53 research outputs found
The phase of iron catalyst nanoparticles during carbon nanotube growth
We study the Fe-catalyzed chemical vapor deposition of carbon nanotubes by complementary in situ grazing-incidence X-ray diffraction, in situ X-ray reflectivity, and environmental transmission electron microscopy. We find that typical oxide supported Fe catalyst films form widely varying mixtures of bcc and fcc phased Fe nanoparticles upon reduction, which we ascribe to variations in minor commonly present carbon contamination levels. Depending on the as-formed phase composition, different growth modes occur upon hydrocarbon exposure: For γ-rich Fe nanoparticle distributions, metallic Fe is the active catalyst phase, implying that carbide formation is not a prerequisite for nanotube growth. For α-rich catalyst mixtures, Fe3C formation more readily occurs and constitutes part of the nanotube growth process. We propose that this behavior can be rationalized in terms of kinetically accessible pathways, which we discuss in the context of the bulk iron–carbon phase diagram with the inclusion of phase equilibrium lines for metastable Fe3C. Our results indicate that kinetic effects dominate the complex catalyst phase evolution during realistic CNT growth recipes.S.H. acknowledges funding from ERC grant InsituNANO (No.
279342). We acknowledge the European Synchrotron
Radiation Facility (ESRF) for provision of synchrotron
radiation facilities. We acknowledge the use of facilities within
the LeRoy Eyring Center for Solid State Science at Arizona
State University. C.T.W. and C.S.E. acknowledge funding from
the EC project Technotubes. A.D.G. acknowledges funding
from the Marshall Aid Commemoration Commission and the
National Science Foundation. R.S.W. acknowledges funding
from EPSRC (Doctoral training award) and B.C.B. acknowledges
a Research Fellowship at Hughes Hall, Cambridge.This is the accepted manuscript. The final version is available from ACS at http://pubs.acs.org/doi/abs/10.1021/cm301402g
Fluorescence detector cell for use in an integrated electrically driven separation system Citation for published version (APA): Fluorescence detector cell for use in an integrated electrically driven separation system
ABSTRACT An integrated design for electrically driven separations is presented. The injector, column and detector are all located within the same cartridge, allowing for integral thermostating and short column lengths. Results on the performance of the proposed fluorescence detector are reported. Molar amounts as low as 2.10-r' mol of fluorescein (IOO-pl detector eel1 volume) can be detected. Short column lengths permit very fast separations, as is demonstrated by the separation of four laser dyes within 35 s
- …