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Energy-efficient CO2 hydrogenation with fast response using photoexcitation of CO2 adsorbed on metal catalysts.
Many heterogeneous catalytic reactions occur at high temperatures, which may cause large energy costs, poor safety, and thermal degradation of catalysts. Here, we propose a light-assisted surface reaction, which catalyze the surface reaction using both light and heat as an energy source. Conventional metal catalysts such as ruthenium, rhodium, platinum, nickel, and copper were tested for CO2 hydrogenation, and ruthenium showed the most distinct change upon light irradiation. CO2 was strongly adsorbed onto ruthenium surface, forming hybrid orbitals. The band gap energy was reduced significantly upon hybridization, enhancing CO2 dissociation. The light-assisted CO2 hydrogenation used only 37% of the total energy with which the CO2 hydrogenation occurred using only thermal energy. The CO2 conversion could be turned on and off completely with a response time of only 3 min, whereas conventional thermal reaction required hours. These unique features can be potentially used for on-demand fuel production with minimal energy input
Singlet Fermionic Dark Matter with Dark
We present a fermionic dark matter model mediated by the hidden gauge boson.
We assume the QED-like hidden sector which consists of a Dirac fermion and
U(1) gauge symmetry, and introduce an additional scalar electroweak doublet
field with the U(1) charge as a mediator. The hidden U(1) symmetry is
spontaneously broken by the electroweak symmetry breaking and there exists a
massive extra neutral gauge boson in this model which is the mediator between
the hidden and visible sectors. Due to the U(1) charge, the additional
scalar doublet does not couple to the Standard Model fermions, which leads to
the Higgs sector of type I two Higgs doublet model. The new gauge boson couples
to the Standard Model fermions with couplings proportional to those of the
ordinary boson but very suppressed, thus we call it the dark boson. We
study the phenomenology of the dark boson and the Higgs sector, and show
the hidden fermion can be the dark matter candidate.Comment: 10 pages, 3 figure
An Empirical Examination of Consumer Behavior for Search and Experience Goods in Sentiment Analysis
With the explosive increase of user-generated content such as product reviews and social media, sentiment analysis has emerged as an area of interest. Sentiment analysis is a useful method to analyze product reviews, and product feature extraction is an important task in sentiment analysis, during which one identifies features of products from reviews. Product features are categorized by product type, such as search goods or experience goods, and their characteristics are totally different. Thus, we examine whether the classification performance differs by product type. The findings show that the optimal threshold varies by product type, and simply decreasing the threshold to cover many features does not guarantee improvement of the classification performance
Improving Generalization of Drowsiness State Classification by Domain-Specific Normalization
Abnormal driver states, particularly have been major concerns for road
safety, emphasizing the importance of accurate drowsiness detection to prevent
accidents. Electroencephalogram (EEG) signals are recognized for their
effectiveness in monitoring a driver's mental state by monitoring brain
activities. However, the challenge lies in the requirement for prior
calibration due to the variation of EEG signals among and within individuals.
The necessity of calibration has made the brain-computer interface (BCI) less
accessible. We propose a practical generalized framework for classifying driver
drowsiness states to improve accessibility and convenience. We separate the
normalization process for each driver, treating them as individual domains. The
goal of developing a general model is similar to that of domain generalization.
The framework considers the statistics of each domain separately since they
vary among domains. We experimented with various normalization methods to
enhance the ability to generalize across subjects, i.e. the model's
generalization performance of unseen domains. The experiments showed that
applying individual domain-specific normalization yielded an outstanding
improvement in generalizability. Furthermore, our framework demonstrates the
potential and accessibility by removing the need for calibration in BCI
applications.Comment: Submitted to 2024 12th IEEE International Winter Conference on
Brain-Computer Interfac
Effects of nanofluids containing graphene/graphene-oxide nanosheets on critical heat flux
The superb thermal conduction property of graphene establishes graphene as an excellent material for thermal management. In this paper, we selected graphene/graphene oxide nanosheets as the additives in nanofluids. The authors interestingly found that the highly enhanced critical heat flux (CHF) in the nanofluids containing graphene/graphene-oxide nanosheets (GON) cannot be explained by both the improved surface wettability and the capillarity of the nanoparticles deposition layer. Here we highlights that the GON nanofluid can be exploited to maximize the CHF the most efficiently by building up a characteristically ordered porous surface structure due to its own self-assembly characteristic resulting in a geometrically changed critical instability wavelength.open363
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