2 research outputs found
A formally exact field theory for classical systems at equilibrium
We propose a formally exact statistical field theory for describing classical
fluids with ingredients similar to those introduced in quantum field theory. We
consider the following essential and related problems : i) how to find the
correct field functional (Hamiltonian) which determines the partition function,
ii) how to introduce in a field theory the equivalent of the indiscernibility
of particles, iii) how to test the validity of this approach. We can use a
simple Hamiltonian in which a local functional transposes, in terms of fields,
the equivalent of the indiscernibility of particles. The diagrammatic expansion
and the renormalization of this term is presented. This corresponds to a non
standard problem in Feynman expansion and requires a careful investigation.
Then a non-local term associated with an interaction pair potential is
introduced in the Hamiltonian. It has been shown that there exists a mapping
between this approach and the standard statistical mechanics given in terms of
Mayer function expansion. We show on three properties (the chemical potential,
the so-called contact theorem and the interfacial properties) that in the field
theory the correlations are shifted on non usual quantities. Some perspectives
of the theory are given.Comment: 20 pages, 8 figure