163 research outputs found
The d 1Πg(v=1) Rydberg state of O2: Optical-optical double-resonance and Huggins-band ozone-photolysis, resonance-enhanced multiphoton-ionization studies with a b 1Σ+g(v=0)-state platform
The d←←b(1,0) band of O2 following Huggins-band photolysis of O3 was explored. Analyses of these REMPI spectra yield, not only the first information on d(v=1) rotational levels with J>29, but also the first estimate of an O2(b-state fragment rotation
Observation of completely destructive quantum interference between interacting resonances in molecular predissociation
Predissociating resonances were observed for destructive interference in a region between the resonances. Multiphoton ionization spectroscopy which was enhanced by resonance was used for probing single rotational levels of O2 in case of double resonance technique. Double resonance technique resulted in the elimination of overlapping rotational structure
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