Phase Behavior of Colloidal Superballs: Shape Interpolation from Spheres to Cubes

The phase behavior of hard superballs is examined using molecular dynamics within a deformable periodic simulation box. A superball's interior is defined by the inequality $|x|^{2q} + |y|^{2q} + |z|^{2q} \leq 1$, which provides a versatile family of convex particles ($q \geq 0.5$) with cube-like and octahedron-like shapes as well as concave particles ($q < 0.5$) with octahedron-like shapes. Here, we consider the convex case with a deformation parameter q between the sphere point (q = 1) and the cube (q = 1). We find that the asphericity plays a significant role in the extent of cubatic ordering of both the liquid and crystal phases. Calculation of the first few virial coefficients shows that superballs that are visually similar to cubes can have low-density equations of state closer to spheres than to cubes. Dense liquids of superballs display cubatic orientational order that extends over several particle lengths only for large q. Along the ordered, high-density equation of state, superballs with 1 < q < 3 exhibit clear evidence of a phase transition from a crystal state to a state with reduced long-ranged orientational order upon the reduction of density. For $q \geq 3$, long-ranged orientational order persists until the melting transition. The width of coexistence region between the liquid and ordered, high-density phase decreases with q up to q = 4.0. The structures of the high-density phases are examined using certain order parameters, distribution functions, and orientational correlation functions. We also find that a fixed simulation cell induces artificial phase transitions that are out of equilibrium. Current fabrication techniques allow for the synthesis of colloidal superballs, and thus the phase behavior of such systems can be investigated experimentally.Comment: 33 pages, 14 figure

SB9: The Ninth Catalogue of Spectroscopic Binary Orbits

The Ninth Catalogue of Spectroscopic Binary Orbits (http://sb9.astro.ulb.ac.be) continues the series of compilations of spectroscopic orbits carried out over the past 35 years by Batten and collaborators. As of 2004 May 1st, the new Catalogue holds orbits for 2,386 systems. Some essential differences between this catalogue and its predecessors are outlined and three straightforward applications are presented: (1) Completeness assessment: period distribution of SB1s and SB2s; (2) Shortest periods across the H-R diagram; (3) Period-eccentricity relation.Comment: Accepte for publication in A&A, 6 pages, 6 figure

Continuous Commissioning of a Central Chilled Water & Hot Water System

A central chilled water / hot water system provides cooling / heating energy from central utility plants to multiple customers (buildings) through campus distribution loops. To effectively transport the chilled water and hot water to the buildings and control the flow, several types of bypass schemes are used, including air handling unit coil bypass, pump bypass, building loop bypass, distribution loop bypass, and central utility plant decoupling. Most of the bypass schemes are designed to provide comfort to each building without regard for the loop pumping requirements. Continuous Commissioning of the building and campus loops is necessary to ensure adequate water flow to each building and reduce the overall pumping energy required for both the campus loops and the building loops. Some optimization of the plant chiller 1 boiler operation is also necessary and beneficial. In general, through Continuous Commissioning, chilled water and hot water loop temperature differences will be improved, leading to reduced chilled water and hot water flow rates. This will save pumping energy and improve chiller/boiler efficiancy

Unusual magnetic-field dependence of partially frustrated triangular ordering in manganese tricyanomethanide

Manganese tricyanomethanide, Mn[C(CN)3]2, consists of two interpenetrating three-dimensional rutile-like networks. In each network, the tridentate C(CN)3- anion gives rise to superexchange interactions between the Mn2+ ions (S=5/2) that can be mapped onto the "row model" for partially frustrated triangular magnets. We present heat capacity measurements that reveal a phase transition at T_N = 1.18K, indicative of magnetic ordering. The zero-field magnetically ordered structure was solved from neutron powder diffraction data taken between 0.04 and 1.2 K. It consists of an incommensurate spiral with a temperature independent propagation vector Q=(2Q 0 0)=(+/-0.622 0 0), where different signs relate to the two different networks. This corresponds to (+/-0.311 +/-0.311 0) in a quasi-hexagonal representation. The ordered moment mu=3.3mu_B is about 2/3 of the full Mn2+ moment. From the values of T_N and Q, the exchange parameters J/k = 0.15 K and J'/J = 0.749 are estimated. The magnetic-field dependence of the intensity of the Bragg reflection, measured for external fields H||Q, indicates the presence of three different magnetic phases. We associate them with the incommensurate spiral (H < 13.5 kOe), an intermediate phase (13.5 kOe 16 kOe) proposed for related compounds. For increasing fields, Q continuously approaches the value 1/3, corresponding to the commensurate magnetic structure of the fully frustrated triangular lattice. This value is reached at H_c = 19 kOe. At this point, the field-dependence reverses and Q adopts a value of 0.327 at 26 kOe, the highest field applied in the experiment. Except for H_c, the magnetic ordering is incommensurate in all three magnetic phases of Mn[C(CN)3]2.Comment: accepted for publication in J. Phys.: Condens. Matte

Annual variability in the seasonal cycles of chlorophyll, nutrients and zooplankton on the North-West European continental shelf

