Polyamorphism of ice at low temperatures from constant-pressure simulations

We report results of MD simulations of amorphous ice in the pressure range 0 - 22.5 kbar. The high-density amorphous ice (HDA) prepared by compression of Ih ice at T = 80 K is annealed to T = 170 K at intermediate pressures in order to generate relaxed states. We confirm the existence of recently observed phenomena, the very high-density amorphous ice and a continuum of HDA forms. We suggest that both phenomena have their origin in the evolution of the network topology of the annealed HDA phase with decreasing volume, resulting at low temperatures in the metastability of a range of densities.Comment: 11 pages, 5 postscript figures. To be published in Physical Review Letter

A Potential Energy Landscape Study of the Amorphous-Amorphous Transformation in H2_2O

We study the potential energy landscape explored during a compression-decompression cycle for the SPC/E (extended simple point charge) model of water. During the cycle, the system changes from low density amorphous ice (LDA) to high density amorphous ice (HDA). After the cycle, the system does not return to the same region of the landscape, supporting the interesting possibility that more than one significantly different configuration corresponds to LDA. We find that the regions of the landscape explored during this transition have properties remarkably different from those explored in thermal equilibrium in the liquid phase

Comment on "First order amorphous-amorphous transformation in silica"

In a recent letter (Phys. Rev. Lett. 84, 4629 (2000)), Lacks presents evidence of a first order amorphous-amorphous transition in silica at T=0. He calculates the free energy along a path of compression and successive decompression of a sample of 108 SiO2 units. The free energy of the two branches cross each other, and this is interpreted as evidence of a first order transition. We show that this conclusion does not follow from the shown data, since qualitatively the same phenomenology is obtained in a model where a first order transition does not exist.Comment: 1 page, 1 figure, to appear in Phys. Rev. Let

Ice XII in its second regime of metastability

We present neutron powder diffraction results which give unambiguous evidence for the formation of the recently identified new crystalline ice phase[Lobban et al.,Nature, 391, 268, (1998)], labeled ice XII, at completely different conditions. Ice XII is produced here by compressing hexagonal ice I_h at T = 77, 100, 140 and 160 K up to 1.8 GPa. It can be maintained at ambient pressure in the temperature range 1.5 < T < 135 K. High resolution diffraction is carried out at T = 1.5 K and ambient pressure on ice XII and accurate structural properties are obtained from Rietveld refinement. At T = 140 and 160 K additionally ice III/IX is formed. The increasing amount of ice III/IX with increasing temperature gives an upper limit of T ~ 150 K for the successful formation of ice XII with the presented procedure.Comment: 3 Pages of RevTeX, 3 tables, 3 figures (submitted to Physical Review Letters

Interplay Between Time-Temperature-Transformation and the Liquid-Liquid Phase Transition in Water

We study the TIP5P water model proposed by Mahoney and Jorgensen, which is closer to real water than previously-proposed classical pairwise additive potentials. We simulate the model in a wide range of deeply supercooled states and find (i) the existence of a non-monotonic ``nose-shaped'' temperature of maximum density line and a non-reentrant spinodal, (ii) the presence of a low temperature phase transition, (iii) the free evolution of bulk water to ice, and (iv) the time-temperature-transformation curves at different densities.Comment: RevTeX4, 4 pages, 4 eps figure

Resistively detected nuclear magnetic resonance via a single InSb two-dimensional electron gas at high temperature

We report on the demonstration of the resistively detected nuclear magnetic resonance (RDNMR) of a single InSb two-dimensional electron gas (2DEG) at elevated temperatures up to 4 K. The RDNMR signal of 115In in the simplest pseudospin quantum Hall ferromagnet triggered by a large direct current shows a peak-dip line shape, where the nuclear relaxation time T1 at the peak and the dip is different but almost temperature independent. The large Zeeman, cyclotron, and exchange energy scales of the InSb 2DEG contribute to the persistence of the RDNMR signal at high temperatures.Comment: 11pages,3figure

Hawking Radiation of a Quantum Black Hole in an Inflationary Universe

The quantum stress-energy tensor of a massless scalar field propagating in the two-dimensional Vaidya-de Sitter metric, which describes a classical model spacetime for a dynamical evaporating black hole in an inflationary universe, is analyzed. We present a possible way to obtain the Hawking radiation terms for the model with arbitrary functions of mass. It is used to see how the expansion of universe will affect the dynamical process of black hole evaporation. The results show that the cosmological inflation has an inclination to depress the black hole evaporation. However, if the cosmological constant is sufficiently large then the back-reaction effect has the inclination to increase the black hole evaporation. We also present a simple method to show that it will always produce a divergent flux of outgoing radiation along the Cauchy horizon where the curvature is a finite value. This means that the Hawking radiation will be very large in there and shall modify the classical spacetime drastically. Therefore the black hole evaporation cannot be discussed self-consistently on the classical Vaidya-type spacetime. Our method can also be applied to analyze the quantum stress-energy tensor in the more general Vaidya-type spacetimes.Comment: Proper boundary will lead to anti-evaporation of schwarzschild-de Sitter black holes, as corrected in Class. Quantum Grav. 11 (1994) 28