An indicator of the multiple equilibria regime of the Atlantic meridional overturning circulation

Recent model results have suggested that there may be a scalar indicator ? monitoring whether the Atlantic meridional overturning circulation (MOC) is in a multiple equilibrium regime. The quantity ? is based on the net freshwater transport by the MOC into the Atlantic basin. It changes sign as soon as the steady Atlantic MOC enters the multiple equilibrium regime because of an increased freshwater input in the northern North Atlantic. This paper addresses the issue of why the sign of ? is such a good indicator for the multiple equilibrium regime. Changes in the Atlantic freshwater budget over a complete bifurcation diagram and in finite amplitude perturbation experiments are analyzed in a global ocean circulation model. The authors show that the net anomalous freshwater transport into or out of the Atlantic, resulting from the interactions of the velocity perturbations and salinity background field, is coupled to the background (steady state) state freshwater budget and hence to ?. The sign of ? precisely shows whether this net anomalous freshwater transport is stabilizing or destabilizing the MOC. Therefore, it can indicate whether the MOC is in a single or multiple equilibrium regime.<br/

Evaluation of models to predict the stoichiometry of volatile fatty acid profiles in rumen fluid of lactating Holstein cows

Volatile fatty acids (VFA), produced in the rumen by microbial fermentation, are the main energy source for ruminants. The VFA profile, particularly the nonglucogenic (acetate, Ac; butyrate, Bu) to glucogenic (propionate, Pr) VFA ratio (NGR), is associated with effects on methane production, milk composition, and energy balance. The aim of this study was to evaluate extant rumen VFA stoichiometry models for their ability to predict in vivo VFA molar proportions. The models were evaluated using an independent data set consisting of 101 treatments from 24 peer-reviewed publications with lactating Holstein cows. All publications contained a full diet description, rumen pH, and rumen VFA molar proportions. Stoichiometric models were evaluated based on root mean squared prediction error (RMSPE) and concordance correlation coefficient (CCC) analysis. Of all models evaluated, the 1998 Friggens model had the lowest RMSPE for Ac and Bu (7.2 and 20.2% of observed mean, respectively). The 2006 Bannink model had the lowest RMSPE and highest CCC for Pr (14.4% and 0.70, respectively). The 2008 Bannink model had comparable predictive performance for Pr to that of the 2006 Bannink model but a larger error due to overall bias (26.2% of MSPE). The 1982 Murphy model provided the poorest prediction of Bu, with the highest RMSPE and lowest CCC (24.6% and 0.15, respectively). The 1988 Argyle and Baldwin model had the highest CCC for Ac with an intermediate RMSPE (0.47 and 8.0%, respectively). The 2006 Sveinbjörnsson model had the highest RMSPE (13.9 and 34.0%, respectively) and lowest CCC (0.31 and 0.40, respectively) for Ac and Pr. The NGR predictions had the lowest RMSPE and highest CCC in the 2 models of Bannink, whereas the lowest predictive performance was in the 2006 Sveinbjörnsson model. It appears that the type of VFA produced is not a simple linear relationship between substrate inputs and pH as currently represented. The analysis demonstrates that most rumen VFA stoichiometric approaches explain a large part of the variation in VFA molar proportions among diets, in particular for Ac, whereas predictive power for Pr and Bu differ largely among approaches. The move toward feed evaluation systems based on animal response might necessitate an improved representation of rumen fermentation, focused on improving our understanding of VFA proportions in diets that vary from the mean

Screening of heterogeneous surfaces: charge renormalization of Janus particles

Nonlinear ionic screening theory for heterogeneously charged spheres is developed in terms of a mode-decomposition of the surface charge. A far-field analysis of the resulting electrostatic potential leads to a natural generalization of charge renormalization from purely monopolar to dipolar, quadropolar, etc., including mode-couplings. Our novel scheme is generally applicable to large classes of surface heterogeneities, and is explicitly applied here to Janus spheres with differently charged upper and lower hemispheres, revealing strong renormalization effects for all multipoles.Comment: 2 figure

