3,973 research outputs found
5-Amino-7-(3-chlorophenyl)-3,7-dihydro-2H-thieno[3,2-b]pyran-6-carbonitrile 1,1-dioxide
The title compound, C14H11ClN2O3S, with fused thiophene and pyran rings, was synthesized via the condensation of dihydrothiophen-3(2H)-one 1,1-dioxide and 2-(3-chlorobenzylidene)malononitrile catalysed by triethylamine in ethanol. The thiophene ring adopts an envelope conformation and the pyran ring is planar (r.m.s. deviation = 0.0067 Å). The dihedral angle between the pyran and phenyl rings is 80.8 (1)°. The crystal packing is stabilized by intermolecular N—H⋯N and N—H⋯O hydrogen bonds in which the cyano N and sulphone O atoms, respectively, acting as acceptors
Ethyl 7-(4-bromophenyl)-5-trifluoromethyl-4,7-dihydrotetrazolo[1,5-a]pyrimidine-6-carboxylate
In the title compound, C14H11BrF3N5O2, the pyrimidine ring adopts a flattened envelope conformation with sp
3-hybridized carbon as the flap [deviation = 0.177 (3) Å]. The dihedral angle between tetrazole and bromophenyl rings is 84.3 (1)°. In the crystal, molecules are linked into centrosymmetric dimers by pairs of N—H⋯N hydrogen bonds
5′-Amino-2-oxo-2′,3′-dihydrospiro[indoline-3,7′-thieno[3,2-b]pyran]-6′-carbonitrile 1′,1′-dioxide
In the title compound, C15H11N3O4S, the dihedral angle between the mean planes of the dihydroindol-2-one (r.m.s. deviation = 0.015 Å) and dihydrothieno[3,2-b]pyran (r.m.s. deviation = 0.011 Å) ring systems is 89.53 (3)°. The crytal packing is consolidated by intermolecular N—H⋯O and N—H⋯N hydrogen bonds, which link the molecules into a two-dimensional network into sheets lying parallel to (100)
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