11 research outputs found
On the nature of striped phases: Striped phases as a stage of "melting" of 2D crystals
We discuss striped phases as a state of matter intermediate between two
extreme states: a crystalline state and a segregated state. We argue that this
state is very sensitive to weak interactions, compared to those stabilizing a
crystalline state, and to anisotropies. Moreover, under suitable conditions a
2D system in a striped phase decouples into (quasi) 1D chains. These
observations are based on results of our studies of an extension of a
microscopic quantum model of crystallization, proposed originally by Kennedy
and Lieb.Comment: 16 pages, 8 figure
Towards a quasiphase transition in the single-file chain of water molecules: Simple lattice model
Recently, X.Ma et al. [Phys. Rev. Lett. 118, 027402 (2017)] have suggested
that water molecules encapsulated in (6,5) single-wall carbon nanotube
experience a temperature-induced quasiphase transition around 150 K interpreted
as changes in the water dipoles orientation. We discuss further this
temperature-driven quasiphase transition performing quantum chemical
calculations and molecular dynamics simulations and, most importantly,
suggesting a simple lattice model to reproduce the properties of the
one-dimensionally confined finite arrays of water molecules. The lattice model
takes into account not only the short-range and long-range interactions but
also the rotations in a narrow tube and the both ingredients provide an
explanation for a temperature-driven orientational ordering of the water
molecules, which persists within a relatively wide temperature range.Comment: 15 pages, 10 figure