased porous material, chromium (III) terephthalate MILâ101. They were systematically characterized by using elemental analysis, powder Xâray diffraction, fourier transform infrared spectroscopy, N2 absorptionâdesorption, and so on, also used as catalyst for the selective oxidation of styrene to benzaldehyde. Comparatively, the immobilized heterogeneous catalyst of CuâSchiff base complex@MILâ101 acted as an efficient heterostructure catalyst in the oxidation of styrene to benzaldehyde up to six cycles, and showed superior activity for styrene oxidation over MILâ101