Internet-based medical education: a realist review of what works, for whom and in what circumstances

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Modelling and parameter estimation of diethyl phthalate partitioning behaviour on glass and aluminum surfaces

The knowledge of the partitioning behaviour of semi-volatile organic compounds (SVOCs), such as phthalates, between different materials and their surrounding air is of extreme importance for quantifying levels of human exposure to these compounds, which have been associated with adverse health effects. Phthalates’ partitioning behaviour also represents a key property for modelling and assessing polymer degradation mechanisms associated with plasticiser loss. However, the characterisation of phthalates partitioning behaviour has been reported only for a limited number of compounds, mainly involving di-2-ethylhexyl phthalate (DEHP), di-isononyl phthalate (DINP) and di-isodecyl phtahalate (DIDP), while the characterisation of diethyl phthalate (DEP) partitioning has been overlooked. As one of the first plasticisers employed in the production of semi-synthetic plastics produced industrially in the late 19th and early 20th century, DEP plays an important role for understanding stability issues associated with historically significant artefacts in museum collections and archives. Here we show that the partitioning behaviour of DEP between borosilicate glass and aluminum surfaces and their surrounding air can be described by an exponential function of temperature, presenting a model to describe this relationship for the first time. Model parameters are estimated using nonlinear regression from experimental measurements acquired using 109 samples which have been equilibrated at different temperatures between 20 and 80 °C in sealed environments. Measured partition coefficients have been predicted accurately by our proposed model. The knowledge of DEP equilibrium distribution between adsorptive surfaces and neighbouring environments will be relevant for developing improved mathematical descriptions of degradation mechanisms related to plasticiser loss

Equilibrium distribution of diethyl phthalate plasticiser in cellulose acetate-based materials: Modelling and parameter estimation of temperature and composition effects

Understanding the transport and fate of semi-volatile organic compounds (SVOCs) such as phthalates in indoor environments is fundamental for quantifying levels of human exposure and preventing adverse health effects. In this context, the partition coefficient of phthalates between indoor built materials and/or consumer goods and the surrounding atmosphere represents a key parameter for determining concentration distributions. Partition coefficients are also of fundamental importance for describing degradation phenomena associated with plasticiser loss from polymeric materials. However, this key parameter has only been determined for a limited number of systems and environmental conditions. Here, we assess the partitioning behaviour of the diethyl phthalate (DEP) plasticiser in cellulose acetate (CA)-based materials for the first time, determining the effects of temperature and plasticiser composition on equilibrium distributions at temperatures between 20 and 80 °C and using CA samples with DEP contents ranging from 6 to 22 wt%. Additionally, we propose a model to describe and quantify the effect of temperature and plasticiser composition, with model parameters being estimated using non-linear regression and measurements from 130 distinct experiments. Finally, we assess the suitability of our developed model to simulate the migration of DEP from CA-based materials

Writing in Britain and Ireland, c. 400 to c. 800

No abstract available

Gas Dynamics and Star Formation in the Galaxy Pair NGC1512/1510

(abridged) Here we present HI line and 20-cm radio continuum data of the nearby galaxy pair NGC1512/1510 as obtained with the Australia Telescope Compact Array. These are complemented by GALEX UV-, SINGG Halpha- and Spitzer mid-infrared images, allowing us to compare the distribution and kinematics of the neutral atomic gas with the locations and ages of the stellar clusters within the system. For the barred, double-ring galaxy NGC1512 we find a very large HI disk, about 4x its optical diameter, with two pronounced spiral/tidal arms. Both its gas distribution and the distribution of the star-forming regions are affected by gravitational interaction with the neighbouring blue compact dwarf galaxy NGC1510. The two most distant HI clumps, at radii of about 80 kpc, show signs of star formation and are likely tidal dwarf galaxies. Star formation in the outer disk of NGC1512 is revealed by deep optical- and two-color ultraviolet images. Using the latter we determine the properties of about 200 stellar clusters and explore their correlation with dense HI clumps in the even larger 2XHI disk. The multi-wavelength analysis of the NGC1512/1510 system, which is probably in the first stages of a minor merger having started about 400 Myr ago, links stellar and gaseous galaxy properties on scales from one to 100 kpc.Comment: accepted in MNRAS (please find the high-resolution pdf file and further information at http://www.atnf.csiro.au/people/bkoribal/ngc1512

New perspective on plastics cleaning: assessing the impact of laser cleaning on cellulose acetate

A 2019 UCL survey at Tate (Lee et al. 2023) and the 2008-2012 project POPART (EU 7th Framework Programme project Preservation of Plastic Artefacts in Museum Collections) showed that dust and ingrained dirt are common causes of damage to plastic museum objects. Cleaning strategies for plastics are currently limited and not completely effective (due to sensitivity to aqueous and solvent-based systems, permanence of residues and potential mechanical damage caused by the cleaning process itself). Even though laser technology has been exploited successfully for cleaning heritage objects for more than thirty years, its use on plastics remains relatively unexplored. This study will help understand the impact of Nd:YAG laser radiation at 1064 nm on both clear and artificially soiled plasticised cellulose acetate undergoing accelerated ageing conditions (70°C, 80% relative humidity), as well as no accelerated ageing. The surface appearance, colour and chemical composition (namely plasticiser content and degree of substitution) of the irradiated samples were assessed through optical microscopy, visible spectrophotometry/colourimetry and attenuated total reflectance Fourier-transform infrared spectroscopy. The results showed satisfactory cleaning efficiency and no detectable chemical changes in the polymer due to the laser. This suggests that lasers can play a role in cleaning plastics, especially when traditional methods are unsuitable