Theory of the Spatial Transfer of Interface-Nucleated Changes of Dynamical Constraints and Its Consequences in Glass-Forming Films

We formulate a new theory for how caging constraints in glass-forming liquids at a surface or interface are modified and then spatially transferred, in a layer-by-layer bootstrapped manner, into the film interior in the context of the dynamic free energy concept of the Nonlinear Langevin Equation theory approach. The dynamic free energy at any mean location involves contributions from two adjacent layers where confining forces are not the same. At the most fundamental level of the theory, the caging component of the dynamic free energy varies essentially exponentially with distance from the interface, saturating deep enough into the film with a correlation length of modest size and weak sensitivity to thermodynamic state. This imparts a roughly exponential spatial variation of all the key features of the dynamic free energy required to compute gradients of dynamical quantities including the localization length, jump distance, cage barrier, collective elastic barrier and alpha relaxation time. The spatial gradients are entire of dynamical, not structural nor thermodynamic, origin. The theory is implemented for the hard sphere fluid and diverse interfaces which can be a vapor, a rough pinned particle solid, a vibrating pinned particle solid, or a smooth hard wall. Their basic description at the level of the spatially-heterogeneous dynamic free energy is identical, with the crucial difference arising from the first layer where dynamical constraints can be weakened, softened, or hardly changed depending on the specific interface. Numerical calculations establish the spatial dependence and fluid volume fraction sensitivity of the key dynamical property gradients for five different model interfaces. Comparison of the theoretical predictions for the dynamic localization length and glassy modulus with simulations and experiments for systems with a vapor interface reveals good agreement.Comment: 17 pages, 11 figures, Accepted on Journal of Chemical Physic

Security assessment of audience response systems using software defined radios

Audience response systems, also known as clickers, are used at many academic institutions to offer active learning environments. Since these systems are used to administer graded assignments, and sometimes even exams, it is crucial to assess their security. Our work seeks to exploit and document potential vulnerabilities of clickers. For this purpose, we use software defined radios to perform eavesdropping attacks on an audience response system in production. The results of our study demon- strate that clickers are easily exploitable. We build a prototype and show that it is practically possible to covertly steal answers from a peer or even the entire classroom, with high levels of confidence. As a result of this study, we discourage using clickers for high-stake assessments, unless manufacturers provide proper security protection.http://people.bu.edu/staro/MIT_Conference_Khai.pdfAccepted manuscrip

Imaging 55^{55}Fe Electron Tracks in a GEM-based TPC Using a CCD Readout

Images of resolved 5.9 keV electron tracks produced from $^{55}$Fe X-ray interactions are presented for the first time using an optical readout time projection chamber (TPC). The corresponding energy spectra are also shown, with the FWHM energy resolution in the 30-40\% range depending on gas pressure and gain. These tracks were produced in low pressure carbon tetrafluoride (CF$_4$) gas, and imaged with a fast lens and low noise CCD camera system using the secondary scintillation produced in GEM/THGEM amplification devices. The GEM/THGEMs provided effective gas gains of $\gtrsim 2 \times 10^5$ in CF$_4$ at low pressures in the 25-100 Torr range. The ability to resolve such low energy particle tracks has important applications in dark matter and other rare event searches, as well as in X-ray polarimetry. A practical application of the optical signal from $^{55}$Fe is that it provides a tool for mapping the detector gain spatial uniformity