9 research outputs found
Photoemission and x-ray absorption spectroscopy study of electron-doped colossal magnetoresistance manganite: La0.7Ce0.3MnO3 film
The electronic structure of La0.7Ce0.3MnO3 (LCeMO) thin film has been
investigated using photoemission spectroscopy (PES) and x-ray absorption
spectroscopy (XAS). The Ce 3d core-level PES and XAS spectra of LCeMO are very
similar to those of CeO2, indicating that Ce ions are far from being trivalent.
A very weak 4f resonance is observed around the Ce 4d 4f absorption edge,
suggesting that the localized Ce 4f states are almost empty in the ground
state. The Mn 2p XAS spectrum reveals the existence of the Mn(2+) multiplet
feature, confirming the Mn(2+)-Mn(3+) mixed-valent states of Mn ions in LCeMO.
The measured Mn 3d PES/XAS spectra for LCeMO agrees reasonably well with the
calculated Mn 3d PDOS using the LSDA+U method. The LSDA+U calculation predicts
a half-metallic ground state for LCeMO.Comment: 7 pages, 7 figure
Synthesis and oxidation of CeN film: An in situ investigation by electron spectroscopies
10.1021/jp0447441Journal of Physical Chemistry B109114953-4958JPCB