Characterisation of fly ashes from 4th Thermal Power Station of Ulaanbaatar city and its applicability for a zeolite synthesis

Fly ash from 4th thermal power station of Ulaanbaatar city have been characterised by x-ray fluorescence (XRF), x-ray diffractometry (XRD), particle size analyzer, specific surface area measurement (BET) and scanning electron microscope (SEM) observation. It was found that fly ash from Baganuur coal contains over 15 wt.% of calcium oxide (CaO) and could be assigned as class C fly ash, according to the International classification. Specific surface area of this fly ash was 2.75 m2/g and mean particle diameter was 59.5 μm. Zeolitic compounds were synthesised by using mixture of this fly ash and a transition aluminium oxide under hydrothermal treatment at 100, 150 and 200°C temperatures for a different duration. Various zeolitic compounds including Na-faujasite and sodium aluminosilicate were synthesised as reaction products.DOI: http://dx.doi.org/10.5564/mjc.v12i0.164 Mongolian Journal of Chemistry Vol.12 2011: 16-19

Characterization of ash pond ashes from 3rd thermal power plant by SEM/EDX and XRD methods

  Coal combustion by products from ash pond of 3rdthermal power plant of Ulaanbaatar city have been collected in 2010 and 2013 years. The ash samples have been characterized by XRD, XRF and SEM-EDX methods in order to evaluate their chemical and mineralogical composition changes with disposed times. The mineralogical composition of ash varies with time though the chemical composition of the ashes were close each other. Possibly, inefficient operating condition of the TPS shows influence on the mineralogical composition.DOI: http://dx.doi.org/10.5564/mjc.v14i0.201Mongolian Journal of Chemistry 14 (40), 2013, p61-6

Preparation of rare earth oxides from Synchysite oxidized ore by acid leaching

Mixed rare earth oxides have been prepared from synchysite ore from the Lugiin gol rare earth deposit (Mongolia) which contains about 6% of cerium light rare earth elements. Ore powders were leached for up to 60 min using 80-120 g/l sulfuric acids at an acid to powder ratio of 20, agitation was performed by magnetic stirring followed by precipitation and calcination at 700°C for 1h. The highest leaching of REEs equal to 85% of the total REE was observed in the acid solution of 80 g/l. Obtained mixed rare earth oxides represent a layered type structure

The mechanochemical activation study of Tsagaan-tsav zeolite

Characterisation of mechanochemically activated Tsagaan-tsav zeolite has been performed. Tsagaan-tsav zeolite has been activated with a vibration mill for 2, 3, 5, 10 and 20 minutes. Ball to powder ratios were varied 1:10, 1:20, 1:50 and 1:100. Efficiency of milling determined based on amorphisation rate and cation exchange capacity changes. The highest efficiency was obtained for zeolite milled with ball to powder ratio of 100. Structural characterisation was performed with XRD, SEM, BET and particle size analyzer. Mechanochemical activation improves cation exchange capacity of natural zeolite.DOI: http://dx.doi.org/10.5564/mjc.v12i0.181 Mongolian Journal of Chemistry Vol.12 2011: 98-101