1 research outputs found
Electronic and Magnetic Properties of Nanographite Ribbons
Electronic and magnetic properties of ribbon-shaped nanographite systems with
zigzag and armchair edges in a magnetic field are investigated by using a tight
binding model. One of the most remarkable features of these systems is the
appearance of edge states, strongly localized near zigzag edges. The edge state
in magnetic field, generating a rational fraction of the magnetic flux (\phi=
p/q) in each hexagonal plaquette of the graphite plane, behaves like a
zero-field edge state with q internal degrees of freedom. The orbital
diamagnetic susceptibility strongly depends on the edge shapes. The reason is
found in the analysis of the ring currents, which are very sensitive to the
lattice topology near the edge. Moreover, the orbital diamagnetic
susceptibility is scaled as a function of the temperature, Fermi energy and
ribbon width. Because the edge states lead to a sharp peak in the density of
states at the Fermi level, the graphite ribbons with zigzag edges show
Curie-like temperature dependence of the Pauli paramagnetic susceptibility.
Hence, it is shown that the crossover from high-temperature diamagnetic to
low-temperature paramagnetic behavior of the magnetic susceptibility of
nanographite ribbons with zigzag edges.Comment: 13 pages including 19 figures, submitted to Physical Rev