30 research outputs found
Enhancement of Photoemission on P-type GaAs using Surface Acoustic Waves
We demonstrate that photoemission properties of GaAs photocathodes (PCs) can
be altered by surface acoustic waves (SAWs) generated on the PC surface due to
dynamical piezoelectric fields of SAWs. Simulations with COMSOL indicate that
electron effective lifetime in p-doped GaAs may increase by a factor of 10x to
20x. It implies a significant, by a factor of 2x to 3x, increase of quantum
efficiency (QE) for GaAs PCs. Essential steps in device fabrication are
demonstrated, including deposition of an additional layer of ZnO for
piezoelectric effect enhancement, measurements of I-V characteristic of the SAW
device, and ability to survive high-temperature annealing.Comment: 5 pages, 4 figure
Simulation of a Nano Plasmonic Pillar-Based Optical Sensor with AI-Assisted Signal Processing
Introduction
With the development of nanofabrication technologies, an increasing effort has been placed on plasmonic sensors [1,2]. Plasmonic sensors are based on surface plasmon resonance (SPR) or localized surface plasmon resonance (LSPR) [1-3]. When the target analytes bond to the functionalized material and altered the local refractive index, the resonance wavelength shifts due to the change of the local refractive index. Many types of plasmonic sensors have been studied and developed for chemical sensing or biochemical sensing applications in the last decade. There are two main challenges for chemical and biochemical sensing, i.e., sensitivity and specificity, especially when working in sensing applications in a complex background such as environmental monitoring, breath analysis, hazard tracing, etc.[1,3,4]. Besides, the development of artificial intelligence and machine learning technology provides the feasibility to correlate sensor responses to multiple parameters[4]. In this work, we report a novel plasmonic sensing platform with enhanced sensitivity and an AI-assisted signal processing algorithm to improve the specificity of plasmonic sensors.
Sensor Simulation
To achieve higher sensitivity and a broader range of detection. We have theoretically studied and simulated a sensing platform, namely, nano plasmonic pillars (NPP) (Figure 1). SiO2 nanopillars with a diameter of 100 nm are coated with a 20 nm-thick gold layer. The nanopillars are hexagonally displaced with a displacement of 300 nm. The Au-coated nanopillar has an interface between metal (Au) and insulators (SiO2) along the nanopillars' whole surface area. This structure will generate localized surface plasmon resonance (LSPR) along the nanopillars and improve the sensitivity due to the large effective surface area. The parameters, i.e., size, material, and displacement of the nanopillars, are simulated and optimized using finite element analysis. Figure 2 compares the simulated wavelength shift of the Au-coated SiO2 pillars and the ones of solid Au pillars when the local refractive index changes from 1.0 to 1.05. It is shown that the sensitivity (slope of the fitted function) of the simulated design is 2.90 times higher than the solid pillar.
AI-Assisted Signal Processing
One advantage of plasmonic sensors is that the sensor response can be captured by CMOS cameras. In this way, the wavelength shift caused by the analytes can be monitored as a color change of the captured image. With the rapid development of machine learning technology, convolutional neural networks have become a robust tool to help process the sensor signals. In this work, we developed a convolutional neural network-based algorithm that can successfully predict the local refractive index based on the simulated wavelength. Figure 3 shows the signal processing method applied in this work. First, the transmission spectra of the NPP with refractive indices of 1.0, 1.01, 1.02, 1.03, 1.04, and 1.05 are simulated. The spectra have dual peaks located in the visible wavelength due to the specifically designed plasmonic features (Figure 1). Second, approximate RGB values are calculated based on the spectra following Plank's law. A random integer (from -3 to 3) was added to the calculated RGB as random noise. Over 5,000 images (64x64 pixels each) for each corresponding spectrum (30,000 images in total) were generated based on the RGB value and the random noises. Finally, the images were trained and tested by the developed convolutional neural network. We successfully predicted the local refractive index with 99% accuracy with 5 cross-validations.
Note: we use the simulated images to prove the concept in this work. The same method can be applied when detecting real analytes with proper adjustment. We believe the reported work can help to improve both sensitivity and selectivity in chemical and biochemical sensing.
References
[1] Soler, M., Huertas, C. S., & Lechuga, L. M. (2019). Label-free plasmonic biosensors for point-of-care diagnostics: a review. Expert review of molecular diagnostics, 19(1), 71-81.
[2] Xu, Y., Bai, P., Zhou, X., Akimov, Y., Png, C. E., Ang, L. K., ... & Wu, L. (2019). Optical refractive index sensors with plasmonic and photonic structures: promising and inconvenient truth. Advanced Optical Materials, 7(9), 1801433..
[3] Zhao, Y., Mukherjee, K., Benkstein, K. D., Sun, L., Steffens, K. L., Montgomery, C. B., ... & Zaghloul, M. E. (2019). Miniaturized nanohole array based plasmonic sensor for the detection of acetone and ethanol with insights into the kinetics of adsorptive plasmonic sensing. Nanoscale, 11(24), 11922-11932.
[4] Feng, S., Farha, F., Li, Q., Wan, Y., Xu, Y., Zhang, T., & Ning, H. (2019). Review on smart gas sensing technology. Sensors, 19(17), 3760.
