Multiple Palaeoproterozoic carbon burial episodes and excursions

Organic-rich rocks (averaging 2–5% total organic carbon) and positive carbonate-carbon isotope excursions (View the MathML source and locally much higher, i.e. the Lomagundi-Jatuli Event) are hallmark features of Palaeoproterozoic successions and are assumed to archive a global event of unique environmental conditions following the c. 2.3 Ga Great Oxidation Event. Here we combine new and published geochronology that shows that the main Palaeoproterozoic carbon burial episodes (CBEs) preserved in Russia, Gabon and Australia were temporally discrete depositional events between c. 2.10 and 1.85 Ga. In northwest Russia we can also show that timing of the termination of the Lomagundi-Jatuli Event may have differed by up to 50 Ma between localities, and that Ni mineralisation occurred at c. 1920 Ma. Further, CBEs have traits in common with Mesozoic Oceanic Anoxic Events (OAEs); both are exceptionally organic-rich relative to encasing strata, associated with contemporaneous igneous activity and marked by organic carbon isotope profiles that exhibit a stepped decrease followed by a stabilisation period and recovery. Although CBE strata are thicker and of greater duration than OAEs (100 s of metres versus metres, ∼106 years versus ∼105 years), their shared characteristics hint at a commonality of cause(s) and feedbacks. This suggests that CBEs represent processes that can be either basin-specific or global in nature and a combination of circumstances that are not unique to the Palaeoproterozoic. Our findings urge circumspection and re-consideration of models that assume CBEs are a Deep Time singularity

Hydrothermal dedolomitisation of carbonate rocks of the Paleoproterozoic Zaonega Formation, NW Russia — Implications for the preservation of primary C isotope signals

This study was supported by Estonian Science Agency project PUT696 and PRG447, and Estonian Centre of Analytical Chemistry. K.P. and A.L. were supported by the Research Council of Norway through its Centres of Excellence funding scheme grant No. 223259.The Paleoproterozoic Zaonega Formation in Karelia, NW Russia, has played a key role in understanding the environmental conditions postdating the Great Oxidation and Lomagundi-Jatuli Events. Its carbonate- and organic-rich rocks (shungite) define the postulated Shunga Event representing an accumulation of very organic-rich sediments at c. 2 Ga and are central in ideas about changing ocean-atmosphere composition in the wake of those worldwide biogeochemical phenomena. Our work focussed on a key interval of carbonate rocks in the upper part of the Formation to: (i) obtain new high-resolution carbon, oxygen and strontium isotope data complemented by detailed petrography and mineralogical characterisation and (ii) expand upon previous studies by using our data to constrain geochemical modelling and show in greater detail how magmatic hydrothermal fluids induced dedolomitisation and altered geochemical signals. Our findings show that the δ13Ccarb of calcite-rich intervals are the most altered, with values between −16.9 to 0.6‰, whereas the dolomite-dominated parts retain the best-preserved (i.e. most original) values. Those define a trend of steadily increasing δ13Ccarb, from −6 to +0.5‰, which we interpret as a return to normal marine conditions and carbonate‑carbon values following the Lomagundi-Jatuli Event.PostprintPeer reviewe

The grandest of them all : the Lomagundi-Jatuli Event and Earth's oxygenation

Funding: K.K., A.L. and T.K. received funding from Estonian Science Agency Project PRG447 and Yu.D., A.R., D.R. and P.M. were supported by the state assignment of the Institute of Geology, Karelian Research Centre of the Russian Academy of Sciences.The Paleoproterozoic Lomagundi–Jatuli Event (LJE) is generally considered the largest, in both amplitude and duration, positive carbonate C-isotope (δ13Ccarb) excursion in Earth history. Conventional thinking is that it represents a global perturbation of the carbon cycle between 2.3–2.1 Ga linked directly with, and in part causing, the postulated rise in atmospheric oxygen during the Great Oxidation Event. In addition to new high-resolution δ13Ccarb measurements from LJE-bearing successions of NW Russia, we compiled 14 943 δ13Ccarb values obtained from marine carbonate rocks 3.0–1.0 Ga in age and from selected Phanerozoic time intervals as a comparator of the LJE. Those data integrated with sedimentology show that, contra to consensus, the δ13Ccarb trend of the LJE is facies (i.e. palaeoenvironment) dependent. Throughout the LJE interval, the C-isotope composition of open and deeper marine settings maintained a mean δ13Ccarb value of +1.5 ± 2.4‰, comparable to those settings for most of Earth history. In contrast, the 13C-rich values that are the hallmark of the LJE are limited largely to nearshore-marine and coastal-evaporitic settings with mean δ13Ccarb values of +6.2 ± 2.0‰ and +8.1 ± 3.8‰, respectively. Our findings confirm that changes in δ13Ccarb are linked directly to facies changes and archive contemporaneous dissolved inorganic carbon pools having variable C-isotopic compositions in laterally adjacent depositional settings. The implications are that the LJE cannot be construed a priori as representative of the global carbon cycle or a planetary-scale disturbance to that cycle, nor as direct evidence for oxygenation of the ocean–atmosphere system. This requires rethinking models relying on those concepts and framing new ideas in the search for understanding the genesis of the grandest of all positive C-isotope excursions, its timing and its hypothesized linkage to oxygenation of the atmosphere.Publisher PDFPeer reviewe

