12 research outputs found

    Chiral Anion Mediated Asymmetric Induction onto Chiral Diquats

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    Diquats—which are important electron transfer agents in biological and photocatalytic systems, as well as structural templates for efficient supramolecular synthesis—are noteworthy for their axial chirality and have been so far reported only in racemic form due to the rapid interconversion between the atropoisomers. We now report the first example of configurational ordering of chiral diquats through their asymmetric ion pairing with novel hexacoordinated phosphate anions TRISPHAT, HYPHAT and BINPHAT

    In Search of Efficient 5-Endo-dig Cyclization of a Carbon-Centered Radical: 40 Years from a Prediction to Another Success for the Baldwin Rules

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    Bilability is Defined when One Electron is Used to Switch between Concerted and Stepwise Pathways in Cu(I)-Based Bistable [2/3]Pseudorotaxanes

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    Organocuprates and Diamagnetic Copper Complexes: Structures and NMR Spectroscopic Structure Elucidation in Solution

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    Stable synthetic equivalents of N-unsubstituted imines: Part 1. Synthesis

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