Quantum Metasurfaces

Metasurfaces mold the flow of classical light waves by engineering sub-wavelength patterns from dielectric or metallic thin films. We describe and analyze a method in which quantum operator-valued reflectivity can be used to control both spatio-temporal and quantum properties of transmitted and reflected light. Such a quantum metasurface is realized by preparing and manipulating entangled superposition states of atomically thin reflectors. Specifically, we show that such a system allows for massively parallel quantum operations between atoms and photons and for the generation of highly non-classical states of light, including photonic GHZ and cluster states suitable for quantum information processing. We analyze the influence of imperfections and decoherence, as well as specific implementations based on atom arrays excited into Rydberg states. Finally, the extension to quantum metamaterials and emulations of quantum gravitational background for light are discussed.Comment: 9 comments, 6 figures, Nat. Phys. (2020

Triplet-singlet conversion in ultracold Cs2_2 and production of ground state molecules

We propose a process to convert ultracold metastable Cs$_2$ molecules in their lowest triplet state into (singlet) ground state molecules in their lowest vibrational levels. Molecules are first pumped into an excited triplet state, and the triplet-singlet conversion is facilitated by a two-step spontaneous decay through the coupled $A^{1}\Sigma_{u}^{+} \sim b ^{3}\Pi_{u}$ states. Using spectroscopic data and accurate quantum chemistry calculations for Cs$_2$ potential curves and transition dipole moments, we show that this process has a high rate and competes favorably with the single-photon decay back to the lowest triplet state. In addition, we demonstrate that this conversion process represents a loss channel for vibrational cooling of metastable triplet molecules, preventing an efficient optical pumping cycle down to low vibrational levels