Figure 1
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Generation and enhancement of surface acoustic waves on a highly doped p-type GaAs substrate
Enhancement of SAWs propagating along the surface of a highly doped p-type GaAs substrate is achieved using a ZnO/SiO2 island.</p
Simulations of energy-bands bending effect and carriers transportation in semiconductor with propagating Surface Acoustic Waves
Enhancement of Photoemission on p-Type GaAs Using Surface Acoustic Waves
We demonstrate that photoemission properties of p-type GaAs can be altered by surface acoustic waves (SAWs) generated on the GaAs surface due to dynamical piezoelectric fields of SAWs. Multiphysics simulations indicate that charge-carrier recombination is greatly reduced, and electron effective lifetime in p-doped GaAs may increase by a factor of 10× to 20×. It implies a significant increase, by a factor of 2× to 3×, of quantum efficiency (QE) for GaAs photoemission applications, like GaAs photocathodes. Conditions of different SAW wavelengths, swept SAW intensities, and varied incident photon energies were investigated. Essential steps in SAW device fabrication on a GaAs substrate are demonstrated, including deposition of an additional layer of ZnO for piezoelectric effect enhancement, measurements of current–voltage (I–V) characteristics of the SAW device, and ability to survive high-temperature annealing. Results obtained and reported in this study provide the potential and basis for future studies on building SAW-enhanced photocathodes, as well as other GaAs photoelectric applications.</jats:p
Research on the Rheological Properties and Diffusion Law of Coal-Based Solid Waste Geopolymer Grouting Material
The rheological properties and diffusion law of coal-based solid waste geopolymer grouting material (CGGM) slurry were investigated by rheological property test and diffusion theory model derivation. Based on the power-law fluid constitutive equation, a theoretical model of slurry diffusion in an inclined fissure aquifer was established, and the effect of slurry grouting time on the slurry diffusion distance under different fissure widths, fissure inclination angles, and grouting pressures were analyzed. The results show that when coal gangue:cement:fly ash = 5:4:1, sodium silicate modulus 2.0, sodium silicate content is 10%, CGGM slurry’s bleeding rate of 1%, the liquidity of 227 mm, the initial and final setting time is 412 min and 825 min, respectively, to meet the requirements of the grouting project. CGGM slurry is a typical viscosity time-varying power-law type fluid, and the slurry diffusion distance is positively correlated with the grouting pressure, fissure width, fissure inclination angle, and negatively correlated with the rheological index. The established theoretical model can provide a reference for the parameter design of CGGM slurry in grouting construction
A Nanotechnology Enhancement to Moore's Law
Intel Moore observed an exponential doubling in the number of transistors in every 18 months through the size reduction of transistor components since 1965. In viewing of mobile computing with insatiate appetite, we explored the necessary enhancement by an increasingly maturing nanotechnology and facing the inevitable quantum-mechanical atomic and nuclei limits. Since we cannot break down the atomic size barrier, the fact implies a fundamental size limit at the atomic/nucleus scale. This means, no more simple 18-month doubling, but other forms of transistor doubling may happen at a different slope. We are particularly interested in the nano enhancement area. (i) 3 Dimensions: If the progress in shrinking the in-plane dimensions is to slow down, vertical integration can help increasing the areal device transistor density. As the devices continue to shrink into the 20 to 30 nm range, the consideration of thermal properties and transport in such devices becomes increasingly important. (ii) Quantum computing: The other types of transistor material are rapidly developed in laboratories worldwide, for example, Spintronics, Nanostorage, HP display Nanotechnology, which are modifying this Law. We shall consider the limitation of phonon engineering fundamental information unit “Qubyte” in quantum computing, Nano/Micro Electrical Mechanical System (NEMS), Carbon Nanotubes, single-layer Graphenes, single-strip Nano-Ribbons, and so forth
The value of the MIND diet in the primary and secondary prevention of hypertension: A cross-sectional and longitudinal cohort study from NHANES analysis
BackgroundThe Mediterranean-Dietary Approaches to Stop Hypertension for neurodegenerative delay (MIND) has been regarded as a novel healthy dietary pattern with huge benefits. However, its value in preventing and treating hypertension has not been investigated. The objective of this study is to investigate the impact of adhering to the MIND diet on the prevalence of hypertension in the entire population and long-term mortality in hypertensive patients.MethodsIn this cross-sectional and longitudinal study, 6,887 participants consisting of 2,984 hypertensive patients in the National Health and Nutritional Examination Surveys were analyzed and divided into 3 groups according to the MIND diet scores (MDS; groups of MDS-low [<7.5], MDS-medium [7.5–8.0] and MDS-high [≥8.5]). In the longitudinal analysis, the primary outcome was all-cause death and the secondary outcome was cardiovascular (CV) death. Hypertensive patients received a follow-up with a mean time of 9.25 years (median time: 111.1 months, range 2 to 120 months). Multivariate logistics regression models and Cox proportional hazards models were applicated to estimate the association between MDS and outcomes. Restricted cubic spline (RCS) was used to estimate the dose–response relationship.ResultsCompared with the MDS-low group, participants in the MDS-high group presented a significantly lower prevalence of hypertension (odds ratio [OR] 0.76, 95% confidence interval [CI] 0.58, 0.97, p = 0.040) and decreased levels of systolic blood pressure (β = −0.41, p = 0.033). Among hypertensive patients, 787 (26.4%) all-cause death consisting of 293 (9.8%) CV deaths were recorded during a 10-year follow-up. Hypertensive patients in the MDS-high group presented a significantly lower prevalence of ASCVD (OR = 0.71, 95% CI, 0.51, 0.97, p = 0.043), and lower risk of all-cause death (hazard ratio [HR] = 0.69, 95% CI, 0.58, 0.81, p < 0.001) and CV death (HR = 0.62, 95% CI, 0.46, 0.85, p for trend = 0.001) when compared with those in the MDS-low group.ConclusionFor the first time, this study revealed the values of the MIND diet in the primary and secondary prevention of hypertension, suggesting the MIND diet as a novel anti-hypertensive dietary pattern
