44 research outputs found
Modelization of flow electrification in a polymer melt
Flow electrification of polymer melts is an important side effect of polymer
processing. The studies dealing with this phenomenon are seldom and most of the
scientific work has been focused on flow electrification of aqueous and
insulating Newtonian liquids. From that prior art it is well established that
the flow electrification in Newtonian liquids is a consequence of the formation
of an ionic double layer. Convection of this layer induces the electrification
of the liquid at the outlet of the pipe. In those models, the key parameters
governing the flow electrification are thus the intrinsic electrical properties
of the polymer and the flow characteristics. In this work, we reconsider the
assumptions made previously and we propose a new approach to modelise the flow
electrification in the particular case of non-Newtonian polymer materials in
laminar flow conditions. We establish that, a key parameter for the
electrification quantification in the polymer melt is the shape of the velocity
profile. Additionally, in some cases, we show that a slip velocity at the
polymer/die wall interface must be considered to describe accurately the
electrification. As a consequence, we deduce that the slip velocity at the
interface can be calculated by measuring the electrification: this work gives
an alternative manner to measure the slip velocity during polymer flow
Polypropylene/polyhydroxybutyrate(pp/phb) blends: preparation of a grafted copolymer and its use as surface-active agent
Linear viscoelasticity of incompatible polymer blends in the melt in relation with interfacial properties
A quite general characteristic of the rheology of incompatible polymer blends in the melt is their highly elastic behaviour at low fiequencies, corresponding to long-time relaxation processes. For emulsions of Newtonian liquids, this property can be readily connected to interfacial tension α : in a macroscopic flow, suspended droplets of radius R are subjected on the one hand to a viscous drag related to the viscosity µm of the matrix liquid and tending to deform their shape, and on the other hand to an elastic force of the order of α/R opposing the deformation. From a rheological point of view, the emulsion shows viscoelastic behaviour with characteristic relaxation times of the order of µmR/α. Blends of incompatible uncrosslinked polymers in the molten state can also be considered as emulsions, but the behaviour of the phases becomes viscoelastic by itself. A recent model, which accounts for the viscoelasticity of the phases, the polydispersity in size of the droplets and their hydrodynamic interactions, allowed us to explain the linear viscoelasticity of some selected polymer blends