Géomatériaux imprimables en 3D

International audienceOne of the many attributes of 3D printing is the ability to produce particles with independent control of morphology and material properties, parameters that are inexorably entwined in naturally occurring geomaterials. In this paper we describe the 3D printing of surrogate granular materials, show examples of the particles produced and present results showing their ability to capture real soil behaviour. Three approaches are demonstrated for the three dimensional generation of model grains. The first method involves the superimposition of a fractal surface with higher level stochastic features on the face of a closed volume such as a geodesic spheroid. The second method involves the use of Fourier descriptors or fractal geometry generated from 2D cross sections and their interpolation to produce simulated geomaterial particles in three dimensions. The third method involves the generation of complex particles by the aggregation of polyhedral elements such as cubes or octahedra which is suitable for the simulation and fabrication of porous or branching particles. Finally, we discuss applications of the fabrication of surrogate materials by 3D printing for use as standardised, printable geomaterials in future up-scaled geotechnical experiments and other geomechanical research.https://doi.org/10.1680/jgeot.15.P.034L'un des nombreux attributs de l'impression 3D est la capacité de produire des particules avec un contrôle indépendant de la morphologie et des propriétés du matériau, paramètres inextricablement liés dans les géomatériaux naturels. Dans cet article, nous décrivons l'impression 3D de matériaux granulaires de substitution, montrons des exemples de particules produites et présentons les résultats montrant leur capacité à capturer le comportement réel du sol. Trois approches sont démontrées pour la génération tridimensionnelle de grains modèles. La première méthode implique la superposition d'une surface fractale avec des caractéristiques stochastiques de niveau supérieur sur la face d'un volume fermé tel qu'un sphéroïde géodésique. La deuxième méthode implique l'utilisation de descripteurs de Fourier ou de géométrie fractale générés à partir de sections transversales 2D et leur interpolation pour produire des particules de géomatériau simulées en trois dimensions. La troisième méthode implique la génération de particules complexes par l'agrégation d'éléments polyédriques, tels que des cubes ou des octaèdres, qui conviennent à la simulation et à la fabrication de particules poreuses ou ramifiées. Enfin, nous discutons des applications de la fabrication de matériaux de substitution par impression 3D pour une utilisation en tant que géomatériaux imprimables et normalisés dans de futures expériences géotechniques à grande échelle et autres recherches géomécaniques.https://doi.org/10.1680/jgeot.15.P.03

Tuning of Electrical and Optical Properties of Highly Conducting and Transparent Ta-Doped TiO2 Polycrystalline Films

We present a detailed study on polycrystalline transparent conducting Ta-doped TiO2 films, obtained by room temperature pulsed laser deposition followed by an annealing treatment at 550°C in vacuum. The effect of Ta as a dopant element and of different synthesis conditions are explored in order to assess the relationship between material structure and functional properties, i.e. electrical conductivity and optical transparency. We show that for the doped samples it is possible to achieve low resistivity (of the order of 5×10-4 Ωcm) coupled with transmittance values exceeding 80% in the visible range, showing the potential of polycrystalline Ta:TiO2 for application as a transparent electrode in novel photovoltaic devices. The presence of trends in the structural (crystalline domain size, anatase cell parameters), electrical (resistivity, charge carrier density and mobility) and optical (transmittance, optical band gap, effective mass) properties as a function of the oxygen background pressures and laser fluence used during the deposition process and of the annealing atmosphere is discussed, and points towards a complex defect chemistry ruling the material behavior. The large mobility values obtained in this work for Ta:TiO2 polycrystalline films (up to 13 cm2V-1s-1) could represent a definitive advantage with respect to the more studied Nb-doped TiO2

Synthesis and Electrochemical Performance of High Entropy Spinel Type Oxides Derived from Multimetallic Polymeric Precursors

High entropy spinel type oxides are synthesized by a modified Pechini process, wet chemistry approach, and solid state synthesis method and characterized as anode materials for Li ion batteries. The Pechini process that involves chelation and polyesterification reactions facilitates the formation of high entropy spinel type oxides without compositional segregation at amp; 8776;600 amp; 8201; C as confirmed by in amp; 8201;situ and ex amp; 8201;situ XRD. XAFS analysis and the Rietveld refinement of room temperature neutron diffraction data suggest the composition Mn0.05Fe0.48Co0.47, tetrahedral Cr0.61Mn0.52Fe0.11Co0.09Ni0.68, octahedral O4 for phase pure specimens. Compared to high entropy spinel type oxides synthesized by the solid state method, the precursor derived materials demonstrate higher specific capacity as anodes, in which the materials without citric acid addition exhibit low capacity fading at high current densities and maintained a capacity of amp; 8776;200 amp; 8201;mAh amp; 8201;g amp; 8722;1 after 1000 cycles. The generation of a rock salt type phase during cycling is confirmed for the first time by in amp; 8201;situ charging discharging XRD. The charging discharging of this anode material is achieved mainly through the embedding disembedding of lithium ions in the lattice of the generated rock salt type phas