Polyamides : hydrogen bonding, the Brill transition, and superheated water

Aliphatic polyamide, commonly known as nylon, was the world’s first synthetic fiber and has found its largest application range in tires, carpets, stockings, upholstery, and adhesives. All polyamides have a recurring amide group (–CONH–) present in the molecular structure with hydrogen bonds between these recurring amide groups. In comparison to other polymers such as polyethylenes, polyamides have a high melting temperature. Although polyamides have been extensively studied by many research groups, much is still to be learned and achieved regarding these materials. The first main achievement reached in this thesis concerns a new and improved insight and understanding of the Brill transition seen in many polyamides. The Brill transition is a solid state crystalline transition observed in polyamides on heating. The Brill transition temperature is defined as the temperature at which the characteristic intersheet and interchain reflections observed in wide angle X-ray diffraction (WAXD) merge to a single reflection which is maintained up to the melt. The nature and mechanisms behind the Brill transition has been a matter of debate ever since it was first studied in 1942. The work presented in this thesis creates a better understanding of the mechanisms involved during the Brill transition, and how the Brill transition might be influenced by hydrogen bonding; a major factor influencing many polyamide properties. It appears plausible that the Brill transition would be influenced by hydrogen bonding, or more specifically, by a weakening of hydrogen bonding. By using a unique set of piperazine based copolyamides specially tailored to study the influence of hydrogen bonding on various (physical) properties, we are able to study how the Brill transition relates to hydrogen bonding. We show that the Brill transition is independent of the piperazine content, and therefore also independent of the hydrogen bond density. The Brill transition is caused by conformational changes in the polyamide main chain which cause the methylene units to twist, whilst hydrogen bonding is retained. When the methylene units next to the amide groups are able to twist sufficiently, the Brill transition is observed. The Brill transition is therefore not a classical first or second order transition, but a solid state crystalline transition driven by the crankshaft motions in the polyamide main chain. The work presented on the Brill transition has made a significant contribution towards completely understanding this transition. The use of specially tailored and designed copolyamides together with the use of many high quality analytical techniques proved essential to the successes achieved here. The work presented in this thesis combines the knowledge and expertise from two distinctly different, yet complementary fields in polymer research. The understanding gained from studying the Brill transition and the chain motions present in polyamides provide the possibility for understanding the influence of water, and more specifically the influence of superheated water, which is water above 100¿C, on polyamides in general. The second main achievement described in this thesis involves dissolving polyamide in water. We show that superheated water is a solvent for various (commercial) polyamides, including polyamide 4,6 and polyamide 6,6. The conformational changes in the polyamide during the Brill transition are key in the dissolution process, allowing highly mobile water molecules in the superheated state to penetrate the crystal lattice and break the hydrogen bonds between the amide groups. On crystallization from the water solution, which occurs upon cooling the solution, water molecules associate to the amide group in the crystal lattice, weakening the amide-amide hydrogen bonds. On heating the dried, water crystallized polyamide above the Brill transition, the water molecules are released from the crystal lattice and the hydrogen bonds are restored. The removal of water molecules at the Brill transition is typically observed by an exothermic event in differential scanning calorimetry (DSC) experiments performed on dried sedimented water crystallized polyamide crystals. The influence of water on the crystal lattice is observed very clearly for polyamide 2,14 where the water molecules incorporated in the crystal lattice cause a slip in the hydrogen bonded planes. This slippage results in the coexistence of a triclinic and monoclinic crystal structure observed in WAXD. On heating above the Brill transition temperature, the water molecules exit from the crystal lattice, and the polyamide shows only the triclinic crystal structure. The work presented in this thesis, especially the work related to the use of superheated water as a polyamide solvent, opens the door for an environmentally friendly processing route. A route in which water instead of organic solvents and acids are used to process polyamides. For the use of (superheated) water in processing applications such as film casting and recycling it is essential that the polyamide crystallization from the superheated water is a controlled process. Currently this is not the case; on cooling the polyamide/water solution the polyamide crystallizes from solution rapidly and uncontrolled when sufficient undercooling is obtained. The growth of large single crystals for example is hampered by this fast crystallization. The next step that needs to be taken is to control the crystallization, for example by adding salts to the solution, thereby preventing or manipulating the crystallization,33 even at room temperature. Dependent on the choice of ions and the requirements applicable to the applications under consideration, it would be possible to influence or suppress the crystallization. The possibilities for environmentally friendly polyamide processing using water-based technology are a promising prospect for the future