Abundant marine calcium suplhates: radical change of seawater sulphate reservoir and sulphur cycle

The modern (pre-industrial) ocean is characterised by a concentration of dissolved sulphate of 28 mM with little variability in its horizontal or vertical distribution. This homogeneity is a consequence of the long residence time of sulphate of some 25 Ma in comparison to the present ocean mixing time of 1,000–2,000 years (e.g. Holland 1984)

Multiple Palaeoproterozoic carbon burial episodes and excursions

Organic-rich rocks (averaging 2–5% total organic carbon) and positive carbonate-carbon isotope excursions (δ13C > 5‰ and locally much higher, i.e. the Lomagundi-Jatuli Event) are hallmark features of Palaeoproterozoic successions and are assumed to archive a global event of unique environmental conditions following the c. 2.3 Ga Great Oxidation Event. Here we combine new and published geochronology that shows that the main Palaeoproterozoic carbon burial episodes (CBEs) preserved in Russia, Gabon and Australia were temporally discrete depositional events between c. 2.10 and 1.85 Ga. In northwest Russia we can also show that timing of the termination of the Lomagundi-Jatuli Event may have differed by up to 50 Ma between localities, and that Ni mineralisation occurred at c. 1920 Ma. Further, CBEs have traits in common with Mesozoic Oceanic Anoxic Events (OAEs); both are exceptionally organic-rich relative to encasing strata, associated with contemporaneous igneous activity and marked by organic carbon isotope profiles that exhibit a stepped decrease followed by a stabilisation period and recovery. Although CBE strata are thicker and of greater duration than OAEs (100 s of metres versus metres, ∼106 years versus ∼105 years), their shared characteristics hint at a commonality of cause(s) and feedbacks. This suggests that CBEs represent processes that can be either basin-specific or global in nature and a combination of circumstances that are not unique to the Palaeoproterozoic. Our findings urge circumspection and re-consideration of models that assume CBEs are a Deep Time singularity

Hydrothermal dedolomitisation of carbonate rocks of the Paleoproterozoic Zaonega Formation, NW Russia — Implications for the preservation of primary C isotope signals

The Paleoproterozoic Zaonega Formation in Karelia, NW Russia, has played a key role in understanding the environmental conditions postdating the Great Oxidation and Lomagundi-Jatuli Events. Its carbonate- and organic-rich rocks (shungite) define the postulated Shunga Event representing an accumulation of very organic-rich sediments at c. 2 Ga and are central in ideas about changing ocean-atmosphere composition in the wake of those worldwide biogeochemical phenomena. Our work focussed on a key interval of carbonate rocks in the upper part of the Formation to: (i) obtain new high-resolution carbon, oxygen and strontium isotope data complemented by detailed petrography and mineralogical characterisation and (ii) expand upon previous studies by using our data to constrain geochemical modelling and show in greater detail how magmatic hydrothermal fluids induced dedolomitisation and altered geochemical signals. Our findings show that the δ13Ccarb of calcite-rich intervals are the most altered, with values between −16.9 to 0.6‰, whereas the dolomite-dominated parts retain the best-preserved (i.e. most original) values. Those define a trend of steadily increasing δ13Ccarb, from −6 to +0.5‰, which we interpret as a return to normal marine conditions and carbonate‑carbon values following the Lomagundi-Jatuli Event