Phase transitions of nematic rubbers

Single crystal nematic elastomers undergo a transition from a strongly ordered phase N to an "isotropic" phase I. We show that: (a) samples produced under tension by the Finkelmann procedure are intrinsically anisotropic and should show a small (temperature dependent) birefringence in the high temperature I phase. (b) for the I->Ntransition via cooling there is a spinodal limit but for the N->I transition via heating there is no soft mode at the standard spinodal temperature. (c) the N->I transition is reminiscent of a martensitic transformation: nucleation of the I phase should occur in the form of platelets, making a well defined angle with the director.Comment: 7 pages, 3 figures (To appear in Europhys. Lett.

Pacman percolation: a model for enzyme gel degradation

We study a model for the gel degradation by an enzyme, where the gel is schematized as a cubic lattice, and the enzyme as a random walker, that cuts the bonds over which it passes. The model undergoes a (reverse) percolation transition, which for low density of enzymes falls in a universality class different from random percolation. In particular we have measured a gel fraction critical exponent beta=1.0+-0.1, in excellent agreement with experiments made on the real system.Comment: 4 pages, 7 eps figure

Opinion influence and evolution in social networks: a Markovian agents model

In this paper, the effect on collective opinions of filtering algorithms managed by social network platforms is modeled and investigated. A stochastic multi-agent model for opinion dynamics is proposed, that accounts for a centralized tuning of the strength of interaction between individuals. The evolution of each individual opinion is described by a Markov chain, whose transition rates are affected by the opinions of the neighbors through influence parameters. The properties of this model are studied in a general setting as well as in interesting special cases. A general result is that the overall model of the social network behaves like a high-dimensional Markov chain, which is viable to Monte Carlo simulation. Under the assumption of identical agents and unbiased influence, it is shown that the influence intensity affects the variance, but not the expectation, of the number of individuals sharing a certain opinion. Moreover, a detailed analysis is carried out for the so-called Peer Assembly, which describes the evolution of binary opinions in a completely connected graph of identical agents. It is shown that the Peer Assembly can be lumped into a birth-death chain that can be given a complete analytical characterization. Both analytical results and simulation experiments are used to highlight the emergence of particular collective behaviours, e.g. consensus and herding, depending on the centralized tuning of the influence parameters.Comment: Revised version (May 2018

Scaling theory for the free-energy barrier to homogeneous nucleation of a non-critical phase near a critical point

Homogeneous nucleation of a new phase near an Ising-like critical point of another phase transition is studied. A scaling analysis shows that the free energy barrier to nucleation contains a singular term with the same scaling as the order parameter associated with the critical point. The total magnetisation of the nucleus scales as the response function and so it diverges. Vapour-liquid critical points are in the Ising universality class and so our results imply that near such a critical point the number of molecules in a nucleus of a another phase, such as a crystalline phase, diverges as the isothermal compressibility. The case where symmetry prevents coupling between the nucleus and the order parameter is also considered.Comment: 7 pages including 2 figures (revision adds consideration of nuclei which do not couple to the order parameter and some dynamic scaling

Factorisation properties of the strong product

We investigate a number of factorisation conditions in the frame- work of sets of probability measures, or coherent lower previsions, with finite referential spaces. We show that the so-called strong product constitutes one way to combine a number of marginal coherent lower previsions into an independent joint lower prevision, and we prove that under some conditions it is the only independent product that satisfies the factorisation conditions

Bulk and surface biaxiality in nematic liquid crystals

Nematic liquid crystals possess three different phases: isotropic, uniaxial, and biaxial. The ground state of most nematics is either isotropic or uniaxial, depending on the external temperature. Nevertheless, biaxial domains have been frequently identified, especially close to defects or external surfaces. In this paper we show that any spatially-varying director pattern may be a source of biaxiality. We prove that biaxiality arises naturally whenever the symmetric tensor \Sb=(\grad \nn)(\grad \nn)^T possesses two distinct nonzero eigenvalues. The eigenvalue difference may be used as a measure of the expected biaxiality. Furthermore, the corresponding eigenvectors indicate the directions in which the order tensor \QQ is induced to break the uniaxial symmetry about the director \nn. We apply our general considerations to some examples. In particular we show that, when we enforce homeotropic anchoring on a curved surface, the order tensor become biaxial along the principal directions of the surface. The effect is triggered by the difference in surface principal curvatures

Nucleation of the crystalline phase of proteins in the presence of semidilute non-adsorbing polymer

Starting from a protein solution which is metastable with respect to the crystalline phase, the effect of adding semidilute non-adsorbing polymer is considered. It is found to increase the chemical potential of the protein by a few tenths of kT, which may be enough to lower the barrier to nucleation of the crystalline phase by enough to allow crystallisation. It is also shown that assuming that the polymer induces a pairwise additive attraction leads to qualitatively incorrect results.Comment: 5 pages, 1 figur

Commutative deformations of general relativity: nonlocality, causality, and dark matter

Hopf algebra methods are applied to study Drinfeld twists of (3+1)-diffeomorphisms and deformed general relativity on \emph{commutative} manifolds. A classical nonlocality length scale is produced above which microcausality emerges. Matter fields are utilized to generate self-consistent Abelian Drinfeld twists in a background independent manner and their continuous and discrete symmetries are examined. There is negligible experimental effect on the standard model of particles. While baryonic twist producing matter would begin to behave acausally for rest masses above $\sim1-10$ TeV, other possibilities are viable dark matter candidates or a right handed neutrino. First order deformed Maxwell equations are derived and yield immeasurably small cosmological dispersion and produce a propagation horizon only for photons at or above Planck energies. This model incorporates dark matter without any appeal to extra dimensions, supersymmetry, strings, grand unified theories, mirror worlds, or modifications of Newtonian dynamics.Comment: 47 pages including references, 0 figures, 0 tables Various typos/omissions correcte