Spectroscopic and in vitro investigations of boron(III) complex with meso-4-methoxycarbonylpropylsubstituted dipyrromethene for fluorescence bioimaging applications

© 2020 by the authors. This study focuses on the behavior of a new fluorescent marker for labeling individual biomolecules and staining cell organelles developed on a meso-substituted BODIPY platform. Boron(III) complex with meso-4-methoxycarbonylpropylsubstituted 3,3',5,5'-tetramethyl-2,20- dipyrromethene has been synthesized and identified via visible, UV-, NMR- and MS-spectra X-ray. The behavior of fluorophore in solutions has been studied with various experimental techniques. It has been found that luminophore exhibits a high quantum yield (almost ∼100-75%) in the blue-green region (513-520 nm) and has high photostability. In addition, biological analysis indicates that the fluorophore exhibits a tendency to effectively penetrate into cell membranes. On the other hand, the proposed BODIPY can be used to study the significant differences among a large number of pathogens of mycotic infections, as well as to visualize structural changes in the plasma membrane, which is necessary for the clearance of mammalian cells undergoing apoptotic cell death

Ultrafast Pump-Push Photocurrent Spectroscopy of Organic Photoconversion Systems

Novel optical pump-push – photocurrent probe ultrafast spectroscopy experiments on organic photoconversion systems show that excessive excitation energy in such systems is not lost but used to reach delocalised states that act as the gateway for long-range charge separation. We also show that the developed experimental approach can be generalised to inorganic and hybrid photoconversion systems

Phase locking of a 3.4 THz third-order distributed feedback quantum cascade laser using a room-temperature superlattice harmonic mixer

<p>We report on the phase locking of a 3.4 THz third-order distributed feedback quantum cascade laser (QCL) using a room temperature GaAs/AlAs superlattice diode as both a frequency multiplier and an internal harmonic mixer. A signal-to-noise level of 60 dB is observed in the intermediate frequency signal between the 18th harmonic of a 190.7 GHz reference source and the 3433 GHz QCL. A phase-lock loop with 7MHz bandwidth results in QCL emission that is 96% locked to the reference source. We characterize the QCL temperature and electrical tuning mechanisms and show that frequency dependence of these mechanisms can prevent phase-locking under certain QCL bias conditions. (C) 2013 AIP Publishing LLC.</p>