Seasonal cycles of salinity, nutrients, chlorophyll and zooplankton at 8 locations on the West-European shelf were analysed with respect to their timing and magnitude in the period 1980-1984. A late spring bloom with low chlorophyll values (2-4 mg.m-³) is observed in the Irish Sea, off the Scottish east coast and the Channel entrance. An early spring bloom and relatively high chlorophyll values (7-12 mg.m-³) are found in the southern Bight and the Skagerrak, whereas a late spring bloom with high chlorophyll concentrations (24 mg.m-³) is found along the Dutch and Belgian coast. In contrast to the other regions, the peak of the phytoplankton cycle in the German Bight (Helgoland) occurs in the summer period instead of the spring period. The peak in the yearly abundance of copepods shifts from May-June in the south to July-August in the north of the shelf. In the Irish Sea and the Channel entrance two seasonal copepods peaks are observed. The January nitrate values in Irish Sea, the southern Bight and the Skagerrak are about 20 % higher than those in the Atlantic input signal in the Channel entrance and east off Scotland. The January DIP values in these regions are comparable to those of the input signal, but the Irish Sea forms an exception here the level is increased by 10-20%. If compared with the Atlantic input signal the January values for nitrate and DIP at the Dutch and Belgium coast are about 10 and 4, and in the German Bight (Helgoland) 4 and 3 times higher, respectively. At most sites changes in the seasonal cycles of chorophyll coincide with changes in nutrient concentrations, wheras the maximum level of the seasonal signal is related to the nutrient levels

Fabrication of an Active Electronic Device Using a Hetero-bimetallic Coordination Polymer

A nickel(II)/lead(II) coordination polymer [(NCS)Pb(H2O)LNi(NCS)]n {H2L=N,N′-bis(3-methoxysalicylidene)propane-1,3-diamine} has been synthesized and characterized. The band gap (3.18 eV) calculated from Tauc’s plot suggests the semiconducting nature of the complex. The material has a photosensitivity of 5.76, indicating its applicability in the fabrication of photosensitive devices. The complex has been successfully applied in a technologically challenging thin-film photosensitive Schottky device

SB9: The ninth catalogue of spectroscopic binary orbits

The Ninth Catalogue of Spectroscopic Binary Orbits (http://sb9.astro.ulb.ac.be) continues the series of compilations of spectroscopic orbits carried out over the past 35 years by Batten and collaborators. As of 2004 May 1st, the new Catalogue holds orbits for 2386 systems. Some essential differences between this catalogue and its predecessors are out-lined and three straightforward applications are presented: (1) completeness assessment: period distribution of SB1s and SB2s; (2) shortest periods across the H-R diagram; (3) period-eccentricity relation.Facultad de Ciencias Astronómicas y Geofísica

The HgMn Binary Star Phi Herculis: Detection and Properties of the Secondary and Revision of the Elemental Abundances of the Primary

Observations of the Mercury-Manganese star Phi Herculis with the Navy Prototype Optical Interferometer (NPOI) conclusively reveal the previously unseen companion in this single-lined binary system. The NPOI data were used to predict a spectral type of A8V for the secondary star Phi Her B. This prediction was subsequently confirmed by spectroscopic observations obtained at the Dominion Astrophysical Observatory. Phi Her B is rotating at 50 +/-3 km/sec, in contrast to the 8 km/sec lines of Phi Her A. Recognizing the lines from the secondary permits one to separate them from those of the primary. The abundance analysis of Phi Her A shows an abundance pattern similar to those of other HgMn stars with Al being very underabundant and Sc, Cr, Mn, Zn, Ga, Sr, Y, Zr, Ba, Ce, and Hg being very overabundant.Comment: Accepted to ApJ, 45 pages, 11 figure

Electronic Structure of Transition-Metal Dicyanamides Me[N(CN)2_2]2_2 (Me = Mn, Fe, Co, Ni, Cu)

The electronic structure of Me[N(CN)$_2$]$_2$ (Me=Mn, Fe, Co, Ni, Cu) molecular magnets has been investigated using x-ray emission spectroscopy (XES) and x-ray photoelectron spectroscopy (XPS) as well as theoretical density-functional-based methods. Both theory and experiments show that the top of the valence band is dominated by Me 3d bands, while a strong hybridization between C 2p and N 2p states determines the valence band electronic structure away from the top. The 2p contributions from non-equivalent nitrogen sites have been identified using resonant inelastic x-ray scattering spectroscopy with the excitation energy tuned near the N 1s threshold. The binding energy of the Me 3d bands and the hybridization between N 2p and Me 3d states both increase in going across the row from Me = Mn to Me = Cu. Localization of the Cu 3d states also leads to weak screening of Cu 2p and 3s states, which accounts for shifts in the core 2p and 3s spectra of the transition metal atoms. Calculations indicate that the ground-state magnetic ordering, which varies across the series is largely dependent on the occupation of the metal 3d shell and that structural differences in the superexchange pathways for different compounds play a secondary role.Comment: 20 pages, 11 figures, 2 table