Shear and extensional deformation of droplets containing polymers and nanoparticles.

We investigate the effects of polymer chains and nanoparticles on the deformation of a droplet in shear and extensional flow using computational modeling that accounts for both the solid and fluid phases explicitly. We show that under shear flow, both the nanoparticles and the encapsulated polymers reduce the shear-induced deformation of the droplet at intermediate capillary numbers. At high capillary numbers, however, long polymer chains can induce the breakup of the droplet. We find that the latter behavior is dependent on the nature of the imposed flow. Specifically, under extensional flow, long polymers inhibit the droplet breakup and reduce deformation. Overall, the findings provide guidelines for tailoring the stability of filled droplets under an imposed flow, and thus, the results can provide useful design rules in a range of technological applications

Effect of encapsulated polymers and nanoparticles on shear deformation of droplets

Using computational modeling, we investigate the shear response of a droplet that encases a dilute concentration of polymers and nanoparticles. We show that the viscoelastic effects of the encapsulated polymers reduce the shear-induced deformation of the droplet at intermediate capillary numbers, but can induce the breakup of the droplet at high capillary numbers. © 2009 The Royal Society of Chemistry

Effect of encapsulated polymers and nanoparticles on shear deformation of droplets

Using computational modeling, we investigate the shear response of a droplet that encases a dilute concentration of polymers and nanoparticles. We show that the viscoelastic effects of the encapsulated polymers reduce the shear-induced deformation of the droplet at intermediate capillary numbers, but can induce the breakup of the droplet at high capillary numbers. © 2009 The Royal Society of Chemistry