Effect of soda-lime glass on sintering and technological properties of porcelain stoneware tiles

The feasibility of waste glass recycling in ceramic tile production was assessed with special reference to fully vitrified products (porcelain stoneware). Soda-lime float or container glass was introduced, in replacement of sodic feldspar, in typical porcelain stoneware bodies (up to 10% wt) that underwent a laboratory simulation of tilemaking process, with a technological and compositional characterization of both fired and unfired tiles. Soda-lime glass had no significant effect on semi-finished products, but it influenced remarkably the firing behaviour, increasing shrinkage and closed porosity, decreasing open porosity and bulk density, and lowering mechanical and tribological performances. Waste glass promotes a more effective melting of quartz and a partial dissolution of mullite, leading to a more abundant and less viscous liquid phase, which accelerates the sintering kinetics. In conclusion, soda-lime glass can be used in small amounts (5% or less) with tolerable modifications of technological behaviour and performances of porcelain stoneware tiles

Zirconium titanate ceramic pigments: Crystal structure, optical spectroscopy and technological properties

Srilankite-type zirconium titanate, a promising structure for ceramic pigments, was synthesized at 1400 degrees C following three main doping strategies: (a) ZrTi(1-x)A(x)O(4), (b) ZrTi(1-x-y)A(x)B(y)O(4) and (c) Zr1-xCTiO4 where A = Co, Cr, Fe, Mn. Ni or V (chromophores), B = Sb or W (counterions) and C = Pr (chromophore); x = y = 0.05. Powders were characterized by XRD with Rietveld refinements and DRS in the UV-visible-NIR range; technological properties were appraised in several ceramic matrices (frits, glazes and body). Zirconium titanate can be usefully coloured with first row transition elements, giving green and greenish yellow (Co and Ni); orange-buff (Cr and V); tan-brown hues (Mn and Fe). In industrial-like synthesis conditions, a disordered structure as (Zr,Ti)O-2, with both Zr and Ti randomly distributed in the octahedral site, is achieved. Doping with chromophores and counterions induces unit cell dimensions variation and causes an oversaturation in zirconium oxide. Optical spectroscopy reveals the occurrence of Co2+, Cr3+, Fe3+, Mn2+, Mn3+, Ni2+, V3+ and V4+. The zirconium titanate pigments fulfil current technological requirements for low-temperature applications, but exhibit a limited chemico-physical stability for higher firing temperature and in chemically aggressive media

How many radio-loud quasars can be detected by the Gamma-Ray Large Area Space Telescope?

In the unification scheme, radio quasars and FR II radio galaxies come from the same parent population, but viewed at different angles. Based on the Comptonization models for the gamma-ray emission from active galactic nuclei (AGNs), we estimate the number of radio quasars and FR II radio galaxies to be detected by the Gamma-Ray Large Area Space Telescope (GLAST) using the luminosity function (LF) of their parent population derived from the flat-spectrum radio quasar (FSRQ) LF. We find that ~1200 radio quasars will be detected by GLAST, if the soft seed photons for Comptonization come from the regions outside the jets. We also consider the synchrotron self-Comptonization (SSC) model, and find it unlikely to be responsible for gamma-ray emission from radio quasars. We find that no FR II radio galaxies will be detected by GLAST. Our results show that most radio AGNs to be detected by GLAST will be FSRQs (~99 % for the external Comptonization model, EC model), while the remainder (~1 %) will be steep-spectrum radio quasars (SSRQs). This implies that FSRQs will still be good candidates for identifying gamma-ray AGNs even for the GLAST sources. The contribution of all radio quasars and FR II radio galaxies to the extragalactic gamma-ray background (EGRB) is calculated, which accounts for ~30 % of the EGRB.Comment: 4 pages, accepted by ApJ Letter

The role of counterions (Mo, Nb, Sb, W) in Cr-, Mn-, Ni- and V-doped rutile ceramic pigments - Part 1. Crystal structure and phase transformations

Rutile is widely used as ceramic pigment for its excellent optical properties, high melting point and intense coloration when doped with transition elements. Industrial ceramic pigments are manufactured from anatase Plus chromophore elements (Cr, Mn, Ni or V) and counterions (Nb, Sb or W). Several solid state reactions occur during the synthesis, involving both the anatase-to-rutile transformation (A --> R) and the formation of accessory phases. The A --> R transition is heavily affected by chromophores with a lowering of the onset temperature: V < Cr < Ni < Mn: the effect of counterions is almost completely hidden by that of chromophores, even if the sequence Mo < Sb < W < Nb may be inferred. The crystal structure of rutile pigments is modified by chromophores and counterions doping; in fact, the doping varies the cell parameters, implies a progressive distortion of the octahedral site and a peculiar variation of the mean Ti-O bond length, with longer basal Ti-O distances and a shorter apical Ti-O distance. The pigment co-doped with V and W is different for its minimum Ti-O bond length distortion (BLD), an almost regular TiO6 octahedron, and the occurrence of Ti3+ within the accessory compound Ti5O9

