5 research outputs found
HIV and Hepatitis B and C incidence rates in US correctional populations and high risk groups: a systematic review and meta-analysis
Get PDFSynthesis of Saturated Heterocycles via Metal-Catalyzed Formal Cycloaddition Reactions That Generate a C–N or C–O Bond
Full text linkThe carbonylation of ammonia to urea catalysed by [Ru<sub>3</sub>(CO)<sub>12</sub>]
No full textAmmonia can be carbonylated catalytically to urea under mild conditions of temperature and pressure using [Ru-3(CO)(12)] as catalyst precursor. (C) 1999 Elsevier Science S.A. All rights reserved.</p
On the reduction of rhodium trichloride in the presence of triisopropylphosphine
No full textThe reduction of RhCl3. 3H(2)O by sodium amalgam in the presence of P-i-Pr-3 has been reexamined. Reaction of RhCl3. 3H(2)O with P-i-Pr-3 in THF gives i-Pr3PO and [RhHCl2(P-i-Pr-3)(2)] or [RhDCl2(P-i-Pr-3)(2)] if D2O is added. Further reaction of [RhHCl2(P-i-Pr-3)(2)] with P-i-Pr-3 gives [i-Pr3PH][RhHCl3(P-i-Pr-3)(2)], which reversibly dissociates to [RhHCl2(P-i-Pr-3)(2)] and [i-Pr3PH]Cl at high temperatures in solution. Sodium amalgam reduction of [RhHCl2(P-i-Pr-3)(2)] in THF containing P-i-Pr-3 gives [RhH(P-i-Pr-3)(3)] if water is rigorously excluded, but [RhH2Cl(P-i-Pr-3)(2)] if water is present.</p
