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    Diethyl­enetriaminium hexa­fluorido­titanate(IV) fluoride

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    The title compound, (C6H21N4)[TiF6]F, was synthesized by the reaction of TiO2, tris­(2-amino­ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF6]2− anions, two fluoride anions and two triply-protonated tris­(2-amino­ethyl)­amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa­hedra. The anions and cations are connected by inter­molecular N—H⋯F hydrogen bonds

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