The Role of counterions (Mo, Nb, Sb, W) in Cr-, Mn-, Ni- and V-doped rutile ceramic pigments. Part 2. Colour and technological properties

Industrial rutile pigments are manufactured using several chromophores: Cr (giving an orange hue), Mn (tan), Ni (yellow) and V (gray); a second element, the so-called counterion (i.e. Mo, Sb, Nb or W) is always added in order to achieve the desired coloration and/or improve the technological properties (e.g. chemico-physical resistance in ceramic bodies and glazes). The colour of these pigments is determined by both metal-ligand charge transfer (Ti4+ <-> O2-) and crystal field effects (transition metals substituting Ti4+ in octahedral coordination). Though the absorbance bands are broad and frequently overlapped, the UV-vis-NIR spectra suggest the occurrence of Cr3+, Mn2+, Mn3+, Ni2+, V3+, and V4+ as chromophores. Rutile pigments are suitable for through-body (up to 1250 degrees C) and glaze applications (up to 1100 degrees C). The best coloration of porcelain stoneware bodies is achieved with Sb or W as counterions, though the higher stability is ensured by Sb, but in the Ti-Ni-W system. The best glaze colours are accomplished by W-bearing pigments, which however are less stable than Nb- or Sb-containing ones, except than for the V + W coupling. This latter represents a new and very interesting Co-free and Cr-free black pigment for low temperature applications

Water vapour permeability of clay bricks

The water vapour permeability of clay bricks has been experimentally measured in order to draw a representative outline of industrial products without pore-forming additives. The correlations between water vapour permeability and the main compositional and microstructural parameters of both bricks and clay bodies have been investigated. A statistical model was set up in order to predict with reasonable precision and reliability, the water vapour permeability on the basis of open porosity, bulk density, mean pore size and pore specific surface values of bricks, and the finer particle size of clay bodies

Crystal structural and optical properties of Cr-doped Y2Ti2O7 and Y2Sn2O7 pyrochlores

Pyrochlore-type [A(2)(VIII)B(2)(VI)O(6)O] rare earth stannates (PS) and titanates (PT), doped with increasing amounts of Cr, develop colours 2 2 ranging from magenta to brown. Combined X-ray and neutron diffraction data revealed that Cr solubility in both pyrochlores is very limited, i.e. 0.07 atoms/formula unit in PS and 0.06 atoms/formula unit in PT. A further increase in the Cr amount determines the formation of the YCrO3 perovskite. Diffuse reflectance spectroscopy data showed that the optical properties of Cr-doped yttrium titanates and stannates are rather similar, and that the final colour of the powders is due to the overlapping peaks of Cr4+ in the octahedral site of the pyrochlore and of Cr3+ in the ternary perovskite. The oxygen occupancy refinement showed that no anion vacancies are formed upon Cr substitution for Sn4+ or Ti4+, implying that such a charge compensation mechanism does not occur, confirming that the Cr in titanate and stannate pyrochlores is mainly in a tetravalent state

Bike Lane Design: the Context Sensitive Approach

In these days of increasing congestion on roads, bicycles continue to provide a valuable contribution to mobility in Europe. Their relatively small size and low cost enable them to blend efficiently into in the traffic flow while needing less space compared to other vehicles. However, cyclists form one of the most vulnerable groups of road users. So the design of safe infrastructures for all travellers categories, included the cyclists, becomes a primary requirement. To obtain these results, a Context Sensitive Design approach is a very useful tool. In this way, in fact, it is possible to examine a project or existing road, reporting its crash potential and safety performances and detecting its deficiencies, taking into consideration communities and lands which it passes through. In this paper the authors, starting from results collected on a bike lane placed in Rimini, provide useful results for designers, construction and maintenance contractors, in order to obtain safe bike lanes

Constraints on the Physical Parameters of TeV Blazars

We consider the constraints on the physical parameters of a homogeneous SSC model that can be derived from the spectral shape and variability of TeV blazars. Assuming that the relativistic electron spectrum is a broken power law, where the break energy $\gamma_b$ is a free parameter, we write the analytical formulae that allow to connect the physical parameters of the model to observable quantities. The constraints can be summarized in a plane where the coordinates are the Doppler factor and the magnetic field. The consistency between the break energy and the balance between cooling and escape and the interpretation of the soft photon lags measured in some sources as radiative cooling times are treated as additional independent constraints. We apply themethod to the case of three well known blazars, PKS 2155-304, Mrk 421 and Mrk 501.Comment: 36 pages, incl. 6 figures in PS format, AAS LaTeX, to be published in ApJ, Dec 199