16,173 research outputs found
Estimate of nuclear technology engine test stand sound power and spectrum
Estimate of nuclear technology engine test stand sound power and spectru
Femtosecond probing of bimolecular reactions: The collision complex
Progress has been made in probing the femtosecond
dynamics of transition states of chemical reactions.(1) The
"half-collision" case of unimolecular reactions has been
experimentally investigated for a number of systems and
much theoretical work has already been developed.(2) For
bimolecular reactions, the case of full collision, the zero of
time is a problem which makes the femtosecond temporal
resolution of the dynamics a difficult task
Femtosecond real-time probing of reactions. VIII. The bimolecular reaction Br+I2
In this paper, we discuss the experimental technique for real-time measurement of the lifetimes of the collision complex of bimolecular reactions. An application to the atom–molecule Br+I_2 reaction at two collision energies is made. Building on our earlier Communication [J. Chem. Phys. 95, 7763 (1991)], we report on the observed transients and lifetimes for the collision complex, the nature of the transition state, and the dynamics near threshold. Classical trajectory calculations provide a framework for deriving the global nature of the reactive potential energy surface, and for discussing the real-time, scattering, and asymptotic (product-state distribution) aspects of the dynamics. These experimental and theoretical results are compared with the extensive array of kinetic, crossed beam, and theoretical studies found in the literature for halogen radical–halogen molecule exchange reactions
Method of statistical filtering
Minimal formula for bounding the cross correlation between a random forcing function and the state error when this correlation is unknown is used in optimal linear filter theory applications. Use of the bound results in overestimation of the estimation-error covariance
Toward an accurate mass function for precision cosmology
Cosmological surveys aim to use the evolution of the abundance of galaxy
clusters to accurately constrain the cosmological model. In the context of
LCDM, we show that it is possible to achieve the required percent level
accuracy in the halo mass function with gravity-only cosmological simulations,
and we provide simulation start and run parameter guidelines for doing so. Some
previous works have had sufficient statistical precision, but lacked robust
verification of absolute accuracy. Convergence tests of the mass function with,
for example, simulation start redshift can exhibit false convergence of the
mass function due to counteracting errors, potentially misleading one to infer
overly optimistic estimations of simulation accuracy. Percent level accuracy is
possible if initial condition particle mapping uses second order Lagrangian
Perturbation Theory, and if the start epoch is between 10 and 50 expansion
factors before the epoch of halo formation of interest. The mass function for
halos with fewer than ~1000 particles is highly sensitive to simulation
parameters and start redshift, implying a practical minimum mass resolution
limit due to mass discreteness. The narrow range in converged start redshift
suggests that it is not presently possible for a single simulation to capture
accurately the cluster mass function while also starting early enough to model
accurately the numbers of reionisation era galaxies, whose baryon feedback
processes may affect later cluster properties. Ultimately, to fully exploit
current and future cosmological surveys will require accurate modeling of
baryon physics and observable properties, a formidable challenge for which
accurate gravity-only simulations are just an initial step.Comment: revised in response to referee suggestions, MNRAS accepte
Imaging Polarimetric Observations of a New Circumstellar Disk System
Few circumstellar disks have been directly observed. Here we use sensitive
differential polarimetric techniques to overcome atmospheric speckle noise in
order to image the circumstellar material around HD 169142. The detected
envelope or disk is considerably smaller than expectations based on the
measured strength of the far-IR excess from this system
Recommended from our members
Alteration and Oxidiation of an Olivine Lamprophyre Dike from Southern Utah, USA: An Analog for Mars
We report on oxidized basaltic dike intrusions on the Colorado Plateau as analog for Martian basalt oxidation
Offspring of parents with recurrent depression: which features of parent depression index risk for offspring psychopathology?
Background: Parental depression is associated with an increased risk of psychiatric disorder in offspring, although outcomes vary. At present relatively little is known about how differences in episode timing, severity, and course of recurrentdepression relate to risk in children. The aim of this study was to consider the offspring of parents with recurrentdepression and examine whether a recent episode of parental depressionindexesrisk for offspringpsychopathology over and above these other parental depressionfeatures.
<p/>Methods: Three hundred and thirty seven recurrently depressed parents and their offspring (aged 9–17) were interviewed as part of an ongoing study, the ‘Early Prediction of Adolescent Depression Study’. The Child and Adolescent Psychiatric Assessment was used to assess two child outcomes; presence of a DSM-IV psychiatric disorder and number of DSM-IV child-rated depression symptoms.
<p/>Results: Children whose parents had experienced a recent episode of depression reported significantly more depression symptoms, and odds of child psychiatric disorder were doubled relative to children whose parents had not experienced a recent episode of depression. Past severity of parental depression was also significantly associated with child depression symptoms.
<p/>Limitations: Statistical analyses preclude causal conclusions pertaining to parental depression influences on offspringpsychopathology; several features of parental depression were recalled retrospectively.
<p/>Conclusions: This study suggests that particular features of parental depression, specifically past depression severity and presence of a recent episode, may be important indicators of risk for child psychiatric disorder and depressive symptoms
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