2,949 research outputs found
Orbitally-driven Peierls state in spinels
We consider the superstructures, which can be formed in spinels containing on
B-sites the transition-metal ions with partially filled t2g levels. We show
that, when such systems are close to itinerant state (e.g. have an
insulator-metal transition), there may appear in them an orbitally-driven
Peierls state. We explain by this mechanism the very unusual superstructures
observed in CuIr2S4 (octamers) and MgTi2O4 (chiral superstructures) and suggest
that similar phenomenon should be observed in NaTiO2 and possibly in some other
systems.Comment: 4 pages, 3 figure
Theoretical prediction of Jahn-Teller distortions and orbital ordering in Cs2CuCl2Br2
With the use of the density function calculations we show that the actual
crystal structure of CsCuClBr should contain elongated in the
plane CuClBr octahedra, in contrast to the experimentally observed
compression in direction. We also predict that the spins on Cu ions
should be ferromagnetically ordered in plane, while the exchange
interaction along direction is small and its sign is uncertain.Comment: 4 pages, 3 figure
Phase separation in systems with charge ordering
A simple model of charge ordering is considered. It is shown explicitly that
at any deviation from half-filling () the system is unstable with
respect to phase separation into charge ordered regions with and
metallic regions with smaller electron or hole density. Possible structure of
this phase-separated state (metallic droplets in a charge-ordered matrix)is
discussed. The model is extended to account for the strong Hund-rule onsite
coupling and the weaker intersite antiferromagnetic exchange. An analysis of
this extended model allows us to determine the magnetic structure of the
phase-separated state and to reveal the characteristic features of manganites
and other substances with charge ordering.Comment: 9 pages, revte
Jahn-Teller distortions and phase separation in doped manganites
A "minimal model" of the Kondo-lattice type is used to describe a competition
between the localization and metallicity in doped manganites and related
magnetic oxides with Jahn-Teller ions. It is shown that the number of itinerant
charge carriers can be significantly lower than that implied by the doping
level x. A strong tendency to the phase separation is demonstrated for a wide
range of intermediate doping concentrations vanishing at low and high doping.
The phase diagram of the model in the x-T plane is constructed. At low
temperatures, the system is in a state with a long-range magnetic order:
antiferromagnetic (AF), ferromagnetic (FM), or AF-FM phase separated (PS)
state. At high temperatures, there can exist two types of the paramagnetic (PM)
state with zero and nonzero density of the itinerant electrons. In the
intermediate temperature range, the phase diagram includes different kinds of
the PS states: AF-FM, FM-PM, and PM with different content of itinerant
electrons. The applied magnetic field changes the phase diagram favoring the FM
ordering. It is shown that the variation of temperature or magnetic field can
induce the metal-insulator transition in a certain range of doping levels.Comment: 14 pages, 7 figures, submitted to Phys. Rev. B.; v.2 contains the
changes introduced according to comments of the PRB Referees; in v. 3, some
misprints are correcte
Integer filling metal insulator transitions in the degenerate Hubbard model
We obtain exact numerical solutions of the degenerate Hubbard model in the
limit of large dimensions (or large lattice connectivity). Successive
Mott-Hubbard metal insulator transitions at integer fillings occur at
intermediate values of the interaction and low enough temperature in the
paramagnetic phase. The results are relevant for transition metal oxides with
partially filled narrow degenerate bands.Comment: 4 pages + 4 figures (in 5 ps-files), revte
Life After Losing an Adult Child to a Drug Overdose: A Kawa Perspective
Background: Limited research is available to occupational therapy practitioners focusing on parents’ abilities to cope with the loss of an adult child to a drug overdose. We examined the unique experiences of grieving parents from a Kawa model perspective to identify potential implications for occupational therapy.
Methods: We used a qualitative approach in which 11 participants completed Kawa drawings and participated in semi-structured interviews.
Results: Following a Kawa model analysis themes emerged: volatile nature of flow, support from inner circle and connection with outer circle, lonely islands, personal attributes of positivity and economics, and enhancing my river’s flow.
Conclusion: The loss of an adult child to a drug overdose presents health care professionals with a unique set of grieving circumstances, including changes in life roles and abilities to participate in occupations, which can be challenging to address. As a result, this study suggests the Kawa model is an effective assessment tool that should be considered for use when working with those grieving the loss of a child to a drug overdose
Role of local geometry in spin and orbital structure of transition metal compounds
We analyze the role of local geometry in the spin and orbital interaction in
transition metal compounds with orbital degeneracy. We stress that the tendency
observed for the most studied case (transition metals in O octahedra with
one common oxygen -- common corner of neighboring octahedra and with metal--oxygen--metal bonds), that ferro-orbital ordering renders
antiferro-spin coupling, and, {\it vice versa}, antiferro-orbitals give
ferro-spin ordering, is not valid in general case, in particular for octahedra
with common edge and with M--O--M bonds. Special attention is
paid to the ``third case'', neighboring octahedra with common face (three
common oxygens) -- the case practically not considered until now, although
there are many real systems with this geometry. Interestingly enough, the
spin--orbital exchange in this case turns out to be to be simpler and more
symmetric than in the first two cases. We also consider, which form the
effective exchange takes for different geometries in case of strong spin--orbit
coupling.Comment: 31 pages, 9 figures, submitted to JET
Elementary excitations of the symmetric spin-orbital model: The XY limit
The elementary excitations of the 1D, symmetric, spin-orbital model are
investigated by studying two anisotropic versions of the model, the pure XY and
the dimerized XXZ case, with analytical and numerical methods. While they
preserve the symmetry between spin and orbital degrees of freedom, these models
allow for a simple and transparent picture of the low--lying excitations: In
the pure XY case, a phase separation takes place between two phases with
free--fermion like, gapless excitations, while in the dimerized case, the
low-energy effective Hamiltonian reduces to the 1D Ising model with gapped
excitations. In both cases, all the elementary excitations involve simultaneous
flips of the spin and orbital degrees of freedom, a clear indication of the
breakdown of the traditional mean-field theory.Comment: Revtex, two figure
Orbital ordering in charge transfer insulators
We discuss a new mechanism of orbital ordering, which in charge transfer
insulators is more important than the usual exchange interactions and which can
make the very type of the ground state of a charge transfer insulator, i.e. its
orbital and magnetic ordering, different from that of a Mott-Hubbard insulator.
This purely electronic mechanism allows us to explain why orbitals in
Jahn-Teller materials typically order at higher temperatures than spins, and to
understand the type of orbital ordering in a number of materials, e.g.
K_2CuF_4, without invoking the electron-lattice interaction.Comment: 4 pages, 2 figure
Orbital ordering in frustrated Jahn-Teller systems
We consider the superexchange in `frustrated' Jahn-Teller systems, such as
the transition metal oxides NaNiO_2, LiNiO_2, and ZnMn_2O_4, in which
transition metal ions with doubly degenerate orbitals form a triangular or
pyrochlore lattice and are connected by the 90-degree metal-oxygen-metal bonds.
We show that this interaction is much different from a more familiar exchange
in systems with the 180-degree bonds, e.g. perovskites. In contrast to the
strong interplay between the orbital and spin degrees of freedom in
perovskites, in the 90-degree exchange systems spins and orbitals are
decoupled: the spin exchange is much weaker than the orbital one and it is
ferromagnetic for all orbital states. Due to frustration, the mean-field
orbital ground state is strongly degenerate. Quantum orbital fluctuations
select particular ferro-orbital states, such as the one observed in NaNiO_2. We
also discuss why LiNiO_2 may still behave as an orbital liquid.Comment: 5 pages, 3 figure
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