Alane adsorption and dissociation on the Si(001) surface

We used DFT to study the energetics of the decomposition of alane, AlH3, on the Si(001) surface, as the acceptor complement to PH3. Alane forms a dative bond with the raised atoms of silicon surface dimers, via the Si atom lone pair. We calculated the energies of various structures along the pathway of successive dehydrogenation events following adsorption: AlH2, AlH and Al, finding a gradual, significant decrease in energy. For each stage, we analyse the structure and bonding, and present simulated STM images of the lowest energy structures. Finally, we find that the energy of Al atoms incorporated into the surface, ejecting a Si atom, is comparable to Al adatoms. These findings show that Al incorporation is likely to be as precisely controlled as P incorporation, if slightly less easy to achieve.Comment: Submitted to J. Phys.: Condens. Matte

Recent Changes in State and Local Funding for Education in Georgia

This report examines how the 2001 recession affected K-12 education spending in Georgia school systems. FRC Report 20

The Price Effect of Georgia's Temporary Suspension of State Fuel Taxes

This report explores the effect of the fuel tax suspension on the price of gasoline in Georgia. FRC Report 14

Conflicts in the learning of real numbers and limits

question: "Is 0.999... (nought point nine recurring) equal to one, or just less than one?". Many answers contained infinitesimal concepts: "The same, because the difference between them is infinitely small." " The same, for at infinity it comes so close to one it can be considered the same." "Just less than one, but it is the nearest you can get to one without actually saying it is one." "Just less than one, but the difference between it and one is infinitely small." The majority of students thought that 0.999... was less than one. It may be that a few students had been taught using infinitesimal concepts, or that the phrase “just less than one ” had connotations for the students different from those intended by the questioner; but it seems more likely that the answers represent the students ’ own rationalisations made in an attempt to resolve conflicts inherent in the students ’ previous experience of limiting processes. Some conscious and subconscious conflicts Most of the mathematics met in secondary school consists of sophisticated idea

Ethnic Disparities in Sentencing and the Washington Sentencing Reform Act: The Case of Yakima County

An important issue confronting the criminal justice system is sentencing disparity. Sentencing disparity involves inequitable sanctions imposed on individuals who have committed similar offenses. These inequalities in sentencing patterns have allegedly centered on group differences and may reflect an ethnic or racial bias

Recent Changes in State and Local Funding for Education in Georgia - Brief

This report examines how the 2001 recession affected K-12 education spending in Georgia school systems. FRC Brief 20

The Price Effect of Georgia's Temporary Suspension of State Fuel Taxes - Brief

This report explores the effect of the fuel tax suspension on the price of gasoline in Georgia. FRC Brief 14

A ship-based methodology for high precision atmospheric oxygen measurements and its application in the Southern Ocean region

A method for achieving continuous high precision measurements of atmospheric O-2 is presented based on a commercially available fuel-cell instrument, (Sable Systems, Oxzilla FC-II) with a precision of 7 per meg (approximately equivalent to 1.2 ppm) for a 6-min measurement. The Oxzilla was deployed on two voyages in the Western Pacific sector of the Southern Ocean, in February 2003 and in April 2004, making these the second set of continuous O-2 measurements ever made from a ship. The results show significant temporal variation in O-2, in the order of +/- 10 per meg over 6-hourly time intervals, and substantial spatial variation. Data from both voyages show an O-2 maximum centred on 50 degrees S, which is most likely to be the result of biologically driven O-2 outgassing in the region of subtropical convergence around New Zealand, and a decreasing O-2 trend towards Antarctica. O-2 from the ship-based measurements is elevated compared with measurements from the Scripps Institution of Oceanography flask-sampling network, and the O-2 maximum is also not captured in the network observations. This preliminary study shows that ship-based continuous measurements are a valuable addition to current fixed site sampling programmes for the understanding of ocean-atmosphere O-2 exchange processes. [References: 39