9 research outputs found
Increased thermal sensitivity of Listeria monocytogenes in sous-vide salmon by oregano essential oil and citric acid
PMID = 3233636
Blue Light Sensitive Dyes for Various Photopolymerization Reactions: Naphthalimide and Naphthalic Anhydride Derivatives
International audienceNovel naphthalimide derivatives (or naphthalic anhydride derivatives) have been prepared and combined with an iodonium salt, Nvinylcarbazole, amines or 2,4,6-tris(trichloromethyl)-1,3,5-triazine to produce radicals and cations upon exposure to low intensity blue lights (e.g., a household blue LED bulb). The photochemical mechanisms are studied by electron spin resonance spin trapping, fluorescence, cyclic voltammetry, laser flash photolysis, and steady state photolysis techniques. The naphthalimide derivatives (ND4) or the naphthalic anhydride derivative (ND10) based photoinitiating systems are particularly efficient for cationic, radical and thiolâ ene photopolymerizations; the synthesis of interpenetrated polymer networks IPNs can also be easily carried out. Compared to camphorquinone/amine or camphorquinone/iodonium salt, the new proposed combinations appear as highly versatile and high performance visible light photoinitiating systems. Some of these photoinitiating systems can also be used for UV LED irradiations (e.g., 365, 385, or 395 nm)