746 research outputs found
Finite lifetime eigenfunctions of coupled systems of harmonic oscillators
We find a Hermite-type basis for which the eigenvalue problem associated to
the operator acting on becomes a three-terms recurrence. Here and are two constant
positive definite matrices with no other restriction. Our main result provides
an explicit characterization of the eigenvectors of that lie in the
span of the first four elements of this basis when .Comment: 11 pages, 1 figure. Some typos where corrected in this new versio
Photonic artificial muscles: From micro robots to tissue engineering
Light responsive shape-changing polymers are able to mimic the function of biological muscles accomplishing mechanical work in response to selected stimuli. A variety of manufacturing techniques and chemical processes can be employed to shape these materials to different length scales, from centimeter fibers and films to 3D printed micrometric objects trying to replicate biological functions and operations. Controlled deformations shown to mimick basic animal operations such as walking, swimming or grabbing objects, while also controlling the refractive index and the geometry of devices, opens up the potential to implement tunable optical properties. Another possibility is that of combining artificial polymers with cells or biological tissue (such as intact cardiac trabeculae) with the aim to improve tissue formation in vitro or to support the mechanical function of damaged biological muscles. Such versatility is afforded by chemistry. New customized liquid crystalline monomers are presented here that modulate material properties for different applications. The role of synthetic material composition is highlighted as we demonstrate how using apparently similar molecular formulations, that liquid crystalline polymers can be adapted to different technological and medical challenges
Dynamic correlation functions and Boltzmann Langevin approach for driven one dimensional lattice gas
We study the dynamics of the totally asymmetric exclusion process with open
boundaries by phenomenological theories complemented by extensive Monte-Carlo
simulations. Upon combining domain wall theory with a kinetic approach known as
Boltzmann-Langevin theory we are able to give a complete qualitative picture of
the dynamics in the low and high density regime and at the corresponding phase
boundary. At the coexistence line between high and low density phases we
observe a time scale separation between local density fluctuations and
collective domain wall motion, which are well accounted for by the
Boltzmann-Langevin and domain wall theory, respectively. We present Monte-Carlo
data for the correlation functions and power spectra in the full parameter
range of the model.Comment: 10 pages, 9 figure
Free-form Light Actuators - Fabrication and Control of Actuation in Microscopic Scale
Liquid crystalline elastomers (LCEs) are smart materials capable of reversible shape-change in response to external stimuli, and have attracted researchers' attention in many fields. Most of the studies focused on macroscopic LCE structures (films, fibers) and their miniaturization is still in its infancy. Recently developed lithography techniques, e.g., mask exposure and replica molding, only allow for creating 2D structures on LCE thin films. Direct laser writing (DLW) opens access to truly 3D fabrication in the microscopic scale. However, controlling the actuation topology and dynamics at the same length scale remains a challenge.
In this paper we report on a method to control the liquid crystal (LC) molecular alignment in the LCE microstructures of arbitrary three-dimensional shape. This was made possible by a combination of direct laser writing for both the LCE structures as well as for micrograting patterns inducing local LC alignment. Several types of grating patterns were used to introduce different LC alignments, which can be subsequently patterned into the LCE structures. This protocol allows one to obtain LCE microstructures with engineered alignments able to perform multiple opto-mechanical actuation, thus being capable of multiple functionalities. Applications can be foreseen in the fields of tunable photonics, micro-robotics, lab-on-chip technology and others
Analysis of isoplanatic high resolution stellar fields by Starfinder code
We describe a new code for the deep analysis of stellar fields, designed for
Adaptive Optics Nyquist-sampled images with high and low Strehl ratio. The
Point Spread Function is extracted directly from the image frame, to take into
account the actual structure of the instrumental response and the atmospheric
effects. The code is written in IDL language and organized in the form of a
self-contained widget-based application, provided with a series of tools for
data visualization and analysis. A description of the method and some
applications to AO data are presented.Comment: 10 pages, 13 figures. Accepted for publication in Astron.& Astrophys.
Sup. Se
StarFinder: an IDL GUI based code to analyze crowded fields with isoplanatic correcting PSF fitting
StarFinder is a new code for the deep analysis of stellar fields, designed
for well-sampled images with high and low Strehl ratio. It is organized in the
form of a self-contained IDL widget-based application, with a 'user-friendly'
graphic interface. We give here a general description of the code along with
some applications to real data with space-invariant Point Spread Function
(PSF). We present also some methods to handle anisoplanatic effects in
wide-field Adaptive Optics (AO)observations.Comment: 9 pages, to to be published on "Proceeedings of Adaptive Optical
Systems Technology",Proc.of SPIE,Vol.4007,2000. In pres
Lipase-Mediated Synthesis of Oleoyl Ethanolamide Starting from High-Oleic Sunflower Oil Soapstock
This work describes the lipase-mediated synthesis of oleoyl ethanolamide, a dietary supplement for body weight loss recently approved by FDA. The target compound is prepared by conversion of the oleic acid contained in a mixture of fatty acids recovered by enzymatic hydrolysis of soapstock, a side-product of high oleic sunflower oil refinement. The use of a packed-bed reactor (a glass column loaded with the commercial lipase Lipozyme 435) in continuous flow mode improves the space-time yield of the reaction and the catalyst productivity. The nontoxic, bioderived, and renewable solvent limonene is used in the reaction medium. The process has been run for more than 157 h of continuous operation, demonstrating the stability and efficiency of the biocatalyst. Additionally, at the end of the reaction, only oleoyl ethanolamide crystallizes from the reaction mixture, thus, it is collected by simple filtration of the outlet solution in 53% isolation yield, showing 99% chemical purity, while all the byproducts of the reaction are left behind in the mother liquors
One-pot multi-enzymatic synthesis of the four stereoisomers of 4-methylheptan-3-ol
The use of pheromones in the integrated pest management of insects is currently considered a sustainable and
environmentally benign alternative to hazardous insecticides. 4-Methylheptan-3-ol is an interesting example of an insect
pheromone, because its stereoisomers are active towards different species. All four possible stereoisomers of this
compd. were prepd. from 4-methylhept-4-en-3-one by a one-pot procedure in which the two stereogenic centers were
created during two sequential redns. catalyzed by an ene-reductase (ER) and an alc. dehydrogenase (ADH), resp
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