3 research outputs found
trans-Bis(2-benzoylÂbenzoato-κO 1)bisÂ(ethanol-κO)bisÂ(1H-imidazole-κN 3)nickel(II)
In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C14H9O3)2(C3H4N2)2(CH3CH2OH)2], the central NiII ion lies on an inversion centre and is octaÂhedrally coordinated. The equatorial plane is formed by two O atoms from two symmetry-related 2-benzoylÂbenzoate ligands and two N atoms from two symmetry-related imidazole ligands, whereas the axial positions are occupied by two O atoms from two ethanol ligands. Intramolecular O---H...O hydrogen bonds stabilize this arrangement. The molÂecules are linked into chains running along the b axis by N—H⋯O hydrogen bonds
BisÂ(benzimidazole-κN 3)bis(2-benzoylÂbenzoato-κO)copper(II)
In the title centrosymmetric mononuclear copper(II) compound, [Cu(C14H9O3)2(C7H6N2)2], the central CuII ion is coordinated by two N atoms from two symmetry-related benzimidazole (bim) ligands and two O atoms from two symmetry-related 2-benzoylÂbenzoate (2-byba) ligands in a square-planar geometry. The molÂecules are linked into chains running along the b axis by N—H⋯O hydrogen bonds and the chains are cross-linked by C—H⋯π interÂactions