A positive relationship between the abundance of ammonia oxidizing archaea and natural abundance δ15N of ecosystems

We present a significant relationship between the natural abundance isotopic composition of ecosystem pools and the abundance of a microbial gene. Natural abundance 15N of soils and soil DNA were analysed and compared with archaeal ammonia oxidizer abundance along an elevation gradient in northern Arizona and along a substrate age gradient in Hawai'i. There was a significant positive correlation between the abundance of archaeal amoA genes and natural abundance δ15N of total soil or DNA suggesting that ammonia oxidizing archaea play an important role in ecosystem N release. © 2013 Elsevier Ltd

Directed Explicit Model Checking with HSF-SPIN

We present the explicit state model checker HSF-SPIN which is based on the model checker SPIN and its Promela modeling language. HSF-SPIN incorporates directed search algorithms for checking safety and a large class of LTL-specified liveness properties. We start off from the A* algorithm and define heuristics to accelerate the search into the direction of a specified failure situation. Next we propose an improved nested depth-first search algorithm that exploits the structure of Promela Never-Claims. As a result of both improvements, counterexamples will be shorter and the explored part of the state space will be smaller than with classical approaches, allowing to analyze larger state spaces. We evaluate the impact of the new heuristics and algorithms on a set of protocol models, some of which are real-world industrial protocols

Mid-infrared emission and absorption in strained and relaxed direct bandgap GeSn semiconductors

By independently engineering strain and composition, this work demonstrates and investigates direct band gap emission in the mid-infrared range from GeSn layers grown on silicon. We extend the room-temperature emission wavelength above ~4.0 {\mu}m upon post-growth strain relaxation in layers with uniform Sn content of 17 at.%. The fundamental mechanisms governing the optical emission are discussed based on temperature-dependent photoluminescence, absorption measurements, and theoretical simulations. Regardless of strain and composition, these analyses confirm that single-peak emission is always observed in the probed temperature range of 4-300 K, ruling out defect- and impurity-related emission. Moreover, carrier losses into thermally-activated non-radiative recombination channels are found to be greatly minimized as a result of strain relaxation. Absorption measurements validate the direct band gap absorption in strained and relaxed samples at energies closely matching photoluminescence data. These results highlight the strong potential of GeSn semiconductors as versatile building blocks for scalable, compact, and silicon-compatible mid-infrared photonics and quantum opto-electronics

Mapping and Characterizing Subtidal Oyster Reefs Using Acoustic Techniques, Underwater Videography and Quadrat Counts

Populations of the eastern oyster Crassostrea virginica have been in long-term decline in most areas. A major hindrance to effective oyster management has been lack of a methodology for accurately and economically obtaining data on their distribution and abundance patterns. Here, we describe early results from studies aimed at development of a mapping and monitoring protocol involving acoustic techniques, underwater videography, and destructive sampling (excavated quadrats). Two subtidal reefs in Great Bay, New Hampshire, were mapped with side-scan sonar and with videography by systematically imaging multiple sampling cells in a grid covering the same areas. A single deployment was made in each cell, and a 5-10-s recording was made of a 0.25-m2 area; the location of each image was determined using a differential global position system. A still image was produced for each of the cells and all (n = 40 or 44) were combined into a single photomontage overlaid onto a geo-referenced base map for each reef using Arc View geographic information system. Quadrat (0.25 m2 ) samples were excavated from 9 or 10 of the imaged areas on each reef, and all live oysters were counted and measured. Intercomparisons of the acoustic, video, and quadrat data suggest: (1) acoustic techniques and systematic videography can readily delimit the boundaries of oyster reefs; (2) systematic videography can yield quantitative data on shell densities and information on reef structure; and (3) some combination of acoustics, systematic videography, and destructive sampling can provide spatially detailed information on oyster reef characteristics

