From fabrication to mode mapping in silicon nitride microdisks with embedded colloidal quantum dots

We report on the fabrication of free-standing and optically active microdisks with cadmium-based colloidal quantum dots embedded directly into silicon nitride. We show that the process optimization results in low-loss silicon nitride microdisks. The Si 3 N 4 matrix provides the stability necessary to preserve the optical properties of the quantum dots and observe efficient coupling of the photoluminescence to the resonating microdisk modes. Using a spectrally and spatially resolved microphotoluminescence measurement, we map the emission pattern from the microdisk. This technique allows us to identify the resonant modes. The results show good agreement with numerical mode simulations. © 2012 American Institute of Physics.SCOPUS: ar.jinfo:eu-repo/semantics/publishe

Tuning the postfocused size of colloidal nanocrystals by the reaction rate

We show that adjusting the reaction rate in a hot injection synthesis is a viable strategy to tune the diameter of colloidal nanocrystals at the end of the size distribution focusing, i.e., the postfocused diameter. Our approach is introduced by synthesis simulations, which describe nucleation and growth of colloidal nanocrystals from a solute or monomer that is formed in situ out of the injected precursors. These simulations indicate that the postfocused diameter is reached at almost full yield and that it can be adjusted by the rate of monomer formation. We implement this size-tuning strategy using a particular CdSe quantum dot synthesis that shows excellent agreement with the model synthesis. After demonstrating that the reaction rate depends in first order on the Cd and Se precursor concentration, the proposed strategy of size control is explored by varying the precursor concentration. This enables the synthesis of colloidal nanocrystals with a predefined size at almost full yield and sharp size distributions with diameters ranging from 2.8 to 4.1 nm. In addition, we demonstrate that the same tuning strategy applies to the synthesis of CdS quantum dots. This result is highly relevant especially in the context of reaction upscaling and automation. Moreover, the results obtained challenge the traditional interpretation of the hot injection synthesis, in particular the link between hot injection, burst nucleation, and sharp size distributions