28 research outputs found
Hybrid solid state qubits: the powerful role of electron spins
We review progress on the use of electron spins to store and process quantum
information, with particular focus on the ability of the electron spin to
interact with multiple quantum degrees of freedom. We examine the benefits of
hybrid quantum bits (qubits) in the solid state that are based on coupling
electron spins to nuclear spin, electron charge, optical photons, and
superconducting qubits. These benefits include the coherent storage of qubits
for times exceeding seconds, fast qubit manipulation, single qubit measurement,
and scalable methods for entangling spatially separated matter-based qubits. In
this way, the key strengths of different physical qubit implementations are
brought together, laying the foundation for practical solid-state quantum
technologies.Comment: 54 pages, 7 figure
Advanced electron paramagnetic resonance on the catalytic iron–sulfur cluster bound to the CCG domain of heterodisulfide reductase and succinate: quinone reductase
Influence of Hyperfine Coupling Strain on Two-Dimensional ESEEM Spectra from I = 1/2 Nuclei
Structural analysis of Cu(II) ligation to the 5'-GMP nucleotide by pulse EPR spectroscopy
Simple copper salts are known to denature poly d(GC). On the other hand, copper complexes of substituted 1,4,7,10,13-pentaazacyclohexadecane-14,16-dione are able to convert the right-handed B form of the same DNA sequence to the corresponding left-handed Z form. A research program was started in order to understand why Cu(II) as an aquated ion melts DNA and induces the conformational change to Z-DNA in the form of an azamacrocyclic complex. In this paper, we present a continuous wave and pulse electron paramagnetic resonance study of the mononucleotide model system Cu(II)-guanosine 5'-monophosphate . Pulse EPR methods like electron-nuclear double resonance and hyperfine sublevel correlation spectroscopy provide unique information about the electronic and geometric structure of this model system through an elaborate mapping of the hyperfine and nuclear quadrupole interactions between the unpaired electron of the Cu(II) ion and the magnetic nuclei of the nucleotide ligand. It was found that the Cu(II) ion is directly bound to N7 of guanosine 5'-monophosphate and indirectly bound via a water of hydration to a phosphate group. This set of experiments opens the way to more detailed structural characterization of specifically bound metal ions in a variety of nucleic acids of biological interest, in particular to understand the role of the metal-(poly)nucleotide interaction