Effects of Star Formation Stochasticity on the Ly-alpha & Lyman Continuum Emission from Dwarf Galaxies during Reionization

Observations of distant galaxies play a key role in improving our understanding of the Epoch of Reionization (EoR). The observed Ly-alpha emission line strength - quantified by its restframe equivalent width (EW) - provides a valuable diagnostic of stellar populations and dust in galaxies during and after the EoR. In this paper we quantify the effects of star formation stochasticity on the predicted Ly-alpha EW in dwarf galaxies, using the publicly available code SLUG ('Stochastically Light Up Galaxies'). We compute the number of hydrogen ionizing photons, as well as flux in the Far UV for a set of models with star formation rates (SFR) in the range 10-3-1 Msol/yr. From these fluxes we compute the luminosity, L-alpha, and the EW of the Ly-alpha line. We find that stochasticity alone induces a broad distribution in L-alpha and EW at a fixed SFR, and that the widths of these distributions decrease with increasing SFR. We parameterize the EW probability density function (PDF) as an SFR-dependent double power law. We find that it is possible to have EW as low as ~EW0/4 and as high as ~3 times the EW0, where EW0 denotes the expected EW in the absence of stochasticity. We argue that stochasticity may therefore be important when linking drop-out and narrow-band selected galaxies, when identifying population III galaxies, and that it may help to explain the large EW (EW > 100 - 200 A) observed for a fraction of Ly-alpha- selected galaxies. Finally, we show that stochasticity can also affect the inferred escape fraction of ionizing photons from galaxies. In particular, we argue that stochasticity may simultaneously explain the observed anomalous ratios of the Lyman continuum flux density to the (non-ionizing) UV continuum density in so-called Lyman-Bump galaxies at z = 3.1, as well as the absence of such objects among a sample of z = 1.3 drop-out galaxies.Comment: 9 pages, 4 figures, accepted for publication in MNRA

Modelling the gas kinematics of an atypical Lyman-alpha emitting compact dwarf galaxy

Star-forming Compact Dwarf Galaxies (CDGs) resemble the expected pristine conditions of the first galaxies in the Universe and are the best systems to test models on primordial galaxy formation and evolution. Here we report on one of such CDGs, Tololo 1214-277, which presents a broad, single peaked, highly symmetric Ly$\alpha$ emission line that had evaded theoretical interpretation so far. In this paper we reproduce for the first time these line features with two different physically motivated kinematic models: an interstellar medium composed by outflowing clumps with random motions and an homogeneous gaseous sphere undergoing solid body rotation. The multiphase model requires a clump velocity dispersion of $54.3\pm 0.6$ km s$^{-1}$ with outflows of $54.3\pm 5.1$ km s$^{-1}$, while the bulk rotation velocity is constrained to be $348^{+75}_{-48}$ km s$^{-1}$. We argue that the results from the multiphase model provide a correct interpretation of the data. In that case the clump velocity dispersion implies a dynamical mass of $2\times 10^{9}$ M$_{\odot}$, ten times its baryonic mass. If future kinematic maps of Tololo 1214-277 confirm the velocities suggested by the multiphase model, it would provide additional support to expect such kinematic state in primordial galaxies, opening the opportunity to use the models and methods presented in this paper to constrain the physics of star formation and feedback in the early generation of Ly-$\alpha$ emitting galaxies.Comment: 10 pages, 5 figures, 2 tables. Accepted for publication in MNRA