First observation of tritium adsorption on graphene

In this work, we report on the first-ever studies of graphene exposed to tritium gas in a controlled environment. The single layer graphene on $\textrm{SiO}_2$/Si substrate was exposed to 400 mbar of $\textrm{T}_2$ for a total time of ~55 h. The resistivity of the graphene sample was measured in-situ during tritium exposure using the Van der Pauw method. After the exposure, the samples were scanned with a confocal Raman microscope to study the effect of tritium on the graphene structure as well as the homogeneity of spectral modifications. We found that the sheet resistance increases by three orders of magnitude during the exposure. By Raman microscopy, we demonstrate that the graphene film can withstand the bombardment from the beta-decay of tritium, and primary and secondary ions. Additionally, the Raman spectra after tritium exposure are comparable with previously observed results in hydrogen-loading experiments carried out by other groups. By thermal annealing we could demonstrate, using Raman spectral analysis, that the structural changes were partially reversible. Considering all observations, we conclude that the graphene film was at least partially tritiated during the tritium exposure.Comment: Submitted to Nanoscale Advances (RSC), 14 pages, 4 figure

Plato, Aristophanes, and the <i>Speeches of Pythagoras</i>

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Pindar’s <i>Olympian</i> 2, Theron’s Faith, and Empedocles’ <i>Katharmoi</i>

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