Pattern forming instability induced by light in pure and dye-doped nematic liquid crystals

We study theoretically the instabilities induced by a linearly polarized ordinary light wave incident at a small oblique angle on a thin layer of homeotropically oriented nematic liquid crystal with special emphasis on the dye-doped case. The spatially periodic Hopf bifurcation that occurs as the secondary instability after the stationary Freedericksz transition is analyzed.Comment: 8 pages, 7 figures, LaTeX, accepted to Phys. Rev.

Miniaturization of molecular conjugated systems for organic solar cells: towards pigmy donors

Organic solar cells with short-circuit current densities and conversion efficiencies of ca. 7.0 mA cm(-2) and 2.0%, respectively, have been fabricated with a very small molecular donor based on substituted triarylamines

Organic dye for dye-sensitized solar cell

Organic dye for a dye-sensitized solar cell (DSSC) comprising at least one electron-acceptor unit and at least one π-conjugated unit. Said organic dye is particularly useful in a dye-sensitized photoelectric transformation element which, in its turn, can be used in a dye-sensitized solar cell (DSSC)

Strain induced pressure effect in pulsed laser deposited thin films of the strongly correlated oxide V2O3

V2O3 thin films about 10 nm thick were grown on Al2O3 (0001) by pulsed laser deposition. The XRD analysis is in agreement with R-3c space group. Some of them exhibit the metal / insulator transition characteristic of V2O3 bulk material and others samples exhibit a metallic behavior. For the latter, the XPS analysis indicates an oxidation state of +III for vanadium. There is no metal / insulator transition around 150 K in this sample and a strongly correlated Fermi liquid rho = AT2 behavior of the resistivity at low temperature is observed, with a value of A of 1.2 10-4 ohm cm, 3 times larger than the bulk value at 25 kbar

Poly(thiophenes) derivatized with linear and macrocyclic polyethers: from cation detection to molecular actuation

The association of linear or macrocyclic polyethers with the electronic properties of the π-conjugated polythiophene backbone leads to functional conducting polymers that exhibit metal cation dependent electronic properties. Based on this concept, various classes of cation sensors have been proposed and investigated for almost two decades. The interactions of metal cations with linear or macrocyclic polyether functional groups lead to modifications of the electronic properties of the π-conjugated backbone through various mechanisms including direct electronic effects on a single conjugated chain, collective electrochemical processes, or conformational changes. Conjugated polymers and oligomers representative of these various processes are discussed with an emphasis on recent examples of derivatized conjugated systems in which the interactions between metal cations and polyether groups serve as driving force to create molecular motion in conjugated systems

Organic dye for dye-sensitized solar cells

Organic dye for a dye-sensitized solar cell (DSSC) comprising at least one electron-acceptor unit and at least one π-conjugated unit. Said organic dye is particularly useful in a dye-sensitized photoelectric transformation element which, in its turn, can be used in a dye-sensitized solar cell (DSSC)

The situation of horticultural family farms in Hajdu-Bihar County

The main aim of this research work is to study horticultural farms in Hajdú-Bihar County, that mobilize labour and capital for thesake of agricultural production, namely family farms. During this study work we tried to chart the main characters, the conditions offunctioning, their profitability and its use possibilities, their external contacts and the resource of information of these farms, beside this toinvestigate the relationships between these parameters. Parallel to this we tried to compensate the relatively high deficiency of information byempirical research work. This deficiency is the characterization of farmers and the inducement of farming and its conditions both on the levelof county and state. By our empirical research work we have made a comprehensive position paper that shows the conditions of farms andfarmer populations, as well. Two hundred questionnaires were evaluated. The percentages of horticultural farms were 25% from allquestionnaires. Above all this paper is looking for the answer to the following questions: How and by which sources do farmers develop andextent their farms? How do farmers see their own future, what kind of aims do they have?Who will stop and who will go on producing? Thecollected information on the whole may help to make much more flexible legislatives and administrative regulations, although the surveycovered only one county

Structure-properties relationships in triarylamine-based donor-acceptor molecules containing naphtyl groups as donor material for organic solar cells

The effects of replacing the phenyl rings of triphenylamine (TPA) by naphtyl groups are analysed on a series of push-pull molecules containing a 2-thienyl-dicyanovinyl acceptor group. UV-Vis absorption spectroscopy and cyclic voltammetry show that the introduction of one or two naphtyl groups in the structure has limited effects on the optical properties and energy levels of the molecule. On the other hand, the evaluation of the compounds as donor material in bi-layer solar cells with C60 as acceptor shows that the number and mode of linkage of the naphtyl groups exert a marked influence on the power conversion efficiency (PCE) of the cell. Two naphtyl groups lead to a decrease of PCE with respect to TPA, while a single naphtyl group produces opposite effects depending on the linking mode. Compared to TPA, an alpha-naphtyl group leads to a small decrease of PCE while in contrast a beta-naphtyl leads to a ~35% increase of PCE due to improved short-circuit current density (Jsc) and fill-factor. The determination of the hole-mobility of these two donors by the space-charge-limited current method shows that these effects are correlated with the higher hole-mobility of the β-naphtyl compound