19 research outputs found

    Can We Optimize Arc Discharge and Laser Ablation for Well-Controlled Carbon Nanotube Synthesis?

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    On the determination of the mechanical properties of wind turbine blades: Geometrical aspects of line based algorithms

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    This paper discusses the aspects relating the geometric discretization of anisotropic wind turbine blade cross sections via line elements and the calculation of its mechanical properties. The geometrical reconstruction of the blade is done through an algorithm that reads a table that contains the representation of the aerodynamic profile of the blade as a set of connected line segments. The composite material theoretical background is based on a vector variant of the classical lamination theory embedded into a geometrically exact large deformation-small strain thin-walled beam formulation; transverse shear and out of plane warping effects are considered. The impact of the geometric reconstruction in the accuracy of the mechanical properties is studied using both rectangular and trapezoidal elements. It is found that a proper geometrical reconstruction of the cross section must be ensured to obtain small errors in the mechanical properties. It is shown that line based algorithms can give very accurate results provided the cross section geometry is adequately represented.Fil: Saravia, César Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca; Argentina. Universidad Tecnológica Nacional. Facultad Regional Bahía Blanca; ArgentinaFil: Gattia, Claudio D.. Universidad Tecnológica Nacional. Facultad Regional Bahía Blanca; ArgentinaFil: Ramireza, José M.. Universidad Tecnológica Nacional. Facultad Regional Bahía Blanca; Argentin

    Hydrogenation-induced microstructure evolution in as cast and severely deformed Mg-10 wt.% Ni alloy

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    We determined the kinetics of hydrogen absorption of the hypoeutectic Mg-10 wt.% Ni alloy in the as-cast state and after processing by four passes of equal channel angular pressing(ECAP). While during the first hydrogenation cycle the ECAP-modified alloy exhibited faster absorption than its as-cast counterpart, this advantage was lost after the second hydrogenation cycle; parity was regained after six cycles. We attributed these differences in the hydrogen absorption kinetics to the formation of large (tens of micrometers) faceted Mg crystals observed during the first hydrogenation cycle. These crystals were significantly larger in the ECAP-modified alloy than in its as-cast counterpart. Wediscussed the growth of large Mg crystals during hydrogenation in terms of self-diffusion of Mg atoms driven by the metal-hydride transformation stress. The larger size of these crystals in the ECAP-processed alloy was attributed to the acceleration of diffusion by ECAP. Our metallographic studies revealed a number of microstructural changes in the alloys upon hydrogenation, such as cracking, accumulation of plastic strain in large Mg crystals, and re-distribution of the dispersed particles of Mg2Ni phase in the partly hydrogenated alloys

    Improvement of DMFC electrode kinetics by using nanohorns catalyst support

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    One of the factors limiting direct methanol fuel cells (DMFC) performance is the slow kinetics of methanol oxidation at the anode. The importance of the catalyst support for fuel cells has been recognized and different forms of carbon have been suggested. Single wall nanohorns (SWNH) are a new class of carbon with a similar graphitic structure of carbon nanotubes. They are self-assembling materials that produce aggregates of about 100 nm. In the present study, the comparison of the performance of a DMFC equipped with electrocatalysts supported on a commercial carbon black and on SWNH was carried out. The SWNH were synthesized by the arc discharge method in air. The deposition of the Pt and Pt/Ru catalysts on the carbon supports was accomplished by using ethylene glycol as reducing agent. The synthesized catalyst nanoparticles have a very small diameter size (ca. 2.5 nm) and they are uniformly distributed on both carbon supports. The supported electrode catalysts were tested in a DMFC and results indicate that employing SWNH is very promising showing catalytic activities 60 % higher. © (2010) Trans Tech Publications
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