Fabrication of Nonenzymatic Glucose Sensors Based on Multiwalled Carbon Nanotubes with Bimetallic Pt-M (M = Ru and Sn) Catalysts by Radiolytic Deposition

Nonenzymatic glucose sensors employing multiwalled carbon nanotubes (MWNTs) with highly dispersed Pt-M (M = Ru and Sn) nanoparticles (Pt-M@PVP-MWNTs) were fabricated by radiolytic deposition. The Pt-M nanoparticles on the MWNTs were characterized by transmittance electron microscopy, elemental analysis, and X-ray diffraction. They were found to be well dispersed and to exhibit alloy properties on the MWNT support. Electrochemical testing showed that these nonenzymatic sensors had larger currents (mA) than that of a bare glassy carbon (GC) electrode and one modified with MWNTs. The sensitivity (A mM−1), linear range (mM), and detection limit (mM) (S/N = 3) of the glucose sensor with the Pt-Ru catalyst in NaOH electrolyte were determined as 18.0, 1.0–2.5, 0.7, respectively. The corresponding data of the sensor with Pt-Sn catalyst were 889.0, 1.00–3.00, and 0.3, respectively. In addition, these non-enzymatic sensors can effectively avoid interference arising from the oxidation of the common interfering species ascorbic acid and uric acid in NaOH electrolyte. The experimental results show that such sensors can be applied in the detection of glucose in commercial red wine samples

SYNGAS PRODUCTION WITH A DUAL FLUIDIZED BED GASIFIER FOR POLYGENERATION

A pilot scale dual fluidized bed gasification system was developed for polygeneration with biomass. The gasification system is designed for supplying syngas for Fischer Tropsch (F-T) synthesis of bio-diesel and power generation with a syngas engine. Characteristics of biomass steam gasification were investigated in a lab scale bubbling fluidized bed, and hydrodynamics of a dual fluidized bed were investigated in a cold flow model. Based on the results from the lab scale test and cold flow model, a pilot scale dual fluidized bed gasifier was designed. In this paper, the developing process of the gasifier and preliminary results of system operation will be presented

Relationship between the stratospheric quasi-biennial oscillation and the spring rainfall in the western North Pacific

©2013. American Geophysical Union. All Rights Reserved.The effects of the stratospheric quasi-biennial oscillation (QBO) on spring rainfall in the western North Pacific (WNP) are investigated using observational and reanalysis data for 1979-2012. After excluding the strong El Nino-Southern Oscillation events, composite analyses between opposite phases of the QBO are applied to the rainfall and related meteorological fields to show the differences in each QBO phase. In comparison with the easterly phase, during the westerly QBO, a midlatitude spring rainband extending from southeastern China to the east of the Japanese Islands is displaced southward, and thus, the spring rainfall over Korea and Japan exhibits a significant decrease. Such changes in the spring WNP rainfall are related to the location and intensity of the WNP subtropical high (WNPSH) and the East Asian jet (EAJ). The possible role of the QBO in modulating the WNPSH and the EAJ is discussed with regard to the strength of the Hadley circulation.OAIID:oai:osos.snu.ac.kr:snu2013-01/102/0000002478/1SEQ:1PERF_CD:SNU2013-01EVAL_ITEM_CD:102USER_ID:0000002478ADJUST_YN:YEMP_ID:A004842DEPT_CD:3345CITE_RATE:4.456DEPT_NM:지구환경과학부SCOPUS_YN:NCONFIRM:

The MR imaging diagnosis of liver diseases using gadoxetic acid: Emphasis on hepatobiliary phase

Hepatocyte specific contrast agents including gadoxetic acid and gadobenate dimeglumine are very useful to diagnose various benign and malignant focal hepatic lesions and even helpful to estimate hepatic functional reservoir. The far delayed phase image referred to as the hepatobiliary phase makes the sensitivity of detection for malignant focal hepatic lesions increased, but specificity of malignant diseases, including hepatocellular carcinoma, metastasis and cholangiocarcinoma, characterization remained to be undetermined

A childhood case of spinal tuberculosis misdiagnosed as muscular dystrophy

Tuberculosis is primarily a pulmonary disease, but extra-pulmonary manifestations are not uncommon, especially in children and adolescents. Ten percent of extra pulmonary tuberculosis localizes to the bones and joints, and 56% of such cases affect the spine. We treated a childhood case of spinal tuberculosis misdiagnosed as muscular dystrophy in a patient without specific constitutional symptoms. We report this case because the patient had an unusual presentation of spinal